US4480060A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Mica-resin composite material
Assignee: Corning Glass Works
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Filing: 1983-01-27
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Granted: 1984-10-30
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Expires: 2003-01-27
Abstract
Abstract A composite material is disclosed which is composed essentially of an ion-exchanged, synthetic, crystalline mica and an organic resin, the mica constituting at least about 50% by weight of the composite, and the mechanical properties of the composite being superior to those of the mica pressed alone.
Inventors
- 👤 Syed N. Hoda
- 👤 Anthony R. Olszewski
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 10:40
CPC Classifications
C; C04; C04B; C04B14/00; C04B14/02; C04B14/04; C04B14/20; C04B14/206; B; B01; B01J; B01J39/00; B01J39/08; B01J39/09; B01J47/00; B01J47/018; C08; C08J; C08J5/00; C08J5/20; C08J5/22
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
139 words
The method of forming a composite body composed of ion-exchanged, synthetic mica crystals and an organic resin which comprises the steps of, providing in flocculated form an ion-exchanged, synthetic, lithium and/or sodium, crystalline mica, the mica being selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, fluorpolylithioinite, polylithionite, phlogopite, and fluorphlogopite, converting the floc to particulate form, mixing the particulate floc with an organic resin in particulate form and in such amount that the processed composite has a greater mechanical strength than similarly processed floc alone, and contains at least 50% floc dispersing the mixture in a solvent, drying the dispersed mixture, and pressing the dried mixture to desired form at an elevated temperature and pressure.
Claim 2
Independent Claim
139 words
The method of forming a composite body composed of ion-exchanged, synthetic mica crystals and an organic resin which comprises the steps of, providing in flocculated form an ion-exchanged, synthetic, lithium and/or sodium, crystalline mica, the mica being selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, fluorpolylithioinite, polylithionite, phlogopite, and fluorphlogopite, converting the floc to particulate form, mixing the particulate floc with an organic resin in particulate form and in such amount that the processed composite has a greater mechanical strength than similarly processed floc alone, and contains at least 50% floc dispersing the mixture in a solvent, drying the dispersed mixture, and pressing the dried mixture to desired form at an elevated temperature and pressure.
Claim 3
Dependent Claim
16 words
A method in accordance with claim 1 wherein the selected water-swelling mica is a lithium fluorhectorite.
Claim 4
Dependent Claim
20 words
A method in accordance with claim 1 wherein the lithium and/or sodium, water-swelling mica is ion-exchanged with an organic cation.
Claim 5
Dependent Claim
18 words
A method in accordance with claim 1 wherein the lithium and/or sodium, water-swelling mica is ion-exchanged with potassium.
Claim 6
Dependent Claim
14 words
A method in accordance with claim 1 wherein the organic resin is an epoxy.
Claim 7
Dependent Claim
23 words
A method in accordance with claim 1 wherein a coupling agent is added in amount up to 2% of the floc plus resin.
Claim 8
Dependent Claim
15 words
A method in accordance with claim 6 wherein the coupling agent is a silane compound.
Claim 9
Dependent Claim
21 words
A method in accordance with claim 1 wherein the floc is redispersed and spray dried to convert it to particulate form.
Claim 10
Dependent Claim
23 words
A method in accordance with claim 1 wherein the mixture of spray dried mica and resin is dispersed, dried and then compression molded.
Claim 11
Independent Claim
218 words
The method of forming a composite body composed of ion-exchanged, synthetic mica crystals and an organic resin which comprises the steps of forming a fully or predominantly crystalline body containing crystals consisting essentially of a synthetic, lithium and/or sodium, water-swelling mica selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, fluorpolylithionite, polylithionite, phlogopite, and fluorphlogopite, contacting the body with a polar liquid to cause the body to swell and disintegrate into platelets having a high aspect ratio which disperse in the liquid and form a gel, mixing the gel with a donor of a larger cation whereby the larger cation exchanges with the lithium and/or sodium ions of the mica to form ion-exchanged particles which flocculate, converting the floc thus formed to a particulate form, mixing the particulate floc with an organic resin in particulate form and in such amount that the processed composite has a greater mechanical strength than similarly processed floc alone while the floc constitutes at least 50% of the composite, adding a coupling agent, dispersing the mixture in a solvent, drying the dispersed mixture to a powder form, pressing the powdered mixture to desired form at an elevated temperature and pressure.
Claim 12
Independent Claim
218 words
The method of forming a composite body composed of ion-exchanged, synthetic mica crystals and an organic resin which comprises the steps of forming a fully or predominantly crystalline body containing crystals consisting essentially of a synthetic, lithium and/or sodium, water-swelling mica selected from the group of fluorhectorite, hydroxyl hectorite, boron fluorphlogopite, hydroxyl boron phlogopite, and solid solutions among those and between those and other structurally-compatible species selected from the group of talc, fluortalc, fluorpolylithionite, polylithionite, phlogopite, and fluorphlogopite, contacting the body with a polar liquid to cause the body to swell and disintegrate into platelets having a high aspect ratio which disperse in the liquid and form a gel, mixing the gel with a donor of a larger cation whereby the larger cation exchanges with the lithium and/or sodium ions of the mica to form ion-exchanged particles which flocculate, converting the floc thus formed to a particulate form, mixing the particulate floc with an organic resin in particulate form and in such amount that the processed composite has a greater mechanical strength than similarly processed floc alone while the floc constitutes at least 50% of the composite, adding a coupling agent, dispersing the mixture in a solvent, drying the dispersed mixture to a powder form, pressing the powdered mixture to desired form at an elevated temperature and pressure.
Claim 13
Dependent Claim
16 words
A method in accordance with claim 10 wherein the crystalline body is a synthetic lithium fluorhectorite.
Claim 14
Dependent Claim
25 words
A method in accordance with claim 10 wherein the polar liquid is water and the solids dispersed therein amount to 5-10% of the gel formed.
Claim 15
Dependent Claim
18 words
A method in accordance with claim 10 wherein the larger ion exchanging for lithium and/or sodium is potassium.
Claim 16
Dependent Claim
18 words
A method in accordance with claim 10 wherein the organic resin mixed with the floc is an epoxy.
Claim 17
Dependent Claim
20 words
A method in accordance with claim 14 wherein the floc in the mixture constitutes at least 50% of the solids.
Claim 18
Independent Claim
23 words
A method in accordance with c1aim 10 wherein the coupling agent is added in an amount up to 2% of the solids content.
Claim 19
Independent Claim
23 words
A method in accordance with c1aim 10 wherein the coupling agent is added in an amount up to 2% of the solids content.
Claim 20
Dependent Claim
15 words
A method in accordance with claim 16 wherein the coupling agent is a silane compound.
Claim 21
Dependent Claim
22 words
A method in accordance with claim 10 wherein the mixture of mica and resin particles is dispersed, dried and then compression molded.
Claim 22
Dependent Claim
21 words
A method in accordance with claim 10 wherein the floc is redispersed and spray dried to convert it to particulate form.
References Cited (Backward Citations)
US2614055A
Cited
US4239519A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-10-30 | 1988-04-30 | 1988-10-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-10-30 | 1992-04-30 | 1992-10-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-10-30 | 1996-04-30 | 1996-10-30 | $7700.00 | Window Closed / Lapsed |