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US4494606A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for improving vertical conformance in a near well bore environment

Assignee: Marathon Oil Co
•
Filing: 1983-05-19
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Granted: 1985-01-22
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Expires: 2003-05-19
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Abstract

Abstract An aqueous solution containing a high molecular weight organic polymer and an aqueous solution containing a cross-linking agent are sequentially injected into the near well bore environment of a subterranean formation interposed by a hydrocarbon spacer. The spacer causes the two aqueous solutions to mix in the near well bore environment and a gel is formed which preferentially plugs the relatively highly permeable zones in the near well bore environment thereby improving conformance and flow profiles of fluids subsequently injected into or produced from the formation.

Inventors

  • 👤 Robert D. Sydansk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:55
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/60; C09K8/84; C09K8/86; C09K8/88; C09K8/887; C09K8/50; C09K8/504; C09K8/506; C09K8/508; C09K8/512

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 214 words
A process for substantially plugging at least one zone of relatively high permeability in a near well bore environment of a subterranean formation penetrated by a well bore in fluid communication therewith, said formation having said at least one zone of relatively high permeability and at least one zone of relatively low permeability, the process comprising the steps of: (a) injecting an aqueous solution containing an organic polymer capable of being cross linked by a cross-linking agent into said near well bore environment via said well bore; (b) injecting a hydrocarbon spacer between said solution containing said polymer and an aqueous solution containing said cross-linking agent into said near well bore environment via said well bore in an amount sufficient to delay mixing of said solutions containing said polymer and said cross-linking agent until said solutions are in said near well bore environment; (c) injecting said solution containing said cross-linking agent into said near well bore environment via said well bore; and (d) reacting said polymer and said cross-linking agent upon said mixing to form a gel preferentially and predominantly within said at least one zone of relatively high permeability in said near well bore environment, which substantially plugs said at least one zone of relatively high permeability in said near well bore environment.
Claim 2
Dependent Claim 214 words
A process for substantially plugging at least one zone of relatively high permeability in a near well bore environment of a subterranean formation penetrated by a well bore in fluid communication therewith, said formation having said at least one zone of relatively high permeability and at least one zone of relatively low permeability, the process comprising the steps of: (a) injecting an aqueous solution containing an organic polymer capable of being cross linked by a cross-linking agent into said near well bore environment via said well bore; (b) injecting a hydrocarbon spacer between said solution containing said polymer and an aqueous solution containing said cross-linking agent into said near well bore environment via said well bore in an amount sufficient to delay mixing of said solutions containing said polymer and said cross-linking agent until said solutions are in said near well bore environment; (c) injecting said solution containing said cross-linking agent into said near well bore environment via said well bore; and (d) reacting said polymer and said cross-linking agent upon said mixing to form a gel preferentially and predominantly within said at least one zone of relatively high permeability in said near well bore environment, which substantially plugs said at least one zone of relatively high permeability in said near well bore environment.
Claim 3
Dependent Claim 13 words
The process of claim 1 wherein said organic polymer is partially hydrolyzed polyacrylamide.
Claim 4
Dependent Claim 12 words
The process of claim 1 wherein said organic polymer is a biopolymer.
Claim 5
Dependent Claim 13 words
The process of claim 1 wherein said cross-linking agent is a polyvalent cation.
Claim 6
Dependent Claim 25 words
The process of claim 4 wherein said polyvalent cation is a trivalent cation selected from the group consisting of ions of chromium, iron, and aluminum.
Claim 7
Dependent Claim 18 words
The process of claim 1 wherein said acrylamide solution containing said organic polymer also contains an inert additive.
Claim 8
Dependent Claim 19 words
The process of claim 6 wherein said inert additive is selected from the group consisting of silicas and silicates.
Claim 9
Dependent Claim 20 words
The process of claim 1 wherein said liquid hydrocarbon spacer is unreactive with said organic polymer and said cross-linking agent.
Claim 10
Dependent Claim 22 words
The process of claim 8 wherein said hydrocarbon spacer is selected from the group consisting of alkanes, alkenes, aromatics and mixtures thereof.
Claim 11
Dependent Claim 31 words
The process of claim 1 wherein at least one zone of relatively high permeability is isolated by a mechanical zone isolation means prior to injecting said aqueous solutions and hydrocarbon spacer.
Claim 12
Dependent Claim 30 words
The process of claim 10 wherein said at least one zone of relatively high permeability is not in fluid communication with said at least one zone of relatively low permeability.
Claim 13
Dependent Claim 22 words
The process of claim 1 wherein said zone of relatively high permeability is vertically juxtaposed to said zone of relatively low permeability.
Claim 14
Dependent Claim 20 words
The process of claim 1 wherein the injection sequence of steps (a), (b) and (c) is repeated at least once.
Claim 15
Dependent Claim 24 words
The process of claim 13 wherein said hydrocarbon spacer is injected into said near well bore environment between each repetition of said injection sequence.
Claim 16
Dependent Claim 14 words
The process of claim 1 wherein said subterranean formation is a subterranean hydrocarbon-bearing formation.

References Cited (Backward Citations)

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US3909423A Cited
US3765484A Cited
US3785437A Cited
US4120361A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1988-01-22 1988-07-23 1989-01-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1992-01-22 1992-07-23 1993-01-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1996-01-22 1996-07-23 1997-01-22 $7700.00 Window Closed / Lapsed

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