US4474728A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Neutron absorber pellets with modified microstructure
Assignee: Westinghouse Electric Corp
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Filing: 1981-12-28
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Granted: 1984-10-02
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Expires: 2001-12-28
Abstract
Abstract An improved annular burnable poison pellet of aluminum oxide-boron carbide (Al2O3-B4C) adapted for positioning in the annular space of concentrically disposed zircaloy tubes. Each tubular pellet is fabricated from Al2O3 powders of moderate sintering activity which serves as a matrix for B4C medium size particle distrbution. Special pellet moisture controls are incorporated in the pellet for moisture stability and the pellet is sintered in the temperature range of 1630 DEG -1650 DEG C. This method of fabrication produces a pellet about 2 inch long with a wall thickness of about 0.020 inch to 0.040 inch. Fabricating each pellet to about 70% theoretical density gives an optimum compromise between fabricability, microstructure, strength and moisture absorption.
Inventors
- 👤 Kenneth C. Radford
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 22:55
CPC Classifications
G; G21; G21C; G21C21/00; G21C21/18; G21C3/00; G21C3/42; G21C3/58; G21C3/62; G21C7/00; G21C7/02; G21C7/04; Y; Y02; Y02E; Y02E30/00; Y02E30/30
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
100 words
A sintered burnable absorber pellet for use in a nuclear reactor fuel assembly comprising: a body of burnable absorber material adapted for positioning in the space between a pair of metal rods in said assembly, said material including aluminum oxide which serves as a matrix for a neutron absorbing compound selected from the group of boron, gadolinium, samarium, cadmium, europium, hafnium and indium, and a sintering additive in said material for limiting the moisture adsorption of said material after sintering, said additive including silica containing compounds having an equivalent SiO 2 content of at least 1 wt.% of said material.
Claim 2
Dependent Claim
100 words
A sintered burnable absorber pellet for use in a nuclear reactor fuel assembly comprising: a body of burnable absorber material adapted for positioning in the space between a pair of metal rods in said assembly, said material including aluminum oxide which serves as a matrix for a neutron absorbing compound selected from the group of boron, gadolinium, samarium, cadmium, europium, hafnium and indium, and a sintering additive in said material for limiting the moisture adsorption of said material after sintering, said additive including silica containing compounds having an equivalent SiO 2 content of at least 1 wt.% of said material.
Claim 3
Dependent Claim
20 words
The pellet according to claim 1 wherein the burnable absorber material after sintering has a theoretical density of about 70%.
Claim 4
Dependent Claim
27 words
The pellet according to claim 1 wherein the sintering additive includes thermally degradable compounds which create pores in the absorber material on reduction to their respective oxides.
Claim 5
Dependent Claim
33 words
The pellet according to claim 1 wherein said SiO 2 content is between 1 and 5 wt.% of said material to provide equilibrium moisture levels in the pellet of less than 100 ppm.
Claim 6
Dependent Claim
34 words
The pellet according to claim 2 wherein the aluminum oxide is of moderate sinterability and the sintering additive includes between 1 and 5 wt.% silicon dioxide for imparting adequate moisture stability to the pellet.
Claim 7
Dependent Claim
30 words
The pellet according to claim 5 wherein the silicon dioxide produces a surface film of uniform thickness on particles on the aluminum oxide to impart moisture stability to the pellet.
Claim 8
Dependent Claim
35 words
The pellet according to claim 1 wherein the burnable absorber material includes boron carbide of between 5 and 20 μm particle size and boron carbide comprises between 2 and 25 wt.% of the absorber material.
Claim 9
Dependent Claim
18 words
The pellet according to claim 7 wherein the boron carbide comprises about 15 wt.% of the absorber material.
Claim 10
Dependent Claim
73 words
A sintered burnable absorber for use in a nuclear reactor fuel assembly comprising a sintered pellet of burnable absorber material including moderately sinterable aluminum oxide and boron carbide particles of about 5 to 20 μm size for establishing a theoretical density of about 70% in the pellet, and an additive of about 3-4 wt.% silicic acid for modifying the open surface areas in the pellet and providing adequate moisture stability to the pellet.
Claim 11
Dependent Claim
73 words
A sintered burnable absorber for use in a nuclear reactor fuel assembly comprising a sintered pellet of burnable absorber material including moderately sinterable aluminum oxide and boron carbide particles of about 5 to 20 μm size for establishing a theoretical density of about 70% in the pellet, and an additive of about 3-4 wt.% silicic acid for modifying the open surface areas in the pellet and providing adequate moisture stability to the pellet.
Claim 12
Dependent Claim
115 words
The process of manufacturing a burnable absorber pellet comprising the steps of: mixing a sinterable alumina powder with about 15 wt.% boron carbide of about 5 to 20 μm particle size and an additive sintering aid including silica containing compounds having an equivalent SiO 2 content of at least 1 wt.% of the pellet for imparting moisture stability to the pellet; spray drying the foregoing mixture, forcing the mixture into a pellet and isostatically pressing the pellet into a unified mass, sintering the pellet at a temperature of 1625° C.±25° C. in an inert gas; grinding the pellet to a substantially uniform diameter, and thereafter annealing the pellet to remove strain energy introduced during grinding.
Claim 13
Dependent Claim
115 words
The process of manufacturing a burnable absorber pellet comprising the steps of: mixing a sinterable alumina powder with about 15 wt.% boron carbide of about 5 to 20 μm particle size and an additive sintering aid including silica containing compounds having an equivalent SiO 2 content of at least 1 wt.% of the pellet for imparting moisture stability to the pellet; spray drying the foregoing mixture, forcing the mixture into a pellet and isostatically pressing the pellet into a unified mass, sintering the pellet at a temperature of 1625° C.±25° C. in an inert gas; grinding the pellet to a substantially uniform diameter, and thereafter annealing the pellet to remove strain energy introduced during grinding.
Claim 14
Dependent Claim
32 words
The process of claim 10, wherein said SiO 2 content is between 1 and 5 wt.% of the pellet to provide equilibrium moisture levels in the pellet of less than 100 ppm.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-10-02 | 1988-04-02 | 1988-10-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-10-02 | 1992-04-02 | 1992-10-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-10-02 | 1996-04-02 | 1996-10-02 | $7700.00 | Window Closed / Lapsed |