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US4498467A Expired / Lapsed US ⏱️ 0.0 years remaining

Orthopedic cast, device and method for forming same and package therefor

Assignee: Zimmer Surgical Inc
•
Filing: 1982-01-20
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Granted: 1985-02-12
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Expires: 2002-01-20
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Abstract

Abstract A device for forming an orthopedic cast is disclosed which is composed of a core having a fibrous, porous tape rolled thereabout. The tape is impregnated with a first liquid component of a two-component hardenable system. The core is composed of a pressure rupturable container having the second component of the two-component system therein in liquid form. The entirety is encased in a flexible package which serves as a mixing chamber for intermixing the first and second components upon application of pressure to the package sufficient to rupture the core. After intermixing, the package is opened, the tape unrolled and placed about the broken limb in the conventional manner. The cast hardens within a short time at ambient temperature to provide a light-weight, breathable and waterproof orthopedic cast.

Inventors

  • 👤 Harold B. Kirkpatrick
  • 👤 Fred A. Ravreby
  • 👤 Henry L. Richbourg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 19:35
CPC Classifications
A; A61; A61F; A61F15/00; A61F13/00; A61F13/04; A61L; A61L15/00; A61L15/07; C; C08; C08G; C08G18/00; C08G18/06; C08G18/08

Claims Analysis

Total Claims: 54
Claim 1
Independent Claim 109 words
A device for forming an orthopedic cast comprising: a fibrous porous tape rolled about a core, said tape being impregnated with a first liquid component of a two-component hardenable system; said core being composed of a sealed liquid impermeable pressure rupturable container and having therein a second component of said two-component hardenable system in liquid form which, on intermixing with said first component, reacts to form a hard resin at ambient temperatures; said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the first and second components upon the application of pressure to said package sufficient to rupture the core.
Claim 2
Independent Claim 109 words
A device for forming an orthopedic cast comprising: a fibrous porous tape rolled about a core, said tape being impregnated with a first liquid component of a two-component hardenable system; said core being composed of a sealed liquid impermeable pressure rupturable container and having therein a second component of said two-component hardenable system in liquid form which, on intermixing with said first component, reacts to form a hard resin at ambient temperatures; said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the first and second components upon the application of pressure to said package sufficient to rupture the core.
Claim 3
Dependent Claim 12 words
The device of claim 1 wherein said core is cylindrical in shape.
Claim 4
Dependent Claim 19 words
The device of claim 1 or 2 wherein the tape is knitted or woven natural, polymeric or glass fiber.
Claim 5
Dependent Claim 43 words
The device of claim 1 or 2 wherein the core is composed of a material selected from the group consisting of paraffin wax, paraffin wax modified with polyethylene or mineral filled phenolic resin, urea resin, melamine resin, modified terephthalate resin, and polymeric film.
Claim 6
Dependent Claim 26 words
The device of claim 1 or 2 wherein the core is composed of a material selected from the group consisting of polyethylene, polypropylene, or polyvinylidine chloride.
Claim 7
Dependent Claim 23 words
The device of claim 1 or 2 wherein the first liquid component is a polyol and the second liquid component is an isocyanate.
Claim 8
Dependent Claim 33 words
The device of claim 1 or 2 wherein the first liquid component is a polyoxyalkylene polyol selected from the group consisting of the reaction products of a multi-functional alcohol and an alkylene oxide.
Claim 9
Dependent Claim 35 words
The device of claim 7 wherein the polyol is the reaction product of a dihydric or trihydric alcohol and an alkylene oxide said alkylene oxide having from 2 to 4 carbon atoms in the molecule.
Claim 10
Dependent Claim 42 words
The device of claim 7 wherein the multi-functional alcohol is selected from the group consisting of glycerine, diethylene glycol, triethylene glycol, and butylene glycol and the alkylene oxide is selected from the group consisting of ethylene oxide, propylene oxide, or butylene oxide.
Claim 11
Dependent Claim 36 words
The device of claim 7 wherein the polyol is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676.
Claim 12
Dependent Claim 24 words
The device of claim 1 or 2 wherein the second liquid component is selected from the group consisting of aromatic, aliphatic and cycloaliphatic isocyanates.
Claim 13
Dependent Claim 25 words
The device of claim 1 or 2 wherein the second liquid component is selected from the group consisting of tolylene diisocyanate and methylene diphenyl diisocyanate.
Claim 14
Dependent Claim 42 words
The device of claim 1 or 2 wherein the first liquid component is a polyol and the second liquid component is an isocyanate and each component contains up to 50 weight percent and up to 30 weight percent, respectively, of a plasticizer.
Claim 15
Dependent Claim 26 words
The device of claim 13 wherein the plasticizer is selected from the group consisting of dibutyl phthalate, dibutyl maleate, butyl benzyl phthalate and acetyl tributyl citrate.
Claim 16
Dependent Claim 14 words
The device of claim 13 wherein the plasticizer is a short chain dialkyl phthalate.
Claim 17
Dependent Claim 45 words
The device of claim 1 or 2 wherein the first liquid component is a polyol and the second liquid component is an isocyanate and the polyol also contains from about 0.1 to 3.0 weight percent of a catalyst based on the weight of the polyol.
Claim 18
Dependent Claim 24 words
The device of claim 16 wherein the catalyst is selected from the group consisting of organo-tin compounds, amines, and metal salts of organic acids.
Claim 19
Dependent Claim 56 words
The device of claim 1 or 2 wherein the first liquid component is a prepolymer formed from a polyol and an isocyanate, said prepolymer having an available isocyanate content from about 5 to 20 percent and said polyol being selected from the group consisting of the reaction products of a multi-functional alcohol and an alkylene oxide.
Claim 20
Dependent Claim 23 words
The device of claim 18 wherein the polyol has a molecular weight of about 260 and a hydroxyl number from 644 to 676.
Claim 21
Dependent Claim 16 words
The device of claim 18 wherein the component within the core is composed of a polyol.
Claim 22
Dependent Claim 19 words
The device of claim 18 wherein the component within the core is composed of a polyol and a catalyst.
Claim 23
Dependent Claim 21 words
The device of claim 18 wherein the component within the core is composed of a polyol, a plasticizer and a catalyst.
Claim 24
Dependent Claim 45 words
The device of claim 22 wherein the plasticizer is selected from the group consisting of dibutyl phthalate, dibutyl maleate, butyl benzyl phthalate and acetyl tributyl citrate and the catalyst is selected from the group consisting of organo-tin compounds, amines, and metal salts of organic acids.
Claim 25
Dependent Claim 15 words
The device of claim 18 wherein the isocyanate is an aromatic, aliphatic or cycloaliphatic isocyanate.
Claim 26
Dependent Claim 12 words
The device of claim 18 wherein the second liquid component is water.
Claim 27
Dependent Claim 35 words
The device of claim 25 wherein the polyol is the reaction product of a dihydric or trihydric alcohol and an alkylene oxide said alkylene oxide having from 2 to 4 carbon atoms in the molecule.
Claim 28
Dependent Claim 42 words
The device of claim 25 wherein the multi-functional alcohol is selected from the group consisting of glycerine, diethylene glycol, triethylene glycol, and butylene glycol and the alkylene oxide is selected from the group consisting of ethylene oxide, propylene oxide, or butylene oxide.
Claim 29
Dependent Claim 36 words
The device of claim 25 wherein the polyol is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676.
Claim 30
Dependent Claim 11 words
The device of claim 25 wherein the water contains a polyol.
Claim 31
Dependent Claim 27 words
The device of claim 29 wherein the water also contains a catalyst selected from the group consisting of organo-tin compounds, amines, and metal salts of organic acids.
Claim 32
Independent Claim 91 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a polyol, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a liquid isocyanate which, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 33
Independent Claim 91 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a polyol, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a liquid isocyanate which, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 34
Independent Claim 119 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a polyol selected from the group consisting of the reaction products of a multi-functional alcohol and an alkylene oxide, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a liquid isocyanate selected from the group consisting of aromatic, aliphatic and cycloaliphatic isocyanates, which, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 35
Independent Claim 119 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a polyol selected from the group consisting of the reaction products of a multi-functional alcohol and an alkylene oxide, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a liquid isocyanate selected from the group consisting of aromatic, aliphatic and cycloaliphatic isocyanates, which, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 36
Independent Claim 132 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a polyol which is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a liquid isocyanate selected from the group consisting of tolylene diisocyanate and methylene diphenyl diisocyanate, which, on intermixing with said polyol reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 37
Independent Claim 132 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a polyol which is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a liquid isocyanate selected from the group consisting of tolylene diisocyanate and methylene diphenyl diisocyanate, which, on intermixing with said polyol reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 38
Independent Claim 117 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a mixture of a polyol and up to about 50 weight percent of a plasticizer, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a mixture of a liquid isocyanate and up to about 30 weight percent of a plasticizer, which, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 39
Independent Claim 117 words
A device for forming an orthopedic cast comprising a fibrous porous tape rolled about a core, said tape being impregnated with a mixture of a polyol and up to about 50 weight percent of a plasticizer, said core being composed of a sealed liquid impermeable pressure rupturable container and containing a mixture of a liquid isocyanate and up to about 30 weight percent of a plasticizer, which, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 40
Independent Claim 228 words
A device for forming an orthopedic cast comprising a fibrous, porous glass tape rolled about a core, said tape being impregnated with a composition composed of from 75.7-75.8 weight percent of a polyol which is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676, from 20.85-20.95 weight percent of dibutylphthalate, from about 2.62 to 2.68 weight percent of a catalyst selected from the group consisting of organo-tin compounds, amines and metal salts of organic acids, and from about 0.66 to 0.70 weight percent of an antifoam agent, the amount of said composition on said tape being about 0.052 gm/in 2 ±0.25 g/in 2 , said core being composed of a sealed liquid impermeable pressure rupturable container and containing a composition composed of from about 89.73 to 89.93 weight percent of methylene diphenyl diisocyanate modified with a carbodiimide so as to be a liquid at ambient temperature, and from about 10.17 to about 10.27 weight percent of dibutylphthalate, which core composition, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 41
Independent Claim 228 words
A device for forming an orthopedic cast comprising a fibrous, porous glass tape rolled about a core, said tape being impregnated with a composition composed of from 75.7-75.8 weight percent of a polyol which is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676, from 20.85-20.95 weight percent of dibutylphthalate, from about 2.62 to 2.68 weight percent of a catalyst selected from the group consisting of organo-tin compounds, amines and metal salts of organic acids, and from about 0.66 to 0.70 weight percent of an antifoam agent, the amount of said composition on said tape being about 0.052 gm/in 2 ±0.25 g/in 2 , said core being composed of a sealed liquid impermeable pressure rupturable container and containing a composition composed of from about 89.73 to 89.93 weight percent of methylene diphenyl diisocyanate modified with a carbodiimide so as to be a liquid at ambient temperature, and from about 10.17 to about 10.27 weight percent of dibutylphthalate, which core composition, on intermixing with said polyol, reacts to form a hard resin at ambient temperatures, said tape and core being encased in a flexible package adapted to serve as a mixing chamber for intermixing the polyol and isocyanate upon the application of hand-pressure to the package sufficient to rupture the core.
Claim 42
Dependent Claim 119 words
In a method for making an orthopedic cast for a limb wherein an underwrap is applied to the area of the limb and an immobilizing support is then formed by wrapping a fibrous, porous tape impregnated with a hardenable material around said underwrap and then hardening said hardenable material, the improvement which comprises said hardenable material being a two-component composition, the first component of which is a polyoxyalkylene polyol, and the second component of which is a liquid isocyanate, said composition being capable of hardening by mixing the two components at ambient temperatures, and wherein said tape is impregnated with a mixture of said two components which are then allowed to harden at ambient temperatures to form said cast.
Claim 43
Dependent Claim 119 words
In a method for making an orthopedic cast for a limb wherein an underwrap is applied to the area of the limb and an immobilizing support is then formed by wrapping a fibrous, porous tape impregnated with a hardenable material around said underwrap and then hardening said hardenable material, the improvement which comprises said hardenable material being a two-component composition, the first component of which is a polyoxyalkylene polyol, and the second component of which is a liquid isocyanate, said composition being capable of hardening by mixing the two components at ambient temperatures, and wherein said tape is impregnated with a mixture of said two components which are then allowed to harden at ambient temperatures to form said cast.
Claim 44
Dependent Claim 21 words
The method of claim 36 wherein the first component is the reaction product of a multi-functional alcohol and an alkylene oxide.
Claim 45
Dependent Claim 35 words
The method of claim 36 wherein the polyol is the reaction product of a dihydric or trihydric alcohol and an alkylene oxide said alkylene oxide having from 2 to 4 carbon atoms in the molecule.
Claim 46
Dependent Claim 42 words
The method of claim 37 wherein the multi-functional alcohol is selected from the group consisting of glycerine, diethylene glycol, triethylene glycol, and butylene glycol and the alkylene oxide is selected from the group consisting of ethylene oxide, propylene oxide, or butylene oxide.
Claim 47
Dependent Claim 36 words
The method of claim 36 wherein the polyol is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676.
Claim 48
Dependent Claim 22 words
The method of claim 36 wherein the second liquid component is selected from the group consisting of aromatic, aliphatic and cycloaliphatic isocyanates.
Claim 49
Dependent Claim 23 words
The method of claim 36 wherein the second liquid component is selected from the group consisting of tolylene diisocyanate and methylene diphenyl diisocyanate.
Claim 50
Dependent Claim 32 words
The method of claim 36 wherein the first component contains up to about 50 weight percent of a plasticizer and the second component contains up to 30 weight percent of a plasticizer.
Claim 51
Dependent Claim 53 words
The method of claim 36 wherein the first component contains up to about 50 weight percent of a plasticizer and the second component contains up to 30 weight percent of a plasticizer and the plasticizer is selected from the group consisting of dibutyl phthalate, dibutyl maleate, butyl benzyl phthalate and acetyl tributyl citrate.
Claim 52
Dependent Claim 27 words
The method of claim 36 wherein the first component contains a catalyst selected from the group consisting of organo-tin compounds, amines, and metal salts of organic acids.
Claim 53
Dependent Claim 44 words
The method of claim 36 wherein the first component contains a catalyst selected from the group consisting of organo-tin compounds, amines, and metal salts of organic acids in an amount from about 0.1 to 3.0 weight percent based on the weight of the polyol.
Claim 54
Dependent Claim 137 words
The method of claim 36 wherein the first component is a composition composed of from 75.7-75.8 weight percent of a polyol which is the reaction product of glycerine and propylene oxide and possesses a molecular weight of about 260 and a hydroxyl number in the range from 644 to 676, from 20.85-20.95 weight percent of dibutylphthalate, from about 2.62 to 2.68 weight percent of a catalyst selected from the group consisting of organo-tin compounds, amines and metal salts of organic acids, and from about 0.66 to 0.70 weight percent of an antifoam agent and the second component is a composition composed of from about 89.73 to 89.93 weight percent of methylene diphenyl diisocyanate modified with a carbodiimide so as to be a liquid at ambient temperature, and from about 10.17 to about 10.27 weight percent of dibutylphthalate.

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