Electrophotographic light-sensitive printing materials

Claim 1

An electrophotographic light-sensitive printing material comprising a conductive base plate having formed thereon an electrophotographic light-sensitive layer containing (a) a hydrazone compound, (b) at least one compound selected from a barbituric acid derivative, a thiobarbituric acid derivative, and other charge generating materials, and (c) a resin binder, wherein said hydrazone compound is one member selected from the group consisting of the following general formulas (I), (II), (III), (IV), (V), and (VI): ##STR18## wherein X represents an oxygen atom, a sulfur atom, a selenium atom, an unsubstituted or substituted imino group, or a methylene group; R 1 represents an alkoxy group, an aralkoxy group, or a substituted amino group shown by ##STR19## wherein R 12 and R 13 , which may be the same or different, each represents an unsubstituted or substituted alkyl or phenyl group or R 12 and R 13 may represent groups which are combined with each other to form a heterocyclic ring including nitrogen atom; R 2 and R 3 , which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, or a lower alkoxy group; R 4 represents a hydrogen atom, an alkyl group, an unsubstituted or substituted phenyl group; R 5 and R 6 , which may be the same or different, each represents an unsubstituted or subtituted straight chain or branched alkyl group having 1 to 12 carbon atoms, an unsubstituted or substituted straight chain or branched aralkyl group having 7 to 20 carbon atoms, or a monovalent group, aryl group, formed by removing one hydrogen atom from an unsubstituted or substituted monocyclic or 2 to 4 cyclic condensed aromatic hydrocarbon, or R 5 and R 6 my form a carbazole ring; R 7 represents an unsubstituted or substituted alkyl group; R 8 , R 9 , R 10 , and R 11 which may be the same or different, each represents a hydrogen atom, a halogen atom, an unsubstituted or substituted alkyl group or phenyl group, an alkoxy group, an aralkoxy group, or an amino group shown by ##STR20## wherein R 14 and R 15 represent a hydrogen atom or the same groups as shown by R 12 and R 13 described above, or may combine with each other to form a condensed carbon ring or a condensed heterocyclic ring; A represents a monocyclic or condensed heterocyclic 5-membered ring or condensed heterocyclic 6-membered ring shown by the following structural formula: ##STR21## wherein Y and Z, which may be the same or different, each represents a sulfur atom, an oxygen atom, or N-R 17' wherein R 17' is an alkyl group having 1 to 4 carbon atoms, R 16 represents a hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a halogen atom, a monoalkylamino group, a dialkylamino group, an amido group or a nitro group, R 17 and R 18 , which may be the same or different, represent a hydrogen atom, an alkyl group or an alkoxy group, or may be groups which combine with each other to form a benzene ring or a naphthalene ring; and B represents an unsubstituted or substituted aryl group; and wherein said barbituric acid derivative or thiobarbituric acid derivative is at least one member selected from the group consisting of the following general formulas (VII) and (VIII): ##STR22## wherein Z represents an oxygen atom or a sulfur atom; R 1 , R 2 , R 3 , R 4 and A are the same as defined above; and R 19 and R 20 , which may be the same or different, each represents an alkyl group, an aralkyl group, or an unsubstituted or substituted phenyl group.