Silicone-polyimide copolymers, condensation vulcanizable compositions obtained therefrom, and methods for making

Claim 2

Condensation vulcanizable compositions comprising a silanol terminated polydiorganosiloxane-polyimide copolymer.

Claim 3

Condensation vulcanizable compositions comprising by weight (A) 100 parts of a silanol terminated polydiorganosiloxane-polyimide copolymer, (B) 0.002 to 10 parts of a curing agent, (C) 0 to 5 parts of a condensation catalyst and (D) 0 to 3000 parts of a silanol-terminated polydiorganosiloxane.

Claim 4

Condensation vulcanizable compositions comprising by weight (A) 100 parts of a silanol terminated polydiorganosiloxane-polyimide copolymer, (B) 0.002 to 10 parts of a curing agent, (C) 0 to 5 parts of a condensation catalyst and (D) 0 to 3000 parts of a silanol-terminated polydiorganosiloxane.

Claim 5

A condensation vulcanizable composition in accordance with claim 1, which is curable at room temperature.

Claim 6

A condensation vulcanizable composition in accordance with claim 1, which is moisture curable.

Claim 7

A room temperature vulcanizable composition in accordance with claim 1, where the curing agent is an alkoxy silane having the formula, ##STR24## where R 7 is selected from the class consisting of C.sub.(1-13) monovalent hydrocarbon radicals and substituted C.sub.(1-13) monovalent hydrocarbon radicals, R 10 is a C.sub.(1-8) aliphatic organic radical selected from the group consisting of alkyl, alkylether, alkylester, alkylketone, and alkylcyano radicals, or C.sub.(7-13) aralkyl radical, X is a hydrolyzable leaving group selected from the group consisting of acyloxy, amido, amino, carbamato, enoxy, halo, imidato, isocyanato, ketoximato, oximato, thioisocyanato and ureido radicals and a is equal to 0 or 4 inclusive, b is a whole number equal to 0 or 1 and the sum of a+b is equal to from 0 to 4 inclusive.

Claim 8

A room temperature vulcanizable composition in accordance with claim 1, where the curing agent is trimethoxy-N-methylacetamide silane.

Claim 9

A room temperature vulcanizable composition in accordance with claim 1, where the curing agent is methyltriacetoxysilane.

Claim 10

A silicon hydride terminated polyimide of the formula, ##STR25##

Claim 11

A silicon hydride terminated polyimide of the formula, ##STR25##

Claim 12

A silanol terminated polydimethylsiloxane-polyimide copolymer of the formula ##STR26## where x is an integer greater than 2.

Claim 13

A silanol terminated polydimethylsiloxane-polyimide copolymer of the formula ##STR26## where x is an integer greater than 2.

Claim 14

A condensation vulcanizable composition in accordance with claim 1, containing methyltrimethoxysilane.

Claim 15

A silanol or silicon hydride terminated polydiorganosiloxane-polyimide copolymer comprising by weight from 1 to 99% of polyimide blocks of the formula, ##STR27## chemically combined with from 99% to 1% of polydiorganosiloxane blocks of the formula, ##STR28## where R is a divalent radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated aromatic hydrocarbon radicals having from 6-20 carbon atoms, (b) alkylene radicals having from 2-20 carbon atoms and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (d) radicals included by the general formula, ##STR29## Q' is a member selected from the class consisting of ##STR30## x is a whole number from 1 to 5 inclusive, Q is a tetravalent radical selected from ##STR31## where D is a member selected from ##STR32## and R 8 is a divalent radical selected from ##STR33## and divalent organic radicals of the general formula, ##STR34## X is a member selected from the class consisting of divalent radicals of the formula, ##STR35## y is an integer from 1 to 5, R 1 -R 6 are selected from hydrogen and C.sub.(1-8) alkyl radicals, R 7 is selected from the class consisting of C.sub.(1-13) monovalent hydrocarbon radicals and substituted C.sub.(1-13) monovalent hydrocarbon radicals, Y is a divalent radical selected from --O-- and --C(R 1 ) 2 --, n is an integer equal to 0-200 inclusive, m is an integer equal to 1-2000 inclusive and p is equal to 0 or 1.

Claim 16

A silanol or silicon hydride terminated polydiorganosiloxane-polyimide copolymer comprising by weight from 1 to 99% of polyimide blocks of the formula, ##STR27## chemically combined with from 99% to 1% of polydiorganosiloxane blocks of the formula, ##STR28## where R is a divalent radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated aromatic hydrocarbon radicals having from 6-20 carbon atoms, (b) alkylene radicals having from 2-20 carbon atoms and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (d) radicals included by the general formula, ##STR29## Q' is a member selected from the class consisting of ##STR30## x is a whole number from 1 to 5 inclusive, Q is a tetravalent radical selected from ##STR31## where D is a member selected from ##STR32## and R 8 is a divalent radical selected from ##STR33## and divalent organic radicals of the general formula, ##STR34## X is a member selected from the class consisting of divalent radicals of the formula, ##STR35## y is an integer from 1 to 5, R 1 -R 6 are selected from hydrogen and C.sub.(1-8) alkyl radicals, R 7 is selected from the class consisting of C.sub.(1-13) monovalent hydrocarbon radicals and substituted C.sub.(1-13) monovalent hydrocarbon radicals, Y is a divalent radical selected from --O-- and --C(R 1 ) 2 --, n is an integer equal to 0-200 inclusive, m is an integer equal to 1-2000 inclusive and p is equal to 0 or 1.

Claim 17

A silicon hydride terminated polyimide having the formula, ##STR36## where R is a divalent radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated aromatic hydrocarbon aromatic hydrocarbon radicals having from 6-20 carbon atoms, (b) alkylene radicals having from 2-20 carbon atoms and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (d) radicals included by the general formula, ##STR37## Q' is a member selected from the class consisting of ##STR38## x is a whole number from 1 to 5 inclusive, Q is a tetravalent radical selected from ##STR39## where D is a member selected from ##STR40## and R 8 is a divalent radical selected from ##STR41## and divalent organic radicals of the general formula, ##STR42## X is a member selected from the class consisting of divalent radicals of the formula, ##STR43## y is an integer from 1 to 5, R 1 -R 6 are selected from hydrogen and C.sub.(1-8) alkyl radicals, R 7 is selected from the class consisting of C.sub.(1-13) monovalent hydrocarbon radicals and substituted C.sub.(1-13) monovalent hydrocarbon radicals, Y is a divalent radical selected from --O-- and --C(R 1 ) 2 --, n is an integer equal to 0-200 inclusive, m is an integer equal to 1-2000 inclusive and p is equal to 0 or 1.

Claim 18

A silicon hydride terminated polyimide having the formula, ##STR36## where R is a divalent radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated aromatic hydrocarbon aromatic hydrocarbon radicals having from 6-20 carbon atoms, (b) alkylene radicals having from 2-20 carbon atoms and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (d) radicals included by the general formula, ##STR37## Q' is a member selected from the class consisting of ##STR38## x is a whole number from 1 to 5 inclusive, Q is a tetravalent radical selected from ##STR39## where D is a member selected from ##STR40## and R 8 is a divalent radical selected from ##STR41## and divalent organic radicals of the general formula, ##STR42## X is a member selected from the class consisting of divalent radicals of the formula, ##STR43## y is an integer from 1 to 5, R 1 -R 6 are selected from hydrogen and C.sub.(1-8) alkyl radicals, R 7 is selected from the class consisting of C.sub.(1-13) monovalent hydrocarbon radicals and substituted C.sub.(1-13) monovalent hydrocarbon radicals, Y is a divalent radical selected from --O-- and --C(R 1 ) 2 --, n is an integer equal to 0-200 inclusive, m is an integer equal to 1-2000 inclusive and p is equal to 0 or 1.

Claim 19

A silanol terminated polyimide having the formula, ##STR44## where Z is a divalent group shown by the formula, ##STR45## R is a divalent radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated aromatic hydrocarbon radicals having from 6-20 carbon atoms, (b) alkylene radicals having from 2-20 carbon atoms and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (d) radicals included by the general formula, ##STR46## Q' is a member selected from the class consisting of ##STR47## x is a whole number from 1 to 5 inclusive, Q is a tetravalent radical selected from ##STR48## where D is a member selected from ##STR49## and R 8 is a divalent radical selected from ##STR50## and divalent organic radicals of the general formula, ##STR51## X is a member selected from the class consisting of divalent radicals of the formula, ##STR52## y is an integer from 1 to 5, R 1 -R 6 are selected from hydrogen and C.sub.(1-8) alkyl radicals, R 7 is selected from the class consisting of C.sub.(1-13) monovalent hydrocarbon radicals and substituted C.sub.(1-13) monovalent hydrocarbon radicals, R 9 is selected from hydrogen and R 7 , Y is a divalent radical selected from --O-- and --C(R 1 ) 2 --, n is an integer equal to 0-200 inclusive, p is equal to 0 or 1, r is a whole number equal to 0 or 1, m is an integer equal to 1-2000 inclusive and l is an integer having a value of from about 1 to 10 4 inclusive.

Claim 20

A silanol terminated polyimide having the formula, ##STR44## where Z is a divalent group shown by the formula, ##STR45## R is a divalent radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated aromatic hydrocarbon radicals having from 6-20 carbon atoms, (b) alkylene radicals having from 2-20 carbon atoms and cycloalkylene radicals having from 2-20 carbon atoms, (c) C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (d) radicals included by the general formula, ##STR46## Q' is a member selected from the class consisting of ##STR47## x is a whole number from 1 to 5 inclusive, Q is a tetravalent radical selected from ##STR48## where D is a member selected from ##STR49## and R 8 is a divalent radical selected from ##STR50## and divalent organic radicals of the general formula, ##STR51## X is a member selected from the class consisting of divalent radicals of the formula, ##STR52## y is an integer from 1 to 5, R 1 -R 6 are selected from hydrogen and C.sub.(1-8) alkyl radicals, R 7 is selected from the class consisting of C.sub.(1-13) monovalent hydrocarbon radicals and substituted C.sub.(1-13) monovalent hydrocarbon radicals, R 9 is selected from hydrogen and R 7 , Y is a divalent radical selected from --O-- and --C(R 1 ) 2 --, n is an integer equal to 0-200 inclusive, p is equal to 0 or 1, r is a whole number equal to 0 or 1, m is an integer equal to 1-2000 inclusive and l is an integer having a value of from about 1 to 10 4 inclusive.