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US4496610A Expired / Lapsed US ⏱️ 0.0 years remaining

Electroluminescent panels and method of manufacture

Assignee: UK Secretary of State for Defence
•
Filing: 1983-03-22
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Granted: 1985-01-29
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Expires: 2003-03-22
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Abstract

Abstract A method in which a phosphor film of manganese doped zinc chalcogenide is produced by chemical vapor deposition from alkyl zinc vapor and the gaseous hydride of the chalcogen. The manganese dopant is introduced uniformly during deposition by decomposition of tricarbonyl alkylcyclopentadienyl manganese: ##STR1## where here R denotes the alkyl radical. Preferably dimethyl zinc and tricarbonyl methylcyclopentadienyl manganese are used. The phosphor produced may be one of the following manganese doped compounds: zinc sulphide, zinc selenide, zinc sulphur selenide, zinc oxy-sulphide, zinc oxy-selenide or zinc cadmium sulphide.

Inventors

  • 👤 Alan F. Cattell
  • 👤 Brian Cockayne
  • 👤 Peter J. Wright
  • 👤 John Kirton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:19
CPC Classifications
H; H05; H05B; H05B33/00; H05B33/12; H05B33/14; H05B33/145

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 50 words
A method for the manufacture of an electroluminescent panel wherein manganese doped zinc chalcogenide phosphor film is grown by exposing a heated electrode bearing substrate to alkyl zinc vapour and a gaseous hydride of one of the chalcogen elements sulphur or selenium, in the presence of tricarbonyl alkylcyclopentadienyl manganese vapor.
Claim 2
Independent Claim 50 words
A method for the manufacture of an electroluminescent panel wherein manganese doped zinc chalcogenide phosphor film is grown by exposing a heated electrode bearing substrate to alkyl zinc vapour and a gaseous hydride of one of the chalcogen elements sulphur or selenium, in the presence of tricarbonyl alkylcyclopentadienyl manganese vapor.
Claim 3
Independent Claim 14 words
A method as claimed in the preceding claim wherein tricarbonyl methylcyclopentadienyl manganese is used.
Claim 4
Dependent Claim 12 words
A method as claimed in claim 1 wherein dimethyl zinc is used.
Claim 5
Dependent Claim 13 words
A method as claimed in claim 1 wherein gaseous hydrogen sulphide is used.
Claim 6
Dependent Claim 13 words
A method as claimed in claim 1 wherein gaseous hydrogen selenide is used.
Claim 7
Dependent Claim 19 words
A method as claimed in claim 1 wherein an admixture of gaseous hydrogen sulphide and hydrogen selenide is used.
Claim 8
Independent Claim 49 words
A method for the manufacture of an electroluminescent panel wherein manganese doped zinc sulphide phosphor film is grown by exposing an electrode bearing substrate, heated to a temperature in excess of 350° C., to dimethyl zinc vapour and gaseous hydrogen sulphide in the presence of tricarbonyl methylcyclopentadienyl manganese vapour.
Claim 9
Independent Claim 49 words
A method for the manufacture of an electroluminescent panel wherein manganese doped zinc sulphide phosphor film is grown by exposing an electrode bearing substrate, heated to a temperature in excess of 350° C., to dimethyl zinc vapour and gaseous hydrogen sulphide in the presence of tricarbonyl methylcyclopentadienyl manganese vapour.

References Cited (Backward Citations)

GB1300548A Cited
DE2432503A1 Cited
US4181753A Cited
GB1571620A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-29 1988-07-30 1989-01-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-29 1992-07-30 1993-01-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-29 1996-07-30 1997-01-29 $7700.00 Window Closed / Lapsed

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