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US4496468A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrated hydroxyethyl cellulose compositions

Assignee: Baroid Technology Inc
•
Filing: 1982-03-29
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Granted: 1985-01-29
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Expires: 2002-03-29
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Abstract

Abstract A method of activating hydroxyethyl cellulose (HEC) such that the HEC will hydrate in heavy brines having a density greater than about 13.5 pounds per gallon at ambient temperature, the activated HEC compositions so produced, and viscous well servicing compositions wherein an oleaginous liquid and a compatiblizing agent are admixed to form a viscous slurry, admixing therewith an aqueous solution of an inorganic salt which has an exothermic heat of solution, and thereafter admixing HEC therewith to form a viscous pourable composition.

Inventors

  • 👤 Roy F. House
  • 👤 Lonnie D. Hoover

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 21:02
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/02; C09K8/03; C09K8/035; C08; C08L; C08L1/00; C08L1/08; C08L1/26; C08L1/28; C08L1/284; Y; Y10; Y10S; Y10S507/00; Y10S507/925; Y10S507/926

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 164 words
A viscosifying composition which will hydrate in and viscosify heavy brines having a density greater than about 13.5 ppg at ambient temperature which consists essentially of from about 35% to about 55% by weight of an oleaginous liquid which is a liquid aliphatic or aromatic hydrocarbon, from about 0.25% to about 3% by weight based on said oleaginous liquid of a compatibilizing agent comprising an organophilic clay, from about 15% to about 55% of an aqueous phase comprising water and an inorganic salt which has exothermic heat of solution wherein the concentration of said inorganic salt is greater than about 10% by weight of said aqueous phase, from about 10% to about 30% by weight of hydroxyethyl cellulose, and from about 20% to about 40% by weight, based on the weight of said organophilic clay, of a dispersant selected from the class consisting of aliphatic alcohols having from 1 to 2 carbon atom ketones having from 2 to 5 carbon atoms, and mixtures thereof.
Claim 2
Dependent Claim 164 words
A viscosifying composition which will hydrate in and viscosify heavy brines having a density greater than about 13.5 ppg at ambient temperature which consists essentially of from about 35% to about 55% by weight of an oleaginous liquid which is a liquid aliphatic or aromatic hydrocarbon, from about 0.25% to about 3% by weight based on said oleaginous liquid of a compatibilizing agent comprising an organophilic clay, from about 15% to about 55% of an aqueous phase comprising water and an inorganic salt which has exothermic heat of solution wherein the concentration of said inorganic salt is greater than about 10% by weight of said aqueous phase, from about 10% to about 30% by weight of hydroxyethyl cellulose, and from about 20% to about 40% by weight, based on the weight of said organophilic clay, of a dispersant selected from the class consisting of aliphatic alcohols having from 1 to 2 carbon atom ketones having from 2 to 5 carbon atoms, and mixtures thereof.
Claim 3
Dependent Claim 81 words
The composition of claim 1 containing from about 15% to about 25% by weight hydroxyethyl cellulose, from about 40% to about 50% by weight of said oleaginous liquid, from about 25% to about 45% of an aqueous phase comprising said water and said inorganic salt wherein the concentration of said inorganic salt is greater than about 20% by weight of said aqueous phase, and from about 0.5% to about 2% by weight based on said oleaginous liquid of said compatiblizing agent.
Claim 4
Dependent Claim 20 words
The composition of claim 1, or 3 which has been heated to a temperature of at least about 150° F.
Claim 5
Dependent Claim 19 words
The composition of claim 3 wherein said temperature results from the solution of said inorganic salt in said water.
Claim 6
Dependent Claim 52 words
A well servicing fluid comprising a heavy brine having a density greater than about 13.5 pounds per gallon containing a soluble salt selected from the group consisting of calcium chloride, calcium bromide, zinc bromide, and mixtures thereof, and a viscosifying amount of the viscosifying composition of claim 1, 2, 3, or 4.
Claim 7
Independent Claim 195 words
A method of activating hydroxyethyl cellulose, such that said hydroxyethyl cellulose will hydrate in heavy brines having a density greater than about 13.5 ppg at ambient temperatures which comprises admixing from about 35% to about 55% of an oleaginous liquid which is a liquid aliphatic or aromatic hydrocarbon, from about 0.25% to about 3% by weight based on said oleaginous liquid of a compatibilizing agent comprising an organophilic clay, and from 20% to about 40% by weight, based on the weight of said organophilic clay, of a dispersant selected from the class consisting of aliphatic alcohols having from 1 to 2 carbon atom ketones having from 2 to 5 carbon atoms, and mixtures thereof, together to form a viscous slurry, admixing therewith from about 15% to about 55% of an aqueous phase comprising water and an inorganic salt which has an exothermic heat of solution, wherein the concentration of said inorganic salt is greater than about 10% by weight of said aqueous phase, said water being added first followed by the addition of said inorganic salt, and thereafter admixing from about 10% to about 30% by weight hydroxyethyl cellulose to form a viscous pourable composition.
Claim 8
Independent Claim 195 words
A method of activating hydroxyethyl cellulose, such that said hydroxyethyl cellulose will hydrate in heavy brines having a density greater than about 13.5 ppg at ambient temperatures which comprises admixing from about 35% to about 55% of an oleaginous liquid which is a liquid aliphatic or aromatic hydrocarbon, from about 0.25% to about 3% by weight based on said oleaginous liquid of a compatibilizing agent comprising an organophilic clay, and from 20% to about 40% by weight, based on the weight of said organophilic clay, of a dispersant selected from the class consisting of aliphatic alcohols having from 1 to 2 carbon atom ketones having from 2 to 5 carbon atoms, and mixtures thereof, together to form a viscous slurry, admixing therewith from about 15% to about 55% of an aqueous phase comprising water and an inorganic salt which has an exothermic heat of solution, wherein the concentration of said inorganic salt is greater than about 10% by weight of said aqueous phase, said water being added first followed by the addition of said inorganic salt, and thereafter admixing from about 10% to about 30% by weight hydroxyethyl cellulose to form a viscous pourable composition.
Claim 9
Dependent Claim 86 words
The method of claim 6 wherein said viscous pourable composition contains from about 15% to about 25% by weight hydroxyethyl cellulose, from about 40% to about 50% by weight of said oleaginous liquid, from about 25% to about 45% of an aqueous phase comprising said water and said inorganic salt wherein the concentration of said inorganic salt is greater than about 20% by weight of said aqueous phase, and from about 0.5% to about 2% by weight based on said oleaginous liquid of said compatiblizing agent.
Claim 10
Dependent Claim 22 words
The method of claim 6, or 7 additionally comprising heating said viscous pourable composition to a temperature of at least 150° F.
Claim 11
Dependent Claim 19 words
The method of claim 8 wherein said temperature results from the solution of said inorganic salt in said water.
Claim 12
Dependent Claim 57 words
A well servicing fluid comprising a heavy brine having a density greater than about 13.5 pounds per gallon containing a soluble salt selected from the group consisting of calcium chloride, calcium bromide, zinc bromide, and mixtures thereof and a viscosifying amount of the viscous pourable composition prepared by the method of claim 6, 7, 8, or 9.

References Cited (Backward Citations)

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GB2000799A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-29 1988-07-30 1989-01-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-29 1992-07-30 1993-01-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-29 1996-07-30 1997-01-29 $7700.00 Window Closed / Lapsed

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