US4481266A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Reactive metal battery having continuous supply of cathode reactant
Assignee: Lockheed Martin Corp
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Filing: 1983-03-25
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Granted: 1984-11-06
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Expires: 2003-03-25
Abstract
Abstract An improved porous cathode structure for use in a battery having a reactive metal electrode and flowed electrolyte. The cathode is preferably formed of an electrically conducting porous material with categorically active surface at an interface with the electrolyte. Alternatively, the cathode may be of an electrochemically reducible porous material and defines an active surface. Structure is provided for delivering electrochemically reducible cathode reactant material continuously through the cathode to the cathode active surface during operation of the battery. The reactant material is delivered in an amount required to be reduced at the active surface to maintain high energy discharge rate with minimum amount of reactant material being utilized. The reactant material, in the illustrated embodiment, is provided from a storage supply and delivered to the porous cathode as needed during operation of the battery. In one form, the cathode is provided with distribution passages for conducting the reactant material therethrough. In another form, the reactant material is introduced through one or more edge portions of the cathode porous body for flow through the pores to the active surface.
Inventors
- 👤 Ernest L. Littauer
- 👤 William R. Momyer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:57
CPC Classifications
H; H01; H01M; H01M12/00; H01M12/04
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
62 words
A battery comprising a reactive metal electrode, flowed electrolyte, porous cathode structure defining a catalytically active surface at an interface with said electrolyte, and means for providing electrochemically reducible soluble cathode reactant material through the cathode to said active surface during operation of the battery in an amount sufficient to be reduced at said surface to maintain a high energy discharge rate.
Claim 2
Dependent Claim
62 words
A battery comprising a reactive metal electrode, flowed electrolyte, porous cathode structure defining a catalytically active surface at an interface with said electrolyte, and means for providing electrochemically reducible soluble cathode reactant material through the cathode to said active surface during operation of the battery in an amount sufficient to be reduced at said surface to maintain a high energy discharge rate.
Claim 3
Dependent Claim
15 words
The battery of claim 1 wherein said cathode comprises a solid electrochemically reducible porous material.
Claim 4
Dependent Claim
37 words
The battery of claim 1 wherein said reactant material providing means comprises means defining flow passages distributed through said cathode to deliver the reactant material through the porous cathode material substantially uniformly to the active surface thereof.
Claim 5
Dependent Claim
62 words
The battery of claim 1 wherein said reactant material providing means comprises means defining flow passages distributed through said cathode to deliver the reactant material through the porous cathode material substantially uniformly to the active surface thereof, means for storing a supply of the reactant material, and means for delivering the reactant material from the storing means to the cathode as needed.
Claim 6
Dependent Claim
48 words
The battery of claim 1 wherein said reactant material providing means comprises means for storing a supply of the reactant material, and means for delivering the reactant material from the storing means to an edge portion of the cathode to be flowed through the porous cathode as needed.
Claim 7
Dependent Claim
49 words
The battery of claim 1 wherein said reactant material providing means comprises means for storing a supply of the reactant material, and means for delivering the reactant material from the storing means to a lower edge portion of the cathode to be flowed through the porous cathode as needed.
Claim 8
Dependent Claim
27 words
The battery of claim 1 wherein said reactant material is selected from the group consisting of hydrogen peroxide, lithium peroxide, nitrites, bromates, chlorates, sulfites, dinitrogentrioxide, and hypochlorites.
Claim 9
Dependent Claim
13 words
The battery of claim 7 wherein said reactant material comprises soluble peroxide ions.
Claim 10
Dependent Claim
12 words
The battery of claim 1 wherein said reactant material comprises a halogen.
Claim 11
Dependent Claim
87 words
A battery comprising a reactive metal electrode, flowed electrolyte, a solid electrochemically reducible porous cathode defining an active surface with an inert metal substrate juxtaposed thereto, and means for providing electrochemically reducible soluble cathode reactant material through the cathode to the cathode active surface adjacent to said inert metal substrate during operation of the battery in an amount sufficient to be reduced at said surface to maintain a high energy discharge rate, the reduced reactant material being removed therefrom as it is formed, by the flowed electrolyte.
Claim 12
Dependent Claim
87 words
A battery comprising a reactive metal electrode, flowed electrolyte, a solid electrochemically reducible porous cathode defining an active surface with an inert metal substrate juxtaposed thereto, and means for providing electrochemically reducible soluble cathode reactant material through the cathode to the cathode active surface adjacent to said inert metal substrate during operation of the battery in an amount sufficient to be reduced at said surface to maintain a high energy discharge rate, the reduced reactant material being removed therefrom as it is formed, by the flowed electrolyte.
Claim 13
Dependent Claim
20 words
The battery of claim 10 wherein said cathode comprises a thin wall member having reactant metal distribution passages formed therein.
Claim 14
Dependent Claim
35 words
The battery of claim 10 wherein said cathode comprises silver oxide active material and said reactant is provided in sufficient quantity to provide a capacity of greater than approximately 23 ampere-minutes per gram of reactant.
Claim 15
Dependent Claim
27 words
The battery of claim 10 wherein said reactant material is selected from the group consisting of hydrogen peroxide, lithium peroxide, nitrites, bromates, chlorates, sulfites, dinitrogentrioxide, and hypochlorites.
Claim 16
Dependent Claim
12 words
The battery of claim 13 wherein said reactant material comprises a peroxide.
Claim 17
Dependent Claim
12 words
The battery of claim 10 wherein said reactant material comprises a halogen.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-11-06 | 1988-05-07 | 1988-11-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-11-06 | 1992-05-07 | 1992-11-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-11-06 | 1996-05-07 | 1996-11-06 | $7700.00 | Window Closed / Lapsed |