← Back to Patent Explorer
US4482470A Expired / Lapsed US ⏱️ 0.0 years remaining

Viscosity modifiers for concentrated surfactants

Assignee: Henkel AG and Co KGaA
•
Filing: 1982-07-06
•
Granted: 1984-11-13
•
Expires: 2002-07-06
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Process for reducing the viscosity of aqueous concentrates of anionic surfactants by adding thereto a small quantity of a compound containing polyglycol ether groups; and the aqueous concentrates prepared thereby.

Inventors

  • 👤 Herbert Reuter
  • 👤 Lothar Pioch
  • 👤 Karl-Heinz Schmid
  • 👤 Wolfgang Seiter

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 05:37
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/02; C11D1/12; C11D1/22; C11D1/14; C11D1/146; C11D1/28; C11D1/66; C11D1/72; C11D1/83; C11D3/00; C11D3/16; C11D3/37; C11D3/3703; C11D3/3707; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/03

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 276 words
A process for the manufacture of powdery or granular spray dried detergents and cleaners comprising the steps of: I. forming an aqueous anionic surfactant concentrate having a viscosity of 10,000 CPS or less at a temperature in the range of 50° to 90° C. comprising A. an anionic surfactant component which is either (a) at least about 33 wt. %, based on the weight of the concentrate, of an alkali metal salt of an α-sulfo fatty acid ester or an alkali metal salt of an alkyl sulfate, or (b) at least about 53 wt. %, based on the weight of the concentrate, of an alkali metal salt of an alkyl aryl sulfonate; and B. from about 0.1 to about 10% by weight of the concentrate of at least one viscosity modifier selected from the group consisting of: (a) a polyethylene glycol having a molecular weight of from about 600 to about 6000; (b) a polypropylene glycol having a molecular weight of from about 250 to about 4000; (c) an adduct of from about 20 to about 80 moles of ethylene oxide with an aliphatic alcohol having from 10 to 20 carbon atoms; and (d) an adduct of from about 20 to about 60 moles of ethylene oxide with an alkyl phenol having from 6 to 12 carbon atoms in the alkyl group; and wherein the aqueous anionic surfactant concentrate in the absence of component B. has a viscosity of more than 10,000 CPS at a temperature in the range of 50°-90° C.; and II. processing the concentrate formed in I. above at a temperature in the range of from about 50° C. to about 90° C.
Claim 2
Dependent Claim 276 words
A process for the manufacture of powdery or granular spray dried detergents and cleaners comprising the steps of: I. forming an aqueous anionic surfactant concentrate having a viscosity of 10,000 CPS or less at a temperature in the range of 50° to 90° C. comprising A. an anionic surfactant component which is either (a) at least about 33 wt. %, based on the weight of the concentrate, of an alkali metal salt of an α-sulfo fatty acid ester or an alkali metal salt of an alkyl sulfate, or (b) at least about 53 wt. %, based on the weight of the concentrate, of an alkali metal salt of an alkyl aryl sulfonate; and B. from about 0.1 to about 10% by weight of the concentrate of at least one viscosity modifier selected from the group consisting of: (a) a polyethylene glycol having a molecular weight of from about 600 to about 6000; (b) a polypropylene glycol having a molecular weight of from about 250 to about 4000; (c) an adduct of from about 20 to about 80 moles of ethylene oxide with an aliphatic alcohol having from 10 to 20 carbon atoms; and (d) an adduct of from about 20 to about 60 moles of ethylene oxide with an alkyl phenol having from 6 to 12 carbon atoms in the alkyl group; and wherein the aqueous anionic surfactant concentrate in the absence of component B. has a viscosity of more than 10,000 CPS at a temperature in the range of 50°-90° C.; and II. processing the concentrate formed in I. above at a temperature in the range of from about 50° C. to about 90° C.
Claim 3
Dependent Claim 25 words
A process in accordance with claim 1 wherein the viscosity modifier in Step I.B. is present in from about 0.1 to about 5 wt. %.
Claim 4
Dependent Claim 25 words
A process in accordance with claim 1 wherein the viscosity modifier in Step I.B. is present in from about 0.5 to about 3 wt. %.
Claim 5
Dependent Claim 32 words
A process in accordance with claim 1, 2 or 3 wherein the viscosity modifier in Step I.B. is a polyethylene glycol having a molecular weight of from about 1000 to about 4000.
Claim 6
Dependent Claim 22 words
A process in accordance with claim 4 wherein the molecular weight of the polyethylene glycol is from about 1500 to about 2500.
Claim 7
Dependent Claim 32 words
A process in accordance with claim 1, 2, or 3 wherein the viscosity modifier in Step I.B. is a polypropylene glycol having a molecular weight of from about 400 to about 2000.
Claim 8
Dependent Claim 23 words
An aqueous concentrate in accordance with claim 6 wherein the molecular weight of the polypropylene glycol is from about 400 to about 800.
Claim 9
Dependent Claim 38 words
A process in accordance with claim 1 2 or 3 wherein the viscosity modifier in Step I.B. is an adduct of ethylene oxide with an aliphatic alcohol wherein from 40 to 60 moles of ethylene oxide are present.
Claim 10
Dependent Claim 24 words
A process in accordance with claim 8 wherein the viscosity modifier is an adduct of 50 moles of ethylene oxide with tallow fatty alcohol.
Claim 11
Dependent Claim 35 words
A process in accordance with claim 1, 2 or 3 wherein the viscosity modifier in Step I.B. is an adduct of from about 30 to about 50 moles of ethylene oxide with a nonyl phenol.
Claim 12
Dependent Claim 36 words
A process in accordance with claim 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10 wherein the aqueous anionic surfactant concentrate in Step I. contains one or more other surface active agents and/or additives.

References Cited (Backward Citations)

US3377289A Cited
DE2251405A1 Cited
US3893955A Cited
GB1402403A Cited
US4198308A Cited
US4000080A Cited
US3998762A Cited
JPS5335711A Cited
US4261941A Cited
JPS5665098A Cited
EP0034039A1 Cited
US4316824A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-11-13 1988-05-14 1988-11-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-11-13 1992-05-14 1992-11-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-11-13 1996-05-14 1996-11-13 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag