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US4480054A Expired / Lapsed US ⏱️ 0.0 years remaining

Foamable polymer blend compositions

Assignee: EIDP Inc
•
Filing: 1984-01-23
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Granted: 1984-10-30
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Expires: 2004-01-23
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Abstract

Abstract Compatible blends of an ethylene/methacrylic or ethylene/acrylic acid dipolymer or a terpolymer with n-butyl or isobutyl acrylate with an ethylene/X/Y terpolymer, where X is vinyl acetate or an alkyl acrylate and Y is CO or SO2, with an elastomer, a blowing agent, and a curing agent can be readily formed into stiff foamed articles having very good physical properties, especially split tear and tensile strength. The foamed articles are useful, among others, in such applications as footwear, insulation, shock absorbance, floatation devices, seals and, gaskets.

Inventors

  • 👤 Susan J. Enderle

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 12:48
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/04; C08J9/0061; C08J2323/00; C08J2323/02; C08J2323/04; C08J2323/08; Y; Y10; Y10S; Y10S521/00; Y10S521/909

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 233 words
A compatible foamable, readily formable, curable polymer blend consisting essentially of the following components present in the following approximate weight amounts: (1) 50-100 parts of a dipolymer E/A or terpolymer E/A/B, wherein E is ethylene; A is acrylic or methacrylic acid; and B is n-butyl or isobutyl acrylate; the weight proportion of monomer A in both the dipolymer and the terpolymer being about 2-20% and the weight proportion of monomer B in the terpolymer being at most about 23%; the carboxylic acid groups in either type of polymer being either unneutralized or neutralized to an extent of at most about 71% with metal ions having a valency of from 1 to 3; (2) 2-40 parts of a terpolymer E/X/Y, where E is ethylene; X is vinyl acetate or a C 1 -C 8 alkyl acrylate; and Y is CO or SO 2 ; the weight proportions of X and Y being as follows: Y about 1-15%; X, when it is vinyl acetate, about 15-30%, and when it is an alkyl acrylate, about 10-55%; (3) 2-40 parts of an elastomer; (4) 1-10 parts of a blowing agent; (5) 0-10 parts of an activator for the blowing agent; (6) 0.5-10 parts of a curing agent for the E/X/Y terpolymer selected from peroxides, sulfur and sulfur-releasing agents, and diamines and their precursors; (7) 0-15 parts of a processing aid; and (8) 0-100 parts of a filler.
Claim 2
Dependent Claim 233 words
A compatible foamable, readily formable, curable polymer blend consisting essentially of the following components present in the following approximate weight amounts: (1) 50-100 parts of a dipolymer E/A or terpolymer E/A/B, wherein E is ethylene; A is acrylic or methacrylic acid; and B is n-butyl or isobutyl acrylate; the weight proportion of monomer A in both the dipolymer and the terpolymer being about 2-20% and the weight proportion of monomer B in the terpolymer being at most about 23%; the carboxylic acid groups in either type of polymer being either unneutralized or neutralized to an extent of at most about 71% with metal ions having a valency of from 1 to 3; (2) 2-40 parts of a terpolymer E/X/Y, where E is ethylene; X is vinyl acetate or a C 1 -C 8 alkyl acrylate; and Y is CO or SO 2 ; the weight proportions of X and Y being as follows: Y about 1-15%; X, when it is vinyl acetate, about 15-30%, and when it is an alkyl acrylate, about 10-55%; (3) 2-40 parts of an elastomer; (4) 1-10 parts of a blowing agent; (5) 0-10 parts of an activator for the blowing agent; (6) 0.5-10 parts of a curing agent for the E/X/Y terpolymer selected from peroxides, sulfur and sulfur-releasing agents, and diamines and their precursors; (7) 0-15 parts of a processing aid; and (8) 0-100 parts of a filler.
Claim 3
Dependent Claim 26 words
A blend of claim 1 wherein monomer A is methacrylic acid, and the weight proportion of methacrylic acid in the dipolymer or terpolymer (1) is 8-15%.
Claim 4
Dependent Claim 22 words
A blend of claim 2 wherein the neutralizing metal ions are selected from the group consisting of sodium, zinc, magnesium, and aluminum.
Claim 5
Dependent Claim 11 words
A blend of claim 1 wherein monomer B is n-butyl acrylate.
Claim 6
Dependent Claim 11 words
A blend of claim 1 wherein monomer B is isobutyl acrylate.
Claim 7
Dependent Claim 18 words
A blend of claim 1 wherein the amount of dipolymer or terpolymer (1) is 75-90 parts by weight.
Claim 8
Dependent Claim 11 words
A blend of claim 1 wherein monomer Y is carbon monoxide.
Claim 9
Dependent Claim 11 words
A blend of claim 7 wherein monomer X is vinyl acetate.
Claim 10
Dependent Claim 21 words
A blend of claim 8 wherein the amount of carbon monoxide in the terpolymer is at most about 7% by weight.
Claim 11
Dependent Claim 12 words
A blend of claim 7 wherein monomer X is an alkyl acrylate.
Claim 12
Dependent Claim 26 words
A blend of claim 10 wherein the alkyl acrylate is n-butyl acrylate, which is present in the terpolymer in an amount of about 15-35% by weight.
Claim 13
Dependent Claim 8 words
A blend of claim 1 which contains fillers.
Claim 14
Dependent Claim 9 words
A blend of claim 1 which contains processing aids.
Claim 15
Dependent Claim 27 words
A blend of claim 1 which contains a blowing agent activator in an amount of at least 0.5 part per 100 parts by weight of polymer blend.
Claim 16
Dependent Claim 14 words
A blend of claim 14 wherein the activator is zinc oxide or zinc stearate.
Claim 17
Dependent Claim 20 words
A blend of claim 1 wherein the elastomer is selected from the group consisting of natural rubber, polyisoprene, and polyurethanes.
Claim 18
Dependent Claim 11 words
A blend of claim 1 wherein the blowing agent is azodicarbonamide.
Claim 19
Dependent Claim 12 words
A blend of claim 1 wherein the curing agent is a peroxide.

References Cited (Backward Citations)

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US3755208A Cited
US4247498A Cited
US4171411A Cited
US4251584A Cited
US4370423A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-30 1988-04-30 1988-10-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-30 1992-04-30 1992-10-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-30 1996-04-30 1996-10-30 $7700.00 Window Closed / Lapsed

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