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US4495243A Expired / Lapsed US ⏱️ 0.0 years remaining

Release agent and product

Assignee: Sekisui Chemical Co Ltd
•
Filing: 1980-08-21
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Granted: 1985-01-22
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Expires: 2000-08-21
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Abstract

Abstract A release agent comprising (A) a polymer of at least one vinyl monomer of the general formula CH2=CR1COO(CH2CHR2O)nCONHR (I) wherein R1 and R2, independently from each other, represent hydrogen or a methyl group, R represents an alkyl group having at least 12 carbon atoms or a fluoroalkyl group having at least 6 carbon atoms, and n is an integer of from 1 to 6, (B) a copolymer of at least one vinyl monomer of general formula (I) above and another compound copolymerizable therewith, or a mixture of said polymer (A) and said copolymer (B); and a product prepared by coating the said release agent on a non-adhesive surface of an adhesive article having an adhesive surface and the non-adhesive surface or on the surface of a release paper.

Inventors

  • 👤 Takaji Kishi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 20:43
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/14; C09J; C09J7/00; C09J7/20; C09J7/201; C09J7/22; C09J7/40; C09J7/401; C08; C08L; C08L2205/00; C08L2205/02; C08L33/00; C08L33/04; C08L33/14; C09J2400/00; C09J2400/20; C09J2400/28; C09J2400/283; C09J2423/00; C09J2423/005; C09J2433/00; C09J2433/005; C09J2451/00; C09J2451/005; C09J2475/00; C09J2475/005; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2839; Y10T428/2848; Y10T428/31504; Y10T428/31551; Y10T428/31565; Y10T428/31591

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 223 words
A release agent comprising: (A) a polymer of at least one vinyl monomer of the formula CH.sub.2 ═CR.sub.1 COO(CH.sub.2 CHR.sub.2 O).sub.n CONHR (I) wherein R 1 and R 2 , independently from each other, represent hydrogen or a methyl group, R represents an alkyl group having at least 12 carbon atoms or a fluoroalkyl group having at least 6 carbon atoms, and n is an integer of from 1 to 6, said vinyl monomer of formula (I) being an adduct of a compound of the following formula CH.sub.2 ═CR.sub.1 COO(CH.sub.2 CHR.sub.2 O).sub.n H (II) wherein R 1 , R 2 and n are as defined above, with a compound of the following formula RNCO (III) wherein R is as defined above, (B) a copolymer of at least one vinyl monomer of general formula (I) above and at least one other monomer selected from the group consisting of stearyl acrylate, stearyl methacrylate, stearyl acrylamide, stearyl methacrylamide, vinyl stearate, stearyl vinyl ether, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, vinyl acetate, styrene, 2-hydroxyethyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, diethylene glycol monomethacrylate, tetraethylene glycol monomethacrylate, polypropylene glycol monomethacrylate, acrylic acid, methacrylic acid, monoesters of maleic acid, monoesters of itaconic acid, crotonic acid, maleic anhydride, glycidyl methacrylate acrylonitrile, methyl vinyl ketone, and N-vinyl pyrrolidone, or (C) a mixture of said polymer (A) and said copolymer (B).
Claim 2
Dependent Claim 223 words
A release agent comprising: (A) a polymer of at least one vinyl monomer of the formula CH.sub.2 ═CR.sub.1 COO(CH.sub.2 CHR.sub.2 O).sub.n CONHR (I) wherein R 1 and R 2 , independently from each other, represent hydrogen or a methyl group, R represents an alkyl group having at least 12 carbon atoms or a fluoroalkyl group having at least 6 carbon atoms, and n is an integer of from 1 to 6, said vinyl monomer of formula (I) being an adduct of a compound of the following formula CH.sub.2 ═CR.sub.1 COO(CH.sub.2 CHR.sub.2 O).sub.n H (II) wherein R 1 , R 2 and n are as defined above, with a compound of the following formula RNCO (III) wherein R is as defined above, (B) a copolymer of at least one vinyl monomer of general formula (I) above and at least one other monomer selected from the group consisting of stearyl acrylate, stearyl methacrylate, stearyl acrylamide, stearyl methacrylamide, vinyl stearate, stearyl vinyl ether, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, vinyl acetate, styrene, 2-hydroxyethyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, diethylene glycol monomethacrylate, tetraethylene glycol monomethacrylate, polypropylene glycol monomethacrylate, acrylic acid, methacrylic acid, monoesters of maleic acid, monoesters of itaconic acid, crotonic acid, maleic anhydride, glycidyl methacrylate acrylonitrile, methyl vinyl ketone, and N-vinyl pyrrolidone, or (C) a mixture of said polymer (A) and said copolymer (B).
Claim 3
Dependent Claim 18 words
A product prepared by coating the release agent of claim 1 on the surface of a release paper.
Claim 4
Dependent Claim 18 words
The release agent of claim 1 wherein said polymer (A) is a homopolymer of said vinyl monomer (I).
Claim 5
Dependent Claim 25 words
The release agent of claim 1 wherein said polymer (A) is a copolymer of at least two of said vinyl monomers of general formula (I).
Claim 6
Dependent Claim 27 words
A product prepared by coating the release agent of claim 1 on a non-adhesive surface of an adhesive article having an adhesive surface and the non-adhesive surface.
Claim 7
Dependent Claim 36 words
The release agent of claim 1 wherein the copolymer (B) is derived from at least 40% by weight of said vinyl monomer of general formula (I) and at most 60% by weight of said other monomer.
Claim 8
Dependent Claim 15 words
The release agent of claim 8 wherein said trunk polymer itself has a release action.
Claim 9
Dependent Claim 30 words
The release agent of claim 1 wherein said copolymer (B) is a graft copolymer resulting from graft copolymerization of said vinyl monomer of general formula (I) with a trunk polymer.

References Cited (Backward Citations)

US2816655A Cited
US2822290A Cited
US2876894A Cited
GB864483A Cited
US3051588A Cited
US3052566A Cited
US4241198A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-22 1988-07-23 1989-01-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-22 1992-07-23 1993-01-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-22 1996-07-23 1997-01-22 $7700.00 Window Closed / Lapsed

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