US4474950A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Cellulose ethers having improved dispersing properties
Assignee: Hoechst AG
•
Filing: 1983-08-26
•
Granted: 1984-10-02
•
Expires: 2003-08-26
Abstract
Abstract Modified cellulose reaction products, which are dispersible in aqueous media over a broad pH range without lump formation, are prepared by reacting water-soluble cellulose ether with a specified silane modifying agent in the amount of from 0.0001 to 0.12 mole of modifying agent per mole of cellulose in the cellulose ether.
Inventors
- 👤 Utz-Hellmuth Felcht
- 👤 Helmut Berenbold
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 14:06
CPC Classifications
C; C08; C08B; C08B11/00; C08B11/20; C08B15/00; C08B15/05
Claims Analysis
Total Claims: 28
Claim 1
Independent Claim
322 words
A process for preparing a modified cellulose reaction product, which is dispersible in aqueous media over a broad pH range without lump formation, by reacting water-soluble cellulose ether with a modifying agent in the amount of from 0.0001 to 0.12 mole of modifying agent per mole of cellulose in the cellulose ether; the modifying agent being a silane, R--R 4 , in which R is of the formula ##STR2## and wherein R 1 is alkyl having from 1 to 4 carbon atoms, alkenyl having from 1 to 4 carbon atoms or carbocyclic aryl having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being ring substituted by a member selected from the group consisting of chloro, bromo, alkoxy having from 1 to 4 carbon atoms, carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and phenyl; R 2 is --H, one of the meanings of R 1 or one of the meanings of R 4 ; R 3 is one of the meanings of R 2 ; and R 4 is alkoxy having from 1 to 4 carbon atoms and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aliphatic carboxylic acid acyloxy having up to 5 carbon atoms, aromatic carboxylic acid acyloxy having one or two 6-membered carbocyclic rings and up to 16 carbon atoms; O--R; or NH--R.
Claim 2
Dependent Claim
322 words
A process for preparing a modified cellulose reaction product, which is dispersible in aqueous media over a broad pH range without lump formation, by reacting water-soluble cellulose ether with a modifying agent in the amount of from 0.0001 to 0.12 mole of modifying agent per mole of cellulose in the cellulose ether; the modifying agent being a silane, R--R 4 , in which R is of the formula ##STR2## and wherein R 1 is alkyl having from 1 to 4 carbon atoms, alkenyl having from 1 to 4 carbon atoms or carbocyclic aryl having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being ring substituted by a member selected from the group consisting of chloro, bromo, alkoxy having from 1 to 4 carbon atoms, carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and phenyl; R 2 is --H, one of the meanings of R 1 or one of the meanings of R 4 ; R 3 is one of the meanings of R 2 ; and R 4 is alkoxy having from 1 to 4 carbon atoms and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aliphatic carboxylic acid acyloxy having up to 5 carbon atoms, aromatic carboxylic acid acyloxy having one or two 6-membered carbocyclic rings and up to 16 carbon atoms; O--R; or NH--R.
Claim 3
Dependent Claim
27 words
A process as claimed in claim 1, wherein R 1 denotes alkyl and R 3 is the same as R 4 and denotes optionally-substituted alkoxy or alkanoyloxy.
Claim 4
Dependent Claim
43 words
A process as claimed in claim 2, wherein R 1 denotes alkyl and R 2 is the same as R 3 and R 4 and denotes alkanoyloxy or alkoxy optionally being substituted with alkoxy, all alkyl groups having 1 or 2 carbon atoms.
Claim 5
Dependent Claim
27 words
A process as claimed in claim 1, which comprises reacting from 0.0005 to 0.1 mole of the modifying agent per mole of cellulose in the cellulose ether.
Claim 6
Dependent Claim
27 words
A process as claimed in claim 2, which comprises reacting from 0.0005 to 0.1 mole of the modifying agent per mole of cellulose in the cellulose ether.
Claim 7
Dependent Claim
27 words
A process as claimed in claim 3, which comprises reacting from 0.0005 to 0.1 mole of the modifying agent per mole of cellulose in the cellulose ether.
Claim 8
Dependent Claim
26 words
A process as claimed in claim 1, which comprises reacting the cellulose ether with the modifying agent and in contact with water-soluble organic solvent and water.
Claim 9
Dependent Claim
26 words
A process as claimed in claim 2, which comprises reacting the cellulose ether with the modifying agent and in contact with water-soluble organic solvent and water.
Claim 10
Dependent Claim
26 words
A process as claimed in claim 3, which comprises reacting the cellulose ether with the modifying agent and in contact with water-soluble organic solvent and water.
Claim 11
Dependent Claim
26 words
A process as claimed in claim 4, which comprises reacting the cellulose ether with the modifying agent and in contact with water-soluble organic solvent and water.
Claim 12
Dependent Claim
26 words
A process as claimed in claim 5, which comprises reacting the cellulose ether with the modifying agent and in contact with water-soluble organic solvent and water.
Claim 13
Dependent Claim
26 words
A process as claimed in claim 6, which comprises reacting the cellulose ether with the modifying agent and in contact with water-soluble organic solvent and water.
Claim 14
Dependent Claim
37 words
A process as claimed in claim 1, wherein the water-soluble cellulose ether is a hydroxyalkylcellulose or an alkyl-hydroxyalkylcellulose, the alkyl radical having 1 or 2 carbon atoms and the hydroxyalkyl radical from 2 to 4 carbon atoms.
Claim 15
Dependent Claim
38 words
A process as claimed in claim 2, wherein the water-soluble cellulose ether is a hydroxyalkylcellulose or an alkyl-hydroxyalkylcellulose, the alkyl radical having 1 or 2 carbon atoms and the hydroxyalkyl radical having from 2 to 4 carbon atoms.
Claim 16
Dependent Claim
38 words
A process as claimed in claim 3, wherein the water-soluble cellulose ether is a hydroxyalkylcellulose or an alkyl-hydroxyalkylcellulose, the alkyl radical having 1 or 2 carbon atoms and the hydroxyalkyl radical having from 2 to 4 carbon atoms.
Claim 17
Dependent Claim
38 words
A process as claimed in claim 4, wherein the water-soluble cellulose ether is a hydroxyalkylcellulose or an alkyl-hydroxyalkylcellulose, the alkyl radical having 1 or 2 carbon atoms and the hydroxyalkyl radical having from 2 to 4 carbon atoms.
Claim 18
Dependent Claim
38 words
A process as claimed in claim 7, wherein the water-soluble cellulose ether is a hydroxyalkylcellulose or an alkyl-hydroxyalkylcellulose, the alkyl radical having 1 or 2 carbon atoms and the hydroxyalkyl radical having from 2 to 4 carbon atoms.
Claim 19
Dependent Claim
15 words
A process as claimed in claim 1, wherein the water-soluble cellulose ether is a hydroxyethylcellulose.
Claim 20
Dependent Claim
15 words
A process as claimed in claim 2, wherein the water-soluble cellulose ether is a hydroxyethylcellulose.
Claim 21
Dependent Claim
15 words
A process as claimed in claim 3, wherein the water-soluble cellulose ether is a hydroxyethylcellulose.
Claim 22
Dependent Claim
15 words
A process as claimed in claim 4, wherein the water-soluble cellulose ether is a hydroxyethylcellulose.
Claim 23
Dependent Claim
15 words
A process as claimed in claim 7, wherein the water-soluble cellulose ether is a hydroxyethylcellulose.
Claim 24
Dependent Claim
15 words
A process as claimed in claim 13, wherein the water-soluble cellulose ether is a hydroxyethylcellulose.
Claim 25
Dependent Claim
304 words
A process for rendering water-soluble cellulose ether dispersible in aqueous media over a broad pH range without lump formation which consists essentially of reacting with the cellulose ether from 0.0001 to 0.12 mole of silane (R 4 --R) per mole of cellulose; R, in the silane structure, being of the formula: ##STR3## wherein R 1 is alkyl having from 1 to 4 carbon atoms, alkenyl having from 1 to 4 carbon atoms or carbocyclic aryl having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being ring substituted by a member selected from the group consisting of chloro, bromo, alkoxy having from 1 to 4 carbon atoms, carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and phenyl; R 2 is --H, one of the meanings of R 1 or one of the meanings of R 4 ; R 3 is one of the meanings of R 2 ; and R 4 is alkoxy having from 1 to 4 carbon atoms and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aliphatic carboxylic acid acyloxy having up to 5 carbon atoms; aromatic carboxylic acid acyloxy having one or two 6-membered carbocyclic rings and up to 16 carbon atoms; O--R; or NH--R.
Claim 26
Dependent Claim
304 words
A process for rendering water-soluble cellulose ether dispersible in aqueous media over a broad pH range without lump formation which consists essentially of reacting with the cellulose ether from 0.0001 to 0.12 mole of silane (R 4 --R) per mole of cellulose; R, in the silane structure, being of the formula: ##STR3## wherein R 1 is alkyl having from 1 to 4 carbon atoms, alkenyl having from 1 to 4 carbon atoms or carbocyclic aryl having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being ring substituted by a member selected from the group consisting of chloro, bromo, alkoxy having from 1 to 4 carbon atoms, carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and phenyl; R 2 is --H, one of the meanings of R 1 or one of the meanings of R 4 ; R 3 is one of the meanings of R 2 ; and R 4 is alkoxy having from 1 to 4 carbon atoms and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aliphatic carboxylic acid acyloxy having up to 5 carbon atoms; aromatic carboxylic acid acyloxy having one or two 6-membered carbocyclic rings and up to 16 carbon atoms; O--R; or NH--R.
Claim 27
Dependent Claim
310 words
A (cellulose ether)/silane reaction product which is dispersible in aqueous media over a broad pH range without lump formation, which is based upon from 0.0001 to 0.12 mole of silane per mole of cellulose and wherein: (a) the cellulose ether is water-soluble cellulose ether and (b) the silane is R 4 --R, R being of the formula: ##STR4## wherein R 1 is alkyl having from 1 to 4 carbon atoms, alkenyl having from 1 to 4 carbon atoms or carbocyclic aryl and one or two 6-membered rings, having up to 15 carbon atoms (including aliphatic side groups) and optionally being ring substituted by a member selected from the group consisting of chloro, bromo, alkoxy having from 1 to 4 carbon atoms, carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and phenyl; R 2 is --H, one of the meanings of R 1 or one of the meanings of R 4 ; R 3 is one of the meanings of R 2 ; and R 4 is alkoxy having from 1 to 4 carbon atoms and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aliphatic carboxylic acid acyloxy having up to 5 carbon atoms; aromatic carboxylic acid acyloxy having one or two 6-membered carbocyclic rings and up to 16 carbon atoms; O--R; or NH--R.
Claim 28
Dependent Claim
310 words
A (cellulose ether)/silane reaction product which is dispersible in aqueous media over a broad pH range without lump formation, which is based upon from 0.0001 to 0.12 mole of silane per mole of cellulose and wherein: (a) the cellulose ether is water-soluble cellulose ether and (b) the silane is R 4 --R, R being of the formula: ##STR4## wherein R 1 is alkyl having from 1 to 4 carbon atoms, alkenyl having from 1 to 4 carbon atoms or carbocyclic aryl and one or two 6-membered rings, having up to 15 carbon atoms (including aliphatic side groups) and optionally being ring substituted by a member selected from the group consisting of chloro, bromo, alkoxy having from 1 to 4 carbon atoms, carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and phenyl; R 2 is --H, one of the meanings of R 1 or one of the meanings of R 4 ; R 3 is one of the meanings of R 2 ; and R 4 is alkoxy having from 1 to 4 carbon atoms and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and carbocyclic aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups) and optionally being substituted by a member selected from the group consisting of alkoxy having from 1 to 4 carbon atoms and aryloxy having one or two 6-membered rings and up to 15 carbon atoms (including aliphatic side groups); aliphatic carboxylic acid acyloxy having up to 5 carbon atoms; aromatic carboxylic acid acyloxy having one or two 6-membered carbocyclic rings and up to 16 carbon atoms; O--R; or NH--R.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-10-02 | 1988-04-02 | 1988-10-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-10-02 | 1992-04-02 | 1992-10-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-10-02 | 1996-04-02 | 1996-10-02 | $7700.00 | Window Closed / Lapsed |