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US4496788A Expired / Lapsed US ⏱️ 0.0 years remaining

Photovoltaic device

Assignee: Daihen Corp
•
Filing: 1983-09-02
•
Granted: 1985-01-29
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Expires: 2003-09-02
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Abstract

Abstract A photovoltaic device comprising at least one crystalline and one amorphous semiconductor region with different photosensitivity is provided to absorb light in a wide range of wavelength, and serves, for example, as a solar battery or a color sensor. Amorphous or microcrystalline semiconductor regions comprising those devices can be deposited easily and in a continuous manufacturing process by the use of a low temperature process, and this allows manufacture of a photovoltaic device at low cost.

Inventors

  • 👤 Yoshihiro Hamakawa
  • 👤 Hiroaki Okamoto
  • 👤 Kouji Okuda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 14:55
CPC Classifications
H; H10; H10F; H10F10/00; H10F10/10; H10F10/16; H10F10/164; H10F10/165; H10F10/166; H10F10/19; H10F77/00; H10F77/10; H10F77/16; H10F77/162; H10F77/164; H10F77/1642; H10F77/1645; H10F77/70; H10F77/703; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/545; Y02E10/548

Claims Analysis

Total Claims: 40
Claim 1
Independent Claim 107 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a heterojunction solar cell comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; an amorphous solar cell tandemly applied on said heterojunction solar cell in optical and electrical series therewith, and comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between said regions, and a p-n junction formed at the interface between said heterojunction solar cell and said amorphous solar cell.
Claim 2
Dependent Claim 107 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a heterojunction solar cell comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; an amorphous solar cell tandemly applied on said heterojunction solar cell in optical and electrical series therewith, and comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between said regions, and a p-n junction formed at the interface between said heterojunction solar cell and said amorphous solar cell.
Claim 3
Dependent Claim 44 words
The device according to claim 1, wherein said solar cells are placed from the light-receiving side in the order of decreasing width of the energy gap of said i-type region in said amorphous solar cell and said crystalline region in said heterojunction solar cell.
Claim 4
Dependent Claim 26 words
The device according to claim 1, wherein at least one of said amorphous or microcrystalline regions is deposited by the use of a low temperature process.
Claim 5
Dependent Claim 19 words
The device according to claim 1, wherein said crystalline semiconductor region in said heterojunction solar cell comprises a wafer.
Claim 6
Dependent Claim 14 words
The device according to claim 4, wherein said crystalline region has an irregular surface.
Claim 7
Dependent Claim 30 words
The device according to claim 1, wherein said crystalline semiconductor region in said heterojunction solar cell comprises a thin film deposited on a substrate of inorganic material or organic material.
Claim 8
Dependent Claim 13 words
The device according to claim 6, wherein said substrate has an irregular surface.
Claim 9
Dependent Claim 130 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a heterojunction solar cell comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; a plurality of tandemly arranged amorphous solar cells applied on said heterojunction solar cell in optical and electrical series therewith, and each comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between associated p-, i-, and n-type regions and forming a p-n junction between each adjacent pair of amorphous solar cells, and a p-n junction formed at the interface between said heterojunction solar cell and the amorphous solar cell applied thereon.
Claim 10
Dependent Claim 130 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a heterojunction solar cell comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; a plurality of tandemly arranged amorphous solar cells applied on said heterojunction solar cell in optical and electrical series therewith, and each comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between associated p-, i-, and n-type regions and forming a p-n junction between each adjacent pair of amorphous solar cells, and a p-n junction formed at the interface between said heterojunction solar cell and the amorphous solar cell applied thereon.
Claim 11
Dependent Claim 44 words
The device according to claim 8, wherein said solar cells are placed from the light-receiving side in the order of increasing width of the energy gap of said i-type regions in said amorphous solar cells and said crystalline region in said heterojunction solar cell.
Claim 12
Dependent Claim 27 words
The device according to claim 8, wherein at least one of said amorphous or microcrystalline semiconductor regions is formed by the use of a low temperature process.
Claim 13
Dependent Claim 14 words
The device according to claim 8, wherein said crystalline semiconductor region comprises a wafer.
Claim 14
Dependent Claim 14 words
The device according to claim 11, wherein said crystalline region has an irregular surface.
Claim 15
Dependent Claim 25 words
The device according to claim 8, wherein said crystalline semiconductor region comprises a thin film deposited on a substrate of inorganic material or organic material.
Claim 16
Dependent Claim 13 words
The device according to claim 13, wherein said substrate has an irregular surface.
Claim 17
Dependent Claim 146 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: two tandemly arranged heterojunction solar cells in optical and electrical series each comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions, an intervening amorphous or microcrystalline semiconductor region applied between an amorphous or microcrystalline region in one of said solar cells and a crystalline region in the other cell, the conductivity type of said intervening region being controlled to be of opposite type to that of said amorphous or microcrystalline semiconductor region in one of said solar cells but of the same type as that of the crystalline region in the other cell, and a p-n junction formed at the interface between said intervening region and said amorphous or microcrystalline region in one of said solar cells.
Claim 18
Dependent Claim 146 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: two tandemly arranged heterojunction solar cells in optical and electrical series each comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions, an intervening amorphous or microcrystalline semiconductor region applied between an amorphous or microcrystalline region in one of said solar cells and a crystalline region in the other cell, the conductivity type of said intervening region being controlled to be of opposite type to that of said amorphous or microcrystalline semiconductor region in one of said solar cells but of the same type as that of the crystalline region in the other cell, and a p-n junction formed at the interface between said intervening region and said amorphous or microcrystalline region in one of said solar cells.
Claim 19
Dependent Claim 34 words
The device according to claim 15, wherein said solar cells are placed in order of decreasing width of the energy gap of said crystalline regions in said heterojunction solar cells from the light-receiving side.
Claim 20
Dependent Claim 24 words
The device according to claim 15, wherein at least one of said amorphous or microcrystalline regions is deposited by using a low temperature process.
Claim 21
Dependent Claim 30 words
The device according to claim 15, wherein the crystalline semiconductor region situated at the farthest side from the light-receiving surface among the semiconductor regions of said device comprises a wafer.
Claim 22
Dependent Claim 16 words
The device according to claim 18, wherein said last mentioned crystalline region has an irregular surface.
Claim 23
Dependent Claim 41 words
The device according to claim 18, wherein said crystalline semiconductor region situated at the farthest side from the light-receiving surface among the semiconductor regions of said device comprises a thin film deposited on a substrate of inorganic material or organic material.
Claim 24
Dependent Claim 13 words
The device according to claim 20, wherein said substrate has an irregular surface.
Claim 25
Dependent Claim 205 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a plurality of tandemly arranged heterojunction solar cells in optical and electrical series, each comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; an intervening amorphous or microcrystalline semiconductor region applied between an amorphous or microcrystalline semiconductor region in one of said heterojunction solar cells and a crystalline region in the adjacent heterojunction solar cell, the conductivity type of said intervening region being controlled to be of the opposite type to that of said amorphous or microcrystalline semiconductor region in one of said heterojunction solar cells but of the same type as that of the crystalline semiconductor region in the adjacent cell; at least one amorphous solar cell tandemly arranged on one of said plurality of heterojunction solar cells in optical and electrical series therewith, and each comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between associated regions, and a p-n junction formed at the interface between said heterojunction solar cell and the amorphous solar cell applied thereon.
Claim 26
Dependent Claim 205 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a plurality of tandemly arranged heterojunction solar cells in optical and electrical series, each comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; an intervening amorphous or microcrystalline semiconductor region applied between an amorphous or microcrystalline semiconductor region in one of said heterojunction solar cells and a crystalline region in the adjacent heterojunction solar cell, the conductivity type of said intervening region being controlled to be of the opposite type to that of said amorphous or microcrystalline semiconductor region in one of said heterojunction solar cells but of the same type as that of the crystalline semiconductor region in the adjacent cell; at least one amorphous solar cell tandemly arranged on one of said plurality of heterojunction solar cells in optical and electrical series therewith, and each comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between associated regions, and a p-n junction formed at the interface between said heterojunction solar cell and the amorphous solar cell applied thereon.
Claim 27
Dependent Claim 44 words
The device according to claim 22, wherein said solar cells are placed from the light-receiving side in the order of decreasing width of the energy gap of said i-type regions in said amorphous solar cells and said crystalline regions in said heterojunction solar cells.
Claim 28
Dependent Claim 26 words
The device according to claim 22, wherein at least one of said amorphous or microcrystalline regions is deposited by the use of a low temperature process.
Claim 29
Dependent Claim 28 words
The device according to claim 22, wherein the crystalline semiconductor region in the heterojunction solar cell situated at the farthest side from the light-receiving side comprises a wafer.
Claim 30
Dependent Claim 16 words
The device according to claim 25, wherein said last mentioned crystalline region has an irregular surface.
Claim 31
Dependent Claim 39 words
The device according to claim 22, wherein said crystalline semiconductor region in the heterojunction solar cell situated at the farthest side from the lightreceiving side comprises a thin film deposited on a substrate of inorganic material or organic material.
Claim 32
Dependent Claim 13 words
The device according to claim 27, wherein said substrate has an irregular surface.
Claim 33
Dependent Claim 202 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a plurality of tandemly arranged heterojunction solar cells in optical and electrical series, each comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; an intervening amorphous or microcrystalline semiconductor region applied between an amorphous or microcrystalline region in one of said heterojunction solar cells and a crystalline region in the adjacent heterojunction solar cell, the conductivity type of said intervening region being controlled to be of the opposite type to that of said amorphous or microcrystalline semiconductor region in one of said heterojunction solar cells but of the same type as that of the crystalline semiconductor region in the adjacent cell; a plurality of amorphous solar cells tandemly arranged on said heterojunction solar cells in optical and electrical series therewith, and each comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between associated regions, and a p-n junction formed at the interface between one of said heterojunction solar cells and the amorphous solar cell applied thereon.
Claim 34
Dependent Claim 202 words
A photovoltaic device which converts solar energy to electric energy, comprising, in combination: a plurality of tandemly arranged heterojunction solar cells in optical and electrical series, each comprising a crystalline semiconductor region and an amorphous or microcrystalline semiconductor region applied on said crystalline region with a p-n junction formed between said regions; an intervening amorphous or microcrystalline semiconductor region applied between an amorphous or microcrystalline region in one of said heterojunction solar cells and a crystalline region in the adjacent heterojunction solar cell, the conductivity type of said intervening region being controlled to be of the opposite type to that of said amorphous or microcrystalline semiconductor region in one of said heterojunction solar cells but of the same type as that of the crystalline semiconductor region in the adjacent cell; a plurality of amorphous solar cells tandemly arranged on said heterojunction solar cells in optical and electrical series therewith, and each comprising a p-type region, an i-type region and an n-type region of amorphous or microcrystalline semiconductor material applied in seriatim layers with a p-i-n junction formed between associated regions, and a p-n junction formed at the interface between one of said heterojunction solar cells and the amorphous solar cell applied thereon.
Claim 35
Dependent Claim 44 words
The device according to claim 29, wherein said solar cells are placed from the light-receiving side in the order of decreasing width of the energy gap of said i-type regions in said amorphous solar cells and said crystalline regions in said heterojunction solar cells.
Claim 36
Dependent Claim 26 words
The device according to claim 29, wherein at least one of said amorphous or microcrystalline regions is deposited by the use of a low temperature process.
Claim 37
Dependent Claim 28 words
The device according to claim 29, wherein said crystalline semiconductor region in the heterojunction solar cell situated at the farthest side from the light-receiving side comprises a wafer.
Claim 38
Dependent Claim 16 words
The device according to claim 32, wherein said last mentioned crystalline region has an irregular surface.
Claim 39
Dependent Claim 39 words
The device according to claim 29, wherein the crystalline semiconductor region in the heterojunction solar cell situated at the farthest side from the lightreceiving side comprises a thin film deposited on a substrate of inorganic material or organic material.
Claim 40
Dependent Claim 13 words
The device according to claim 34, wherein said substrate has an irregular surface.

References Cited (Backward Citations)

US4016586A Cited
US4271328A Cited
US4270018A Cited
US4253882A Cited
US4377723A Cited
US4292461A Cited
JPS5749278A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-29 1988-07-30 1989-01-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-29 1992-07-30 1993-01-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-29 1996-07-30 1997-01-29 $7700.00 Window Closed / Lapsed

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