US4485046A
Expired / Lapsed
US
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Production of cupric and manganous alkanoates
Assignee: Celanese International Corp
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Filing: 1982-09-28
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Granted: 1984-11-27
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Expires: 2002-09-28
Abstract
Abstract A process for the production of cupric and manganous alkanoates containing from 6 to 9 carbon atoms is described. This process comprises first thermally decomposing a mixture of cupric and manganous oxalates, obtained from the oxidation of C 6 to C 9 aldehydes to the corresponding acids using a mixture of copper and manganese compounds soluble in the acid product as the catalyst, in the presence of an organic saturated aliphatic monocarboxylic acid containing from 6 to 9 carbon atoms, and in the absence of oxygen, to produce manganous alkanoate and metallic copper. The metallic copper is then oxidized with oxygen to copper in the cupric form, which reacts with the organic saturated aliphatic monocarboxylic acid present to produce cupric alkanoate. The mixtures of cupric and manganous alkanoates obtained can be used as oxidation catalysts, and in fact may be recycled to the reaction sphere in which the C 6 -C 9 saturated aliphatic aldehydes are oxidized to the corresponding monocarboxylic acids for use as catalysts therein.
Inventors
- 👤 Olan S. Fruchey
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 14:04
CPC Classifications
C; C11; C11C; C11C1/00; C07; C07C; C07C51/00; C07C51/16; C07C51/21; C07C51/23; C07C51/235; C07C51/41; C07C51/412
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
94 words
A process for producing a mixture of cupric and manganous alkanoates containing from 6 to 9 carbon atoms comprising (1) thermally decomposing a mixture of cupric oxalate and manganous oxalate in the presence of an organic saturated aliphatic monocarboxylic acid containing from 6 to 9 carbon atoms in the absence of oxygen, producing the corresponding manganous alkanoate in admixture with metallic copper, (2) oxidizing said metallic copper to the cupric form in the presence of oxygen, and (3) reacting said copper in the cupric form with said acid to produce the corresponding cupric alkanoate.
Claim 2
Dependent Claim
94 words
A process for producing a mixture of cupric and manganous alkanoates containing from 6 to 9 carbon atoms comprising (1) thermally decomposing a mixture of cupric oxalate and manganous oxalate in the presence of an organic saturated aliphatic monocarboxylic acid containing from 6 to 9 carbon atoms in the absence of oxygen, producing the corresponding manganous alkanoate in admixture with metallic copper, (2) oxidizing said metallic copper to the cupric form in the presence of oxygen, and (3) reacting said copper in the cupric form with said acid to produce the corresponding cupric alkanoate.
Claim 3
Dependent Claim
15 words
The process of claim 1 wherein the organic saturated aliphatic monocarboxylic acid is heptanoic acid.
Claim 4
Dependent Claim
15 words
The process of claim 1 wherein the organic saturated aliphatic monocarboxylic acid is nonanoic acid.
Claim 5
Dependent Claim
29 words
The process of claim 1 wherein the thermal composition of the cupric and manganous oxalates is carried out at temperatures ranging from about 220° C. to about 300° C.
Claim 6
Dependent Claim
25 words
The process of claim 1 wherein the oxidation of the metallic copper is conducted at air pressures ranging from about 100 to about 500 psig.
Claim 7
Dependent Claim
36 words
The process of claim 1 wherein the oxidation of the metallic copper is conducted at air pressures ranging from about 225 to about 275 psig at temperatures ranging from about 50° C. to about 125° C.
Claim 8
Dependent Claim
104 words
A process for producing a mixture of cupric and manganous heptanoates comprising (1) thermally decomposing a mixture of cupric and manganous oxalates at a temperature of from about 225° C. to about 275° C. in the presence of heptanoic acid and the absence of oxygen to produce manganous heptanoate and metallic copper, (2) oxidizing said metallic copper to the cupric form with air at a temperature of from about 80° C. to about 110° C. and an air pressure of from about 225 to about 275 psig, and (3) reacting said copper in the cupric form with said heptanoic acid to form cupric heptanoate.
Claim 9
Dependent Claim
104 words
A process for producing a mixture of cupric and manganous heptanoates comprising (1) thermally decomposing a mixture of cupric and manganous oxalates at a temperature of from about 225° C. to about 275° C. in the presence of heptanoic acid and the absence of oxygen to produce manganous heptanoate and metallic copper, (2) oxidizing said metallic copper to the cupric form with air at a temperature of from about 80° C. to about 110° C. and an air pressure of from about 225 to about 275 psig, and (3) reacting said copper in the cupric form with said heptanoic acid to form cupric heptanoate.
Claim 10
Dependent Claim
104 words
A process for producing a mixture of cupric and manganous nonanoates comprising (1) thermally decomposing a mixture of cupric and manganous oxalates at a temperature of from about 250° C. to about 275° C. in the presence of nonanoic acid and the absence of oxygen to produce manganous nonanoate and metallic copper, (2) oxidizing said metallic copper to the cupric form with air at a temperature of from about 80° C. to about 110° C. and an air pressure of from about 225 to about 275 psig, and (3) reacting said copper in the cupric form with said nonanoic acid to form cupric nonanoate.
Claim 11
Dependent Claim
104 words
A process for producing a mixture of cupric and manganous nonanoates comprising (1) thermally decomposing a mixture of cupric and manganous oxalates at a temperature of from about 250° C. to about 275° C. in the presence of nonanoic acid and the absence of oxygen to produce manganous nonanoate and metallic copper, (2) oxidizing said metallic copper to the cupric form with air at a temperature of from about 80° C. to about 110° C. and an air pressure of from about 225 to about 275 psig, and (3) reacting said copper in the cupric form with said nonanoic acid to form cupric nonanoate.
Claim 12
Dependent Claim
163 words
In a process for the production of a saturated aliphatic monocarboxylic acid containing from 6 to 9 carbon atoms by oxidation of its corresponding aldehyde using a mixture of cupric and manganous compounds as oxidation catalyst wherein the cupric and manganous compounds in the product mixture are reacted with oxalic acid to form cupric and manganous oxalates and said oxalates are separated from said saturated aliphatic monocarboxylic acid, the improvement comprising thermally decomposing said oxalates in the presence of an organic saturated aliphatic monocarboxylic acid containing from 6 to 9 carbon atoms in the absence of oxygen, producing the corresponding manganous alkanoate and metallic copper; oxidizing said metallic copper to the cupric form in the presence of oxygen; reacting said copper in the cupric form with said acid to produce the corresponding cupric alkanoate, and recycling said manganous and cupric alkanoates to the oxidation reaction wherein a saturated aliphatic monocarboxylic acid containing 6 to 9 carbon atoms is produced from its corresponding aldehyde.
Claim 13
Dependent Claim
163 words
In a process for the production of a saturated aliphatic monocarboxylic acid containing from 6 to 9 carbon atoms by oxidation of its corresponding aldehyde using a mixture of cupric and manganous compounds as oxidation catalyst wherein the cupric and manganous compounds in the product mixture are reacted with oxalic acid to form cupric and manganous oxalates and said oxalates are separated from said saturated aliphatic monocarboxylic acid, the improvement comprising thermally decomposing said oxalates in the presence of an organic saturated aliphatic monocarboxylic acid containing from 6 to 9 carbon atoms in the absence of oxygen, producing the corresponding manganous alkanoate and metallic copper; oxidizing said metallic copper to the cupric form in the presence of oxygen; reacting said copper in the cupric form with said acid to produce the corresponding cupric alkanoate, and recycling said manganous and cupric alkanoates to the oxidation reaction wherein a saturated aliphatic monocarboxylic acid containing 6 to 9 carbon atoms is produced from its corresponding aldehyde.
Claim 14
Dependent Claim
25 words
The process of claim 9 wherein heptanal is oxidized to heptanoic acid and the manganous and cupric alkanoates formed are manganous heptanoate and cupric heptanoate.
Claim 15
Dependent Claim
25 words
The process of claim 9 wherein nonanal is oxidized to nonanoic acid and the manganous and cupric alkanoates formed are manganous nonanoate and cupric nonanoate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-11-27 | 1988-05-28 | 1988-11-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-11-27 | 1992-05-28 | 1992-11-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-11-27 | 1996-05-28 | 1996-11-27 | $7700.00 | Window Closed / Lapsed |