US4500281A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Burning of fuels
Assignee: Phillips Petroleum Co
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Filing: 1982-08-02
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Granted: 1985-02-19
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Expires: 2002-08-02
Abstract
Abstract NO x emissions are reduced in the combustion of a fuel, containing significant amounts of NO x precursors, by carrying out the combustion in at least three, serially connected combustion zones in open communication with one another, including at least two fuel-rich zones and a last fuel-lean zone and in the presence of a combustion catalyst added to the fuel adjacent the upstream end of the first of the fuel-rich zones. SO x emissions are also reduced when burning a fuel, containing significant amounts of SO x precursors, by additionally adding a sulfur scavenger to the fuel adjacent the upstream end of the first fuel-rich zone.
Inventors
- 👤 David H. Beardmore
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 19:51
CPC Classifications
F; F23; F23C; F23C13/00; C; C10; C10L; C10L10/00; C10L10/02; C10L9/00; C10L9/02; F23C6/00; F23C6/04; F23C6/045; F23J; F23J7/00
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
428 words
A method of burning a fuel, containing significant amounts of NO x precursors, comprising: (a) passing said fuel through at least three serially connected combustion zones in open communication with one another, including; at least two fuel-rich zones and a last fuel-lean zone; (b) adding a first volume of combustion-supporting material adjacent the upstream end of the first of said fuel-rich zones and intimately mixing the thus added first volume of combustion-supporting material with all of said fuel adjacent said upstream end of said first of said fuel-rich zones; (c) adding an additional volume of combustion-supporting material adjacent the upstream end of each of the remaining fuel-rich zones and intimately mixing the thus added additional volume of combustion-supporting material with effluent from the immediately preceeding fuel-rich zone adjacent said upstream end of each of said remaining fuel-rich zones; (d) the total combustion-supporting material thus added to the upstream end of said first fuel-rich zone and said remaining fuel-rich zones, together with said fuel, resulting in a fuel/combustion-supporting material equivalence ratio greater than 1.0; (e) adding a still further volume of combustion-supporting material adjacent the upstream end of said fuel-lean zone and intimately mixing the thus added still further volume of combustion-supporting material with effluent from the last of said fuel-rich zones adjacent said upstream end of said fuel-lean zone; (f) the total combustion-supporting material thus added to the upstream ends of said first fuel-rich zone, said remaining fuel-rich zones and said fuel-lean zone, together with said fuel, resulting in a fuel/combustion-supporting material equivalence ratio less than 1.0; (g) providing an outlet from each combustion zone of substantially less cross-sectional area than the cross-sectional area of the beginning of the next succeeding combustion zone and abruptly terminating more fuel-rich combustion adjacent the downstream end of each of a preceeding one of said combustion zones and initiating less fuel-rich combustion adjacent the upstream end of each of an immediately succeeding one of said combustion zones, at least in part, by thus adding combustion-supporting material to the effluent of said preceding one of said combustion zones as a plurality of radial jets toward the center of said combustion zone, whereby at least three clearly defined combustion zones are formed; (h) adding a catalytic amount of a combustion catalyst to the thus formed mixture of said fuel and said first volume of combustion-supporting material adjacent said upstream end of said first of said fuel-rich zones; and (i) burning said fuel in the presence of said combustion-supporting material and said combustion catalyst in a serial manner in said at least three combustion zones.
Claim 2
Independent Claim
428 words
A method of burning a fuel, containing significant amounts of NO x precursors, comprising: (a) passing said fuel through at least three serially connected combustion zones in open communication with one another, including; at least two fuel-rich zones and a last fuel-lean zone; (b) adding a first volume of combustion-supporting material adjacent the upstream end of the first of said fuel-rich zones and intimately mixing the thus added first volume of combustion-supporting material with all of said fuel adjacent said upstream end of said first of said fuel-rich zones; (c) adding an additional volume of combustion-supporting material adjacent the upstream end of each of the remaining fuel-rich zones and intimately mixing the thus added additional volume of combustion-supporting material with effluent from the immediately preceeding fuel-rich zone adjacent said upstream end of each of said remaining fuel-rich zones; (d) the total combustion-supporting material thus added to the upstream end of said first fuel-rich zone and said remaining fuel-rich zones, together with said fuel, resulting in a fuel/combustion-supporting material equivalence ratio greater than 1.0; (e) adding a still further volume of combustion-supporting material adjacent the upstream end of said fuel-lean zone and intimately mixing the thus added still further volume of combustion-supporting material with effluent from the last of said fuel-rich zones adjacent said upstream end of said fuel-lean zone; (f) the total combustion-supporting material thus added to the upstream ends of said first fuel-rich zone, said remaining fuel-rich zones and said fuel-lean zone, together with said fuel, resulting in a fuel/combustion-supporting material equivalence ratio less than 1.0; (g) providing an outlet from each combustion zone of substantially less cross-sectional area than the cross-sectional area of the beginning of the next succeeding combustion zone and abruptly terminating more fuel-rich combustion adjacent the downstream end of each of a preceeding one of said combustion zones and initiating less fuel-rich combustion adjacent the upstream end of each of an immediately succeeding one of said combustion zones, at least in part, by thus adding combustion-supporting material to the effluent of said preceding one of said combustion zones as a plurality of radial jets toward the center of said combustion zone, whereby at least three clearly defined combustion zones are formed; (h) adding a catalytic amount of a combustion catalyst to the thus formed mixture of said fuel and said first volume of combustion-supporting material adjacent said upstream end of said first of said fuel-rich zones; and (i) burning said fuel in the presence of said combustion-supporting material and said combustion catalyst in a serial manner in said at least three combustion zones.
Claim 3
Dependent Claim
72 words
A method in accordance with claim 1 wherein abrupt termination of more fuel-rich combustion adjacent the downstream end of each preceding combustion zone is attained by abruptly expanding the effluent from the downstream end of said each preceding combustion zone into the upstream end of each immediately succeeding combustion zone and adding the combustion-supporting material to the effluent from said each preceding combustion zone immediately adjacent the location of such abrupt expansion.
Claim 4
Dependent Claim
95 words
A method in accordance with claim 1 wherein abrupt termination of more fuel-rich combustion adjacent the downstream end of each preceding combustion zone is attained by reducing the peripheral dimension of the effluent from the downstream end of said each preceding combustion zone, immediately thereafter abruptly expanding the effluent of reduced peripheral dimension from said downstream end of said each preceding combustion zone into the upstream end of each immediately succeeding combustion zone and adding the combustion-supporting material to the effluent from said each preceding combustion zone immediately adjacent the location of such abrupt expansion.
Claim 5
Dependent Claim
22 words
A method in accordance with claim 2 or 3 wherein the combustion-supporting material is added immediately preceding the expansion of the effluent.
Claim 6
Dependent Claim
21 words
A method in accordance with claim 3 wherein the combustion-supporting material is introduced into the reduced diameter portion of the effluent.
Claim 7
Dependent Claim
16 words
A method in accordance with claim 1 wherein the fuel is a normally liquid organic fuel.
Claim 8
Dependent Claim
16 words
A method in accordance with claim 1 wherein the fuel is a normally solid carbonaceous material.
Claim 9
Dependent Claim
15 words
A method in accordance with claim 1 wherein the combustion catalyst is an organo-metallic compound.
Claim 10
Dependent Claim
16 words
A method in accordance with claim 8 wherein the organo-metallic compound is an iron containing compound.
Claim 11
Dependent Claim
32 words
A method in accordance with claim 9 wherein the iron containing organo-metallic compound is selected from the group consisting of Fe 2 O 3 , Fe 3 O 4 and mixtures thereof.
Claim 12
Dependent Claim
26 words
A method in accordance with claim 1 wherein the combustion catalyst is added in amounts between about 1 and about 10 wt. percent of the fuel.
Claim 13
Dependent Claim
39 words
A method in accordance with claim 1 wherein the total combustion-supporting material added adjacent the upstream ends of all of the fuel-rich zones forms, with the fuel, a fuel-combustion supporting material equivalence ratio between about 1 and about 1.7.
Claim 14
Dependent Claim
49 words
A method in accordance with claim 1 wherein the fuel additionally contains significant amounts of SO x precursors and a sulfur scavanger which forms solid sulfur compounds is added to the fuel and the first volume of combustion supporting material adjacent the upstream end of the first fuel-rich zone.
Claim 15
Dependent Claim
15 words
A method in accordance with claim 13 wherein the sulfur scavenger is a calcium compound.
Claim 16
Dependent Claim
33 words
A method in accordance with claim 14 wherein the calcium compound is a compound selected from the group consisting of Ca(OH) 2 , CaCO 3 , CaMg(CO 3 ) 2 and mixtures thereof.
Claim 17
Dependent Claim
15 words
A method in accordance with claim 13 wherein the sulfur scavenger is a metal carbonate.
Claim 18
Dependent Claim
31 words
A method in accordance with claim 16 wherein the metal carbonate is selected from the group consisting of CaCO 3 , CaMg(CO 3 ) 2 , MgCO 3 and mixtures thereof.
Claim 19
Dependent Claim
29 words
A method in accordance with claim 13 wherein the sulfur scavenger is a metal compound and the metal compound is present in an amount near the metal/sulfur stoichiometric ratio.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-02-19 | 1988-08-20 | 1989-02-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-02-19 | 1992-08-20 | 1993-02-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-02-19 | 1996-08-20 | 1997-02-19 | $7700.00 | Window Closed / Lapsed |