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US4478740A Expired / Lapsed US ⏱️ 0.0 years remaining

Benzonitriles

Assignee: Merck Patent GmbH
•
Filing: 1983-02-18
•
Granted: 1984-10-23
•
Expires: 2003-02-18
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Abstract

Abstract New benzonitriles of formula I ##STR1## wherein R 1 and R 2 are each alkyl groups of 1-8 C atoms, and one of these radicals can also be alkoxy of 1-8 C atoms, and Q is one or two radicals selected from 1,4-phenylene, 1,4-cyclohexylene and/or 1,4-bicyclo[2.2.2] octylene, are very useful for preparing liquid crystallene dielectrics and electrooptical display elements based thereon.

Inventors

  • 👤 Rudolf Eidenschink
  • 👤 Jurgen Eichler
  • 👤 Georg Weber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 22:07
CPC Classifications
C; C07; C07C; C07C255/00; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/08; C09K19/10; C09K19/12; C09K19/30; C09K19/3001; C09K19/3003; C09K19/32; C09K19/321

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 49 words
A benzonitrile of the formula ##STR5## wherein R 1 and R 2 are each independently alkyl of 1-8 C atoms, or one is C 1-8 -alkyl and the other is alkoxy of 1-8 C atoms; and Q is one or two groups selected from 1.4-phenylene, 1,4-cyclohexylene and/or 1,4-bicyclo[2.2.2 ]-octylene.
Claim 2
Dependent Claim 49 words
A benzonitrile of the formula ##STR5## wherein R 1 and R 2 are each independently alkyl of 1-8 C atoms, or one is C 1-8 -alkyl and the other is alkoxy of 1-8 C atoms; and Q is one or two groups selected from 1.4-phenylene, 1,4-cyclohexylene and/or 1,4-bicyclo[2.2.2 ]-octylene.
Claim 3
Dependent Claim 40 words
A compound of claim 1 of the formula R.sup.1 --Phe--Phe(CN)--R.sup.2 R.sup.1 --Cy--Phe(CN)--R.sup.2 R.sup.1 Cy--Phe--Phe(CN)--R.sup.2 R.sup.1 --Bi--Phe--Phe(CN)--R.sup.2, wherein Phe is 1,4-phenylene, Cy is 1,4-cyclohexylene, Bi is 1,4-bicyclo[2.2.2]octylene and Phe(CN) is 1,4-phenylene substituted by nitrilo in the 2-, 3-, 5- or 6-position.
Claim 4
Dependent Claim 46 words
A compound of claim 1 of the formula R.sup.1 --Bi--Phe(CN)--R.sup.2 R.sup.1 --Cy--Cy--Phe(CN)--R.sup.2 R.sup.1 --Phe--Phe--Phe(CN)--R.sup.2 R.sup.1 --Phe--Cy--Phe(CN)--R.sup.2 R.sup.1 --Bi--Cy--Phe(CN)--R.sup.2 R.sup.1 --Phe--Bi--Phe(CN)--R.sup.2 R.sup.1 --Bi--Bi--Phe(CN)--R.sup.2 wherein Phe is 1,4-phenylene, Cy is 1,4-cyclohexylene, Bi is 1,4-bicyclo[2.2.2]octylene and Phe(CN) is 1,4-phenylene substituted by nitrilo in the 2-, 3-, 5- or 6-position.
Claim 5
Dependent Claim 14 words
A compound of claim 1 wherein R 1 and R 2 are straight chained.
Claim 6
Dependent Claim 23 words
A compound of claim 1 wherein only one of R 1 or R 2 is branched and it has only one chain branching.
Claim 7
Dependent Claim 16 words
A compound of claim 1 wherein R 1 and R 2 each have 3-5 C atoms.
Claim 8
Dependent Claim 13 words
A compound of claim 4 wherein R 1 and R 2 are alkyl.
Claim 9
Dependent Claim 13 words
A compound of claim 2 of the formula R.sup.1 --Phe--Phe(CN)--R.sup.2 or R.sup.1 --Bi--Phe--Phe(CN)--R.sup.2.
Claim 10
Dependent Claim 18 words
A compound of claim 3 of the formula R.sup.1 --Bi--Phe(CN)--R.sup.2 R.sup.1 --Phe--Phe--Phe(CN)--R.sup.2 R.sup.1 --Bi--Cy--Phe(CN)--R.sup.2 R.sup.1 --Phe--Bi--Phe(CN)--R.sup.2 R.sup.1 --Bi--Bi--Phe(CN)--R.sup.2.
Claim 11
Dependent Claim 20 words
A compound of claim 1 of the formula R.sup.1 --Cy--Bi--Phe(CN)--R.sup.2 R.sup.1 --Bi--Phe--Phe(CN)--R.sup.2 R.sup.1 --Bi--Phe(CN)--R.sup.2 R.sup.1 --Bi--Cy--Phe(CN)--R.sup.2 R.sup.1 --Phe--Bi--Phe(CN)--R.sup.2 R.sup.1 --Bi--Bi--Phe(CN)--R.sup.2.
Claim 12
Dependent Claim 27 words
A liquid crystal dielectric useful in electrooptical display elements comprising at least two liquid crystal compounds, wherein at least one compound is a benzonitrile of claim 1.
Claim 13
Dependent Claim 12 words
A liquid crystal dielectric of claim 11 comprising 3-12 liquid crystal compounds.
Claim 14
Dependent Claim 17 words
A liquid crystal dielectric of claim 11 wherein the amount of said benzonitrile is 0.1-60 wt. %.
Claim 15
Dependent Claim 26 words
In an electrooptical display element based on a liquid crystal cell comprising a liquid crystal dielectric, the improvement wherein the dielectric is that of claim 11.

References Cited (Backward Citations)

US4130502A Cited
GB2027027A Cited
US4349452A Cited
US4368135A Cited
US4415470A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-10-23 1988-04-23 1988-10-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-10-23 1992-04-23 1992-10-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-10-23 1996-04-23 1996-10-23 $7700.00 Window Closed / Lapsed

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