US4482701A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Hydrolyzable polyester resins, varnishes and coating compositions containing the same
Assignee: Nippon Paint Co Ltd
•
Filing: 1982-09-28
•
Granted: 1984-11-13
•
Expires: 2002-09-28
Abstract
Abstract Preparation of hydrolyzable polyester resin comprising reacting polycarboxylic acid and polyhydric alcohol components, which is characterized by using, as at least part of said polyhydric alcohol component, a metallic salt of hydroxy carboxylic acid of the formula defined and effecting the polycondensation at a temperature which is no more than the decomposition temperature of said metallic salt. The polyester resins are useful as resinous vehicle of varnishes and antifouling paints.
Inventors
- 👤 Naoki Yamamori
- 👤 Junji Yokoi
- 👤 Motoyoshi Yoshikawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 13:56
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/60; C08K; C08K3/00; C08K3/02; C08K3/08; C08K3/18; C08K3/20; C08K3/22; C08K3/28; C08K5/00; C08K5/36; C08K5/39; C08K5/56; C08K5/57; C09; C09D; C09D167/00; C09D167/04; C09D5/00; C09D5/16; C09D5/1606; C09D5/1637; C09D5/165; Y; Y10; Y10S; Y10S260/00; Y10S260/43; Y10S525/00; Y10S525/938
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
121 words
A process for preparing a hydrolyzable polyester resin comprising reacting polycarboxylic acid and polyhydric alcohol components, which is characterized in that a metallic salt of hydroxy carboxylic acid of the formula: ##STR9## wherein R is a hydrocarbon residue or residue of a half ester of a dicarboxylic acid, M stands for monovalent to tetravalent metal belonging to anyone of the groups Ia, Ib, IIa, IIb, IVa, VIIb and VIII of the Periodic Table, and l is an integer corresponding to the valency of said metal M, is used as at least part of said polyhydric alcohol component and the polycondensation is effected at a temperature which is no more than the decomposition temperature of said metallic salt of hydroxy carboxylic acid.
Claim 2
Dependent Claim
121 words
A process for preparing a hydrolyzable polyester resin comprising reacting polycarboxylic acid and polyhydric alcohol components, which is characterized in that a metallic salt of hydroxy carboxylic acid of the formula: ##STR9## wherein R is a hydrocarbon residue or residue of a half ester of a dicarboxylic acid, M stands for monovalent to tetravalent metal belonging to anyone of the groups Ia, Ib, IIa, IIb, IVa, VIIb and VIII of the Periodic Table, and l is an integer corresponding to the valency of said metal M, is used as at least part of said polyhydric alcohol component and the polycondensation is effected at a temperature which is no more than the decomposition temperature of said metallic salt of hydroxy carboxylic acid.
Claim 3
Dependent Claim
29 words
The process according to claim 1, wherein R is a saturated aliphatic hydrocarbon residue of the formula: --(C.sub.a H.sub.2a)-- in which a is an integer from 1 to 38.
Claim 4
Dependent Claim
63 words
The process according to claim 2, wherein the saturated aliphatic hydrocarbon residue is the group of the formula: ##STR10## in which R 1 and R 2 each represents a member selected from hydrogen atom, alkyl having 1 to 10 carbon atoms and alkene having 2 to 10 carbon atoms, and m and n each is 0 or an integer from 1 to 16.
Claim 5
Dependent Claim
42 words
The process according to claim 3, wherein R 1 and R 2 each represents a member selected from hydrogen atom and alkyl having 1 to 8 carbon atoms, and m and n each is 0 or an integer from 1 to 10.
Claim 6
Dependent Claim
24 words
The process according to claim 1, wherein the hydroxy carboxylic acid is selected from lactic acid, hydracrylic acid, 12-hydroxy stearic acid and glycolic acid.
Claim 7
Dependent Claim
29 words
The process according to claim 1, wherein R is an unsaturated aliphatic hydrocarbon residue of the formula: --(C.sub.b H.sub.2b-2)-- in which b is an integer from 2 to 38.
Claim 8
Dependent Claim
64 words
Thre process according to claim 6, wherein the unsaturated aliphatic hydrocarbon residue is the group of the formula: ##STR11## in which R 3 and R 4 each represents a member selected from hydrogen atom, alkyl having 1 to 10 carbon atoms and alkene having 2 to 10 carbon atoms, and x, y and z each is 0 or an integer from 1 to 10.
Claim 9
Dependent Claim
59 words
The process according to claim 7, wherein R 3 and R 4 each represents a member selected from hydrogen atom and alkyl having 1 to 8 carbon atoms, x is 0 or an integer from 1 to 4, y is 0 or an integer from 1 to 6 and z is 0 or an integer from 1 to 10.
Claim 10
Dependent Claim
19 words
The process according to claim 1, wherein the hydroxy carboxylic acid is selected from ricinoleic acid and ricinoelaidic acid.
Claim 11
Dependent Claim
67 words
The process according to claim 1, wherein R is a residue of half ester of aliphatic dicarboxylic acid of the formula: ##STR12## in which R 5 is a member selected from alkylene having 1 to 8 carbon atoms and ether bonding bearing alkylene having 4 to 8 carbon atoms, and R 6 is a member selected from saturated and unsaturated alkylenes having 2 to 4 carbon atoms.
Claim 12
Dependent Claim
53 words
The process according to claim 1, wherein the hydroxy carboxylic acid is a half ester of an aliphatic dicarboxylic acid selected from maleic anhydride, succinic anhydride, dimethyl maleic anhydride, and dimethyl succinic anhydride, with a polyol selected from ethylene glycol, propylene glycol, 1,3-butylenediol, 1,6-hexanediol, diethylene glycol, dipropylene glycol, neopentyl glycol, and triethylene glycol.
Claim 13
Dependent Claim
71 words
The process according to claim 1, wherein R is a residue of half ester of a saturated or unsaturated cyclic dicarboxylic acid of the formula: ##STR13## in which R 7 is a member selected from alkylene having 1 to 8 carbon atoms and ether bonding bearing alkylene having 4 to 8 carbon atoms, and R 8 is a member selected from saturated and unsaturated cyclic hydrocarbons having 6 to 7 atoms.
Claim 14
Dependent Claim
55 words
The process according to claim 1, wherein the hydroxy carboxylic acid is a half ester of a saturated or unsaturated cyclic dicarboxylic acid selected from phthalic anhydride, tetrahydrophthalic anhydride, hexahydro phthalic anhydride, and himic anhydride with a polyol selected from ethylene glycol, propylene glycol, 1,3-butylenediol, 1,6-hexanediol, diethylene glycol, dipropylene glycol, neopentyl glycol and triethylene glycol.
Claim 15
Dependent Claim
36 words
The process according to anyone of the preceding claims, wherein M is selected from the group consisting of Li, K, Na, Cu, Ag, Mg, Ca, Ba, Zn, Cd, Hg, Sn, Pb, Mn, Fe, Co and Ni.
Claim 16
Dependent Claim
27 words
The process according to claim 14, wherein M is selected from the group consisting of K, Na, Cu, Ag, Mg, Zn, Sn, Pb, Fe, Co and Ni.
Claim 17
Dependent Claim
21 words
The process according to claim 15, wherein M is selected from the group consisting of Na, Cu, Mg, Zn and Ni.
References Cited (Backward Citations)
US2985624A
Cited
US3053783A
Cited
US3057826A
Cited
US3075936A
Cited
US3318763A
Cited
US3761450A
Cited
US3725327A
Cited
US4036908A
Cited
US4130432A
Cited
US4128429A
Cited
US4277392A
Cited
US4282126A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-11-13 | 1988-05-14 | 1988-11-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-11-13 | 1992-05-14 | 1992-11-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-11-13 | 1996-05-14 | 1996-11-13 | $7700.00 | Window Closed / Lapsed |