US4491461A
Expired / Lapsed
US
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Method of desulfurization of flue gases
Assignee: Individual
•
Filing: 1983-05-17
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Granted: 1985-01-01
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Expires: 2003-05-17
Abstract
Abstract Preliminarily cooled flue gases from which particulates and sulfur trioxide have been removed are contacted with an SO 2 absorbing liquid and the SO 2 laden liquid is then regenerated by multi-stage vacuum stripping and returned in a closed cycle to the absorber. The absorbing liquid contains an additive and is a dilute solution of, preferably, calcium ions in water. The additive is added in minor amount sufficient to provide a partial pressure of SO 2 in the absorber equivalent to the partial pressure of SO 2 in water in the temperature range of about 15° C. to -20° C. The preliminarily cooled gas is at a temperature in the order of 125° F. The heat removed from the closed cycle by vacuum stripping is substantially equal to the heat given up by the flue gas in the absorber, and the temperature difference between the liquid on entering and leaving the desorber is in the order of 10°-30° F.
Inventors
- 👤 Irenus A. Hoekstra
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 22:43
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501; Y; Y10; Y10S; Y10S62/00; Y10S62/922
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
234 words
The method of significantly reducing the sulfur oxides content of flue gases, which comprises the steps of: (a) cooling the flue gases to a temperature in the order of about 125° F. while removing particulates and sulfur-trioxides therefrom; (b) absorbing a major part of the SO 2 content of the cooled flue gases by circulating, in a closed system, an absorbing liquid which is contacted with the flue gases to effect the absorption of SO 2 , said absorbing liquid being a dilute solution in water of an additive capable of decreasing the partial pressure of SO 2 in the liquid at a temperature of the liquid leaving the absorber which is equivalent to the partial pressure of SO 2 in water at a temperature in the range of about 15° C. to about -20° C; (c) desorbing SO 2 from the absorbing liquid by subjecting the liquid to multi-stage vacuum stripping; (d) condensing the steam and vapor stripped in step (c) to recover SO 2 ; and (e) controlling the flow rate of absorbing liquid in said closed system and the rate of desorption of step (c) such that the quantity of heat removed by stripping is substantially equal to the heat given up by the flue gases in step (b) while the temperature difference between the absorbing liquid before and after absorption of SO 2 is in the order of 10°-30° F.
Claim 2
Independent Claim
234 words
The method of significantly reducing the sulfur oxides content of flue gases, which comprises the steps of: (a) cooling the flue gases to a temperature in the order of about 125° F. while removing particulates and sulfur-trioxides therefrom; (b) absorbing a major part of the SO 2 content of the cooled flue gases by circulating, in a closed system, an absorbing liquid which is contacted with the flue gases to effect the absorption of SO 2 , said absorbing liquid being a dilute solution in water of an additive capable of decreasing the partial pressure of SO 2 in the liquid at a temperature of the liquid leaving the absorber which is equivalent to the partial pressure of SO 2 in water at a temperature in the range of about 15° C. to about -20° C; (c) desorbing SO 2 from the absorbing liquid by subjecting the liquid to multi-stage vacuum stripping; (d) condensing the steam and vapor stripped in step (c) to recover SO 2 ; and (e) controlling the flow rate of absorbing liquid in said closed system and the rate of desorption of step (c) such that the quantity of heat removed by stripping is substantially equal to the heat given up by the flue gases in step (b) while the temperature difference between the absorbing liquid before and after absorption of SO 2 is in the order of 10°-30° F.
Claim 3
Dependent Claim
29 words
The method as defined in claim 1 wherein the additive is an alkaline metal salt and the absorbing liquid contains less than 1% of ionized electrolyte ions in solution.
Claim 4
Dependent Claim
14 words
The method as defined in claim 2 wherein the additive is limestone or dolomite.
Claim 5
Dependent Claim
14 words
The method as defined in claim 1 wherein the additive is limestone or dolomite.
Claim 6
Dependent Claim
24 words
The method as defined in claim 1 wherein the temperature of the flue gases exiting the absorber is in the order of 95° F.
Claim 7
Dependent Claim
29 words
The method as defined in claim 5 wherein the additive is an alkaline metal salt and the absorbing liquid contains less than 1% of ionized electrolyte ions in solution.
Claim 8
Dependent Claim
14 words
The method as defined in claim 6 wherein the additive is limestone or dolomite.
Claim 9
Dependent Claim
14 words
The method as defined in claim 5 wherein the additive is limestone or dolomite.
Claim 10
Dependent Claim
24 words
The method as defined in claim 1 wherein the temperature of the absorbing liquid leaving the desorber is in the order of 85° F.
Claim 11
Dependent Claim
29 words
The method as defined in claim 9 wherein the additive is an alkaline metal salt and the absorbing liquid contains less than 1% of ionized electrolyte ions in solution.
Claim 12
Dependent Claim
14 words
The method as defined in claim 9 wherein the additive is limestone or dolomite.
Claim 13
Dependent Claim
14 words
The method as defined in claim 11 wherein the additive is limestone or dolomite.
Claim 14
Dependent Claim
24 words
The method as defined in claim 9 wherein the temperature of the flue gases exiting the absorber is in the order of 95° F.
Claim 15
Dependent Claim
29 words
The method as defined in claim 13 wherein the additive is an alkaline metal salt and the absorbing liquid contains less than 1% of ionized electrolyte ions in solution.
Claim 16
Dependent Claim
14 words
The method as defined in claim 13 wherein the additive is limestone or dolomite.
Claim 17
Dependent Claim
14 words
The method as defined in claim 15 wherein the additive is limestone or dolomite.
Claim 18
Independent Claim
225 words
The method of significantly reducing the sulfur oxides content of flue gases, which comprises the steps of: (a) cooling the flue gases while removing particulates and sulfur-trioxides therefrom; (b) absorbing a major part of the SO 2 content of the cooled flue gases by circulating, in a closed system, an absorbing liquid which is contacted with the flue gases to effect the absorption of SO 2 , said absorbing liquid being a dilute solution in water of an additive capable of decreasing the partial pressure of SO 2 in the liquid at the temperature of the liquid leaving the absorber which is equivalent to the partial pressure of SO 2 in water at a temperature in the range of about 15° C. to about -20° C.; (c) desorbing SO 2 from the absorbing liquid by subjecting the liquid to multi-stage vacuum stripping; (d) condensing the steam and vapor stripped in step (c) to recover SO 2 ; and (e) controlling the flow rate of absorbing liquid in said closed system and the rate of desorption of step (c) such that the quantity of heat removed by stripping is substantially equal to the heat given up by the flue gases in step (b) while the temperature difference between the absorbing liquid before and after absorption of SO 2 is in the order of about 10°-30° F.
Claim 19
Independent Claim
225 words
The method of significantly reducing the sulfur oxides content of flue gases, which comprises the steps of: (a) cooling the flue gases while removing particulates and sulfur-trioxides therefrom; (b) absorbing a major part of the SO 2 content of the cooled flue gases by circulating, in a closed system, an absorbing liquid which is contacted with the flue gases to effect the absorption of SO 2 , said absorbing liquid being a dilute solution in water of an additive capable of decreasing the partial pressure of SO 2 in the liquid at the temperature of the liquid leaving the absorber which is equivalent to the partial pressure of SO 2 in water at a temperature in the range of about 15° C. to about -20° C.; (c) desorbing SO 2 from the absorbing liquid by subjecting the liquid to multi-stage vacuum stripping; (d) condensing the steam and vapor stripped in step (c) to recover SO 2 ; and (e) controlling the flow rate of absorbing liquid in said closed system and the rate of desorption of step (c) such that the quantity of heat removed by stripping is substantially equal to the heat given up by the flue gases in step (b) while the temperature difference between the absorbing liquid before and after absorption of SO 2 is in the order of about 10°-30° F.
Claim 20
Dependent Claim
29 words
The method as defined in claim 17 wherein the additive is an alkaline metal salt and the absorbing liquid contains less than 1% of ionized electrolyte ions in solution.
Claim 21
Dependent Claim
14 words
The method as defined in claim 18 wherein the additive is limestone or dolomite.
Claim 22
Dependent Claim
14 words
The method as defined in claim 17 wherein the additive is limestone or dolomite.
References Cited (Backward Citations)
US4189309A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-01-01 | 1988-07-02 | 1989-01-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-01-01 | 1992-07-02 | 1993-01-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-01-01 | 1996-07-02 | 1997-01-01 | $7700.00 | Window Closed / Lapsed |