US4484939A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Herbicidal sulfonamide inner salts
Assignee: EIDP Inc
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Filing: 1983-11-16
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Granted: 1984-11-27
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Expires: 2003-11-16
Abstract
Abstract Certain sulfonamide inner salts, such as 2-[N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]benzoic acid methyl ester, dimethylsulfonium inner salt, possess utility as herbicides.
Inventors
- 👤 Chi-Ping Tseng
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 05:42
CPC Classifications
C; C07; C07D; C07D239/00; C07D239/02; C07D239/24; C07D239/28; C07D239/32; C07D239/42; A; A01; A01N; A01N47/00; A01N47/08; A01N47/28; A01N47/36; A01N47/40; A01N47/42; A01N47/44; C07D239/46; C07D239/47; C07D239/52; C07D251/00; C07D251/02; C07D251/12; C07D251/26; C07D251/40; C07D251/42; C07D251/46; C07D521/00
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
492 words
A compound of the formula: ##STR60## wherein R a is CH 3 or CH 2 CH 3 ; R b is CH 3 or CH 2 CH 3 ; L is ##STR61## R 5 is C 1 -C 4 alkyl, C 1 -C 4 alkoxy, OCH 2 CH 2 OCH 3 , F, Cl, Br, NO 2 , CF 3 , CO 2 R 19 , SO 2 NR 20 R 21 , SO 2 N(OCH 3 )CH 3 , OSO 2 R 22 , S(O) n R 23 , WCF 3 , WCHF 2 , C 3 -C 4 alkenyloxy, C 3 -C 4 alkynyloxy, C 1 -C 2 alkyl substituted with OCH 3 or OCH 2 CH 3 , C 6 H 5 , ##STR62## R 6 is H, F, Cl, Br, CF 3 , CH 3 , OCH 3 , SCH 3 or OCF 2 H; R 7 is H, CH, 3 , OCH 3 , F, Cl, Br. OSO 2 CH 3 or S(O) n CH 3 ; R 10 is Cl, NO 2 , CO 2 CH 3 , CO 2 CH 2 CH 3 , SO 2 N(CH 3 ) 2 , OSO 2 CH 3 , SO 2 CH 3 , SO 2 CH 2 CH 3 , OCH 3 or OCH 2 CH 3 ; R 19 is C 1 -C 4 alkyl, CH 2 CH 2 OCH 3 , CH 2 CH 2 Cl or CH 2 CH═CH 2 ; R 20 is C 1 -C 3 alkyl; R 21 is C 1 -C 3 alkyl; R 22 is C 1 -C 3 alkyl or N(CH 3 ) 2 ; R 23 is C 1 -C 3 alkyl or CH 2 CH=CH 2 ; n is 0 or 2; and W is O, S or SO 2 ; A is ##STR63## X is CH 3 , OCH 3 , OCH 2 CH 3 , Cl, F, Br, OCF 2 H, CH 2 F or CF 3 ; Y is H, CH 3 , OCH 3 ,OCH 2 CH 3 , CH 2 OCH 3 , CH 2 OCH 2 CH 3 , N(CH 3 ) 2 , CH 2 CH 3 , CF 3 , SCH 3 , OCH 2 CH═CH 2 , OCH 2 C.tbd.CH, OCH 2 CF 3 , OCH 2 CH 2 OCH 3 , CH 2 SCH 3 , OCF 2 H, SCF 2 H, CR 24 (QCH 3 ) 2 , ##STR64## or CR 24 (QCH 2 CH 3 ) 2 ; Q is O or S; R 24 is H or CH 3 ; Z is CH; provided that (1) the total number of carbon atoms of R 20 and R 21 is less than or equal to four; and (2) when X is Cl, F, or Br, then Y is OCH 3 , OCH 2 CH 3 , N(CH 3 ) 2 or OCF 2 H.
Claim 2
Dependent Claim
492 words
A compound of the formula: ##STR60## wherein R a is CH 3 or CH 2 CH 3 ; R b is CH 3 or CH 2 CH 3 ; L is ##STR61## R 5 is C 1 -C 4 alkyl, C 1 -C 4 alkoxy, OCH 2 CH 2 OCH 3 , F, Cl, Br, NO 2 , CF 3 , CO 2 R 19 , SO 2 NR 20 R 21 , SO 2 N(OCH 3 )CH 3 , OSO 2 R 22 , S(O) n R 23 , WCF 3 , WCHF 2 , C 3 -C 4 alkenyloxy, C 3 -C 4 alkynyloxy, C 1 -C 2 alkyl substituted with OCH 3 or OCH 2 CH 3 , C 6 H 5 , ##STR62## R 6 is H, F, Cl, Br, CF 3 , CH 3 , OCH 3 , SCH 3 or OCF 2 H; R 7 is H, CH, 3 , OCH 3 , F, Cl, Br. OSO 2 CH 3 or S(O) n CH 3 ; R 10 is Cl, NO 2 , CO 2 CH 3 , CO 2 CH 2 CH 3 , SO 2 N(CH 3 ) 2 , OSO 2 CH 3 , SO 2 CH 3 , SO 2 CH 2 CH 3 , OCH 3 or OCH 2 CH 3 ; R 19 is C 1 -C 4 alkyl, CH 2 CH 2 OCH 3 , CH 2 CH 2 Cl or CH 2 CH═CH 2 ; R 20 is C 1 -C 3 alkyl; R 21 is C 1 -C 3 alkyl; R 22 is C 1 -C 3 alkyl or N(CH 3 ) 2 ; R 23 is C 1 -C 3 alkyl or CH 2 CH=CH 2 ; n is 0 or 2; and W is O, S or SO 2 ; A is ##STR63## X is CH 3 , OCH 3 , OCH 2 CH 3 , Cl, F, Br, OCF 2 H, CH 2 F or CF 3 ; Y is H, CH 3 , OCH 3 ,OCH 2 CH 3 , CH 2 OCH 3 , CH 2 OCH 2 CH 3 , N(CH 3 ) 2 , CH 2 CH 3 , CF 3 , SCH 3 , OCH 2 CH═CH 2 , OCH 2 C.tbd.CH, OCH 2 CF 3 , OCH 2 CH 2 OCH 3 , CH 2 SCH 3 , OCF 2 H, SCF 2 H, CR 24 (QCH 3 ) 2 , ##STR64## or CR 24 (QCH 2 CH 3 ) 2 ; Q is O or S; R 24 is H or CH 3 ; Z is CH; provided that (1) the total number of carbon atoms of R 20 and R 21 is less than or equal to four; and (2) when X is Cl, F, or Br, then Y is OCH 3 , OCH 2 CH 3 , N(CH 3 ) 2 or OCF 2 H.
Claim 3
Dependent Claim
47 words
A compound of claim 1 where Y is CH 3 , OCH 3 , OCH 2 CH 3 , CH 2 OCH 3 , OCH 2 CF 3 or CH(OCH 3 ) 2 and X is CH 3 , OCH 3 , Cl or CF 3 .
Claim 4
Dependent Claim
11 words
A compound of claim 2 where L is L-1 or L-2.
Claim 5
Dependent Claim
95 words
A compound of claim 3 where L is L-1; R 5 is OCH 3 , OCH 2 CH 3 , Cl, NO 2 , CF 3 , CO 2 CH 3 , CO 2 CH 2 CH 3 , SO 2 N(CH 3 ) 2 , SO 2 N(OCH 3 )CH 3 , OSO 2 R 22 , S(O) n R 23 , OCF 2 H, SCF 2 H, OCH 2 CH═CH 2 , OCH 2 C.tbd.CH, ##STR65## R 22 is C 1 -C 3 alkyl; R 23 is CH 3 and n is 2.
Claim 6
Dependent Claim
22 words
Compounds of claim 3 where L is L-2and R 7 is Cl, CH 3 , OCH 3 , SCH 3 or Br.
Claim 7
Dependent Claim
14 words
The compound of claim 1 which is 2-[[(4-methoxy-6-methypyrimidin-2-yl)aminocarcarbonyl]aminosulfonyl]benzoic acid methyl ester, dimethylsulfonium inner salt.
Claim 8
Dependent Claim
14 words
The compound of claim 1 which is 2-[[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]aminosulfonyl]-benzoic acid methyl ester, dimethylsulfonium inner salt.
Claim 9
Dependent Claim
11 words
The compound of claim 1 which is N-[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]-2-methylsulfonylbenzenesulfonamide, dimethylsulfonium inner salt.
Claim 10
Dependent Claim
14 words
The compound of claim 1 which is 2-[[(4,6-dimethylpyrimidin-2-yl)aminocarbonyl]aminosulfonyl]-benzoic acid methyl ester, dimethylsulfonium inner salt.
Claim 11
Dependent Claim
11 words
The compound of claim 1 which is N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2-dimethylaminosulfonylbenzenesulfonamide, dimethylsulfonium inner salt.
Claim 12
Dependent Claim
33 words
A composition suitable for controlling the growth of undesired vegetation comprising an effective amount of a compound of claim 1 and at least one of the following: surfactant, solid or liquid inert diluent.
Claim 13
Dependent Claim
33 words
A composition suitable for controlling the growth of undesired vegetation comprising an effectiv amount of the compound of claim 6 and at least one of the following: surfactant, solid or liquid inert diluent.
Claim 14
Dependent Claim
33 words
A composition suitable for controlling the growth of undesired vegetation comprising an effective amount of the compound of claim 7 and at least one of the following: surfactant, solid or liquid inert diluent.
Claim 15
Dependent Claim
33 words
A composition suitable for controlling the growth of undesired vegetation comprising an effective amount of the compound of claim 8 and at least one of the following: surfactant, solid or liquid inert diluent.
Claim 16
Dependent Claim
33 words
A composition suitable for controlling the growth of undesired vegetation comprising an effective amount of the compound of claim 9 and at least one of the following: surfactant, solid or liquid inert diluent.
Claim 17
Dependent Claim
33 words
A composition suitable for controlling the growth of undesired vegetation comprising an effective amount of the compound of claim 10 and at least one of the following: surfactant, solid or liquid inert diluent.
Claim 18
Dependent Claim
26 words
A method of controlling the growth of undesired vegetation comprising applying to the locus of said vegetation an effective amount of a compound of claim 1.
Claim 19
Dependent Claim
26 words
A method of controlling the growth of undesired vegetation comprising applying to the locus of said vegetation an effective amount of the compound of claim 6.
Claim 20
Dependent Claim
26 words
A method of controlling the growth of undesired vegetation comprising applying to the locus of said vegetation an effective amount of the compound of claim 7.
Claim 21
Dependent Claim
26 words
A method of controlling the growth of undesired vegetation comprising applying to the locus of said vegetation an effective amount of the compound of claim 8.
Claim 22
Dependent Claim
26 words
A method of controlling the growth of undesired vegetation comprising applying to the locus of said vegetation an effective amount of the compound of claim 9.
Claim 23
Dependent Claim
26 words
A method of controlling the growth of undesired vegetation comprising applying to the locus of said vegetation an effective amount of the compound of claim 10.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-11-27 | 1988-05-28 | 1988-11-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-11-27 | 1992-05-28 | 1992-11-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-11-27 | 1996-05-28 | 1996-11-27 | $7700.00 | Window Closed / Lapsed |