US4499245A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Curable resin composition
Assignee: Mitsubishi Gas Chemical Co Inc
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Filing: 1983-07-15
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Granted: 1985-02-12
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Expires: 2003-07-15
Abstract
Abstract A curable resin composition comprising a mixture and/or a preliminary reaction product of (a) at least one cyanate compound selected from the group consisting of polyfunctional cyanate esters, prepolymers of the cyanate esters, coprepolymers of the cyanate esters and an amine and mixtures thereof, (b) a polyhydantoin resin and optionally (c) at least one maleimide compound selected from the group consisting of polyfunctional maleimides, prepolymer of the maleimides, coprepolymers of the maleimides and an amine and mixtures thereof is disclosed.
Inventors
- 👤 Nobuyuki Ikeguchi
- 👤 Hidenori Kimbara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 13:06
CPC Classifications
C; C08; C08G; C08G73/00; C08L; C08L79/00; Y; Y10; Y10S; Y10S525/00; Y10S525/908
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
240 words
A curable resin composition comprising: (a) at least one cyanate ester compound selected from the group consisting of: (1) a polyfunctional aromatic cyanate ester monomer having the formula: R--O--C.tbd.N).sub.m where m is 2 to 5 and R is an aromatic organic group, the cyanate groups being bonded to an aromatic ring of said aromatic organic group, (2) a prepolymer of one or more of said cyanate ester monomer, said prepolymer containing a sym-triazine ring and having an average molecular weight in the range of about 400 to 6,000, and (3) a coprepolymer of said cyanate ester monomer and an amine; (b) a polyhydantoin resin having a hydantoin ring in the main chain and having the following repeated units: ##STR6## (c) at least one compound selected from the group consisting of: (1) a polyfunctional maleimide, (2) a homoprepolymer of one or more of said maleimide, and (3) a coprepolymer of said maleimide and an amine, said composition including a mixture of components the (a), the (b), and the (c), a preliminary reaction product of components the (a), the (b), and the (c), a combination of said mixture and said preliminary reaction product, a composition of the (a) an a preliminary reaction product of the (b) and the (c), a combination of the (b), and a preliminary reaction product of the (a) and the (c), or a combination of the (c) and a preliminary reaction product of the (a) and the (b).
Claim 2
Dependent Claim
240 words
A curable resin composition comprising: (a) at least one cyanate ester compound selected from the group consisting of: (1) a polyfunctional aromatic cyanate ester monomer having the formula: R--O--C.tbd.N).sub.m where m is 2 to 5 and R is an aromatic organic group, the cyanate groups being bonded to an aromatic ring of said aromatic organic group, (2) a prepolymer of one or more of said cyanate ester monomer, said prepolymer containing a sym-triazine ring and having an average molecular weight in the range of about 400 to 6,000, and (3) a coprepolymer of said cyanate ester monomer and an amine; (b) a polyhydantoin resin having a hydantoin ring in the main chain and having the following repeated units: ##STR6## (c) at least one compound selected from the group consisting of: (1) a polyfunctional maleimide, (2) a homoprepolymer of one or more of said maleimide, and (3) a coprepolymer of said maleimide and an amine, said composition including a mixture of components the (a), the (b), and the (c), a preliminary reaction product of components the (a), the (b), and the (c), a combination of said mixture and said preliminary reaction product, a composition of the (a) an a preliminary reaction product of the (b) and the (c), a combination of the (b), and a preliminary reaction product of the (a) and the (c), or a combination of the (c) and a preliminary reaction product of the (a) and the (b).
Claim 3
Dependent Claim
66 words
The composition as defined in claim 1 wherein the cyanate ester is selected from the group consisting of 1,3-, 1,4-dicyanatobenzene; 1,3,5-tricyanatobenzene; 1,3-, 1,4- 1,6-, 1,8-, 2,6- or 2,7-dicyanatonaphthalene; 1,3,6-tricyanatonaphthalene; 4,4'-dicyanatobiphenyl; bis(4-cyanatophenyl)methane; 2,2-bis(4-cyanatophenyl)propane, 2,2-bis(3,5-dichloro-4-cyanatophenyl)propane; 2,2-bis(3,5-dibromo-4-dicyanatophenyl)propane; bis(4-cyanatophenyl)ether; bis(4-cyanatophenyl)thioether; bis(4-cyanatophenyl)sulfone; tris(4-cyanatophenyl)phosphite; tris(4-cyanatophenyl)phosphate; bis(3-chloro-4-cyanatophenyl)methane; cyanated novolak produced by reacting a novolak with cyanogen halide; cyanated bisphenol type polycarbonate oligomer produced by reacting a bisphenol type polycarbonate oligomer and mixture thereof.
Claim 4
Dependent Claim
27 words
The composition as defined in claim 1 wherein the ratio by weight of component (a) to component (b) is in the range of from 99:1 to 1:99.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-02-12 | 1988-08-13 | 1989-02-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-02-12 | 1992-08-13 | 1993-02-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-02-12 | 1996-08-13 | 1997-02-12 | $7700.00 | Window Closed / Lapsed |