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US4495211A
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Process for the decaffeination of green coffee beans
Assignee: Douwe Egberts Koninklijke Tabaksfabriek Koffiebranderijen Theehandel NV
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Filing: 1982-10-14
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Granted: 1985-01-22
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Expires: 2002-10-14
Abstract
Abstract A process for the decaffeination of green coffee beans by the extraction, in process stage (a), of soaked green coffee beans with an equilibrium extract of coffee beans, from which extract caffeine has been removed, resulting in caffeine-deficient beans, which are recovered, and an equilibrium extract of the beans, which in a series of successive process stages (b), (c), (d) and (e), is contacted with an adsorbent circulating counter-currently through the same process steps, said adsorbent having a preferential adsorption capacity for caffeine. The equilibrium extract from stage (a) together with solution from stage (e) are contacted in stage (b) with adsorbent from stage (c) with adsorption of caffeine from the solution. The resulting solution is partly returned to stage (a), and partly, in stage (e), contacted with "clean" adsorbent from stage (d). The resulting "clean" solution is contacted, in stage (d) with adsorbent from stage (e) with desorption of caffeine from said adsorbent. The resulting caffeine-rich solution is partly recovered and partly, in stage (e), contacted with adsorbent from stage (b).
Inventors
- 👤 Gerben D. Mooiweer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:36
CPC Classifications
B; B01; B01D; B01D15/00; B01D15/02; A; A23; A23F; A23F5/00; A23F5/16; A23F5/18; A23F5/185; A23F5/20; A23F5/208; A23F5/22; A23F5/223
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
344 words
A continuous process for the decaffeination of green coffee beans, comprising the following integrated process stages: (a) contacting the green coffee beans after soaking in water with a caffeine-deficient aqueous solution from stage (b), being an equilibrium extract of these beans from which caffeine has been withdrawn, resulting in caffeine-deficient beans on the one hand and an equilibrium extract of the beans on the other; (b) contacting the equilibrium extract of the green coffee beans, produced in stage (a) together with the solution of coffee bean components, produced in stage (e), with a caffeine-deficient adsorbent loaded with non-caffeine coffee bean components, and loaded adsorbent being produced in stage (c) and having a preferential adsorption capacity for caffeine, resulting, on the one hand, in a caffeine-deficient solution of coffee bean components, which solution is concentrated by evaporation, the distillate being condensed and returned to stage (d) while the concentrate is partially passed to stage (c) and partially recycled to stage (a), and, on the other hand, an adsorbent loaded with coffee bean components, which loaded adsorbent is supplied to stage (e); (c) contacting the caffeine-deficient solution of coffee bean components, produced in stage (b), with clean adsorbent, resulting, on the one hand, in a clean aqueous solution and, on the other, in an adsorbent loaded with soluble coffee bean components, but deficient in caffeine, which loaded adsorbent is supplied to stage (b); (d) contacting the clean aqueous solution produced in stage (c) with the adsorbent loaded with coffee bean components rich in caffeine, which solution is concentrated by evaporation, the distillate being condensed and returned to stage (d) while the concentrate is partially discharged and partially supplied to stage (e); (e) contacting the caffeine-rich solution of coffee bean components from stage (d) with the adsorbent loaded with soluble coffee bean components from stage (b), resulting, on the one hand, in a solution of coffee bean components, which is supplied to stage (b), and on the other hand, in an adsorbent loaded with soluble coffee bean components rich in caffeine, which is supplied to stage (d).
Claim 2
Dependent Claim
344 words
A continuous process for the decaffeination of green coffee beans, comprising the following integrated process stages: (a) contacting the green coffee beans after soaking in water with a caffeine-deficient aqueous solution from stage (b), being an equilibrium extract of these beans from which caffeine has been withdrawn, resulting in caffeine-deficient beans on the one hand and an equilibrium extract of the beans on the other; (b) contacting the equilibrium extract of the green coffee beans, produced in stage (a) together with the solution of coffee bean components, produced in stage (e), with a caffeine-deficient adsorbent loaded with non-caffeine coffee bean components, and loaded adsorbent being produced in stage (c) and having a preferential adsorption capacity for caffeine, resulting, on the one hand, in a caffeine-deficient solution of coffee bean components, which solution is concentrated by evaporation, the distillate being condensed and returned to stage (d) while the concentrate is partially passed to stage (c) and partially recycled to stage (a), and, on the other hand, an adsorbent loaded with coffee bean components, which loaded adsorbent is supplied to stage (e); (c) contacting the caffeine-deficient solution of coffee bean components, produced in stage (b), with clean adsorbent, resulting, on the one hand, in a clean aqueous solution and, on the other, in an adsorbent loaded with soluble coffee bean components, but deficient in caffeine, which loaded adsorbent is supplied to stage (b); (d) contacting the clean aqueous solution produced in stage (c) with the adsorbent loaded with coffee bean components rich in caffeine, which solution is concentrated by evaporation, the distillate being condensed and returned to stage (d) while the concentrate is partially discharged and partially supplied to stage (e); (e) contacting the caffeine-rich solution of coffee bean components from stage (d) with the adsorbent loaded with soluble coffee bean components from stage (b), resulting, on the one hand, in a solution of coffee bean components, which is supplied to stage (b), and on the other hand, in an adsorbent loaded with soluble coffee bean components rich in caffeine, which is supplied to stage (d).
Claim 3
Dependent Claim
64 words
A process according to claim 1, wherein the caffeine-rich solution produced in stage (d) is concentrated by evaporation prior to being supplied to stage (e), the distillate is condensed and returned to stage (d), and the portion of the caffeine-deficient solution rich in chlorogenic acid, produced in stage (b) and supplied to stage (c) is concentrated by evaporation before being supplied to stage (c).
Claim 4
Dependent Claim
84 words
A process according to claim 2, wherein, in stage (d), for the desorption of the caffeine-rich adsorbent from stage (e), a mixture of water and a water-miscible organic solvent having a lower boiling point than water and having a higher affinity to caffeine than has pure water, separating from the caffeine-rich solution produced with this mixture a caffeine-rich aqueous solution by means of fractionated distillation, and discharging a portion of said caffeine-rich aqueous solution as a product and passing another portion to stage (e).
Claim 5
Dependent Claim
24 words
A process according to claim 3, wherein a mixture of alcohol and water is used for the desorption of the adsorbent in stage (d).
Claim 6
Dependent Claim
22 words
A process according to claim 4, wherein the mixture used for the desorption in stage (d) comprises 60-70% water and 40-30% alcohol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-01-22 | 1988-07-23 | 1989-01-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-01-22 | 1992-07-23 | 1993-01-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-01-22 | 1996-07-23 | 1997-01-22 | $7700.00 | Window Closed / Lapsed |