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US4472266A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrodewaxing with Mo, Ni-Mo, or Co-Mo on Zsm-5 type catalysts

Assignee: Mobil Oil AS
•
Filing: 1982-09-27
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Granted: 1984-09-18
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Expires: 2002-09-27
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Abstract

Abstract A high quality lube base stock oil of low pour point and excellent stability is produced from a waxy crude oil fraction in a single-stage hydrodewaxing process by using an improved ZSM-5 type catalyst having nickel-molybdenum, cobalt-molybdenum or a molybdenum hydrogenation agent incorporated thereon.

Inventors

  • 👤 Stephen M. Oleck
  • 👤 Robert C. Wilson, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:00
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/48; C; C10; C10G; C10G2400/00; C10G2400/10

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 131 words
In the process for hydrodewaxing a waxy lube stock having a high pour point wherein said waxy lube stock is contacted under reaction conditions in a single stage with a hydrodewaxing catalyst comprising as the sole zealite an aluminosilicate zeolite of the ZSM-5 type having a silica/alumina ratio of at least about 12 and a constraint index of 1 to about 12 the improvement which comprises reducing the pour point of said waxy lube stock to not greater than +20° F. and increasing the viscosity index of said waxy lube stock relative to the pour point obtained by incorporating onto said catalyst a hydrogenation component comprising molybdenum, cobalt-molybdenum or nickel-molybdenum, said hydrogenation component being present in an amount ranging from about 3 to 20 weight percent based on the total catalyst.
Claim 2
Dependent Claim 131 words
In the process for hydrodewaxing a waxy lube stock having a high pour point wherein said waxy lube stock is contacted under reaction conditions in a single stage with a hydrodewaxing catalyst comprising as the sole zealite an aluminosilicate zeolite of the ZSM-5 type having a silica/alumina ratio of at least about 12 and a constraint index of 1 to about 12 the improvement which comprises reducing the pour point of said waxy lube stock to not greater than +20° F. and increasing the viscosity index of said waxy lube stock relative to the pour point obtained by incorporating onto said catalyst a hydrogenation component comprising molybdenum, cobalt-molybdenum or nickel-molybdenum, said hydrogenation component being present in an amount ranging from about 3 to 20 weight percent based on the total catalyst.
Claim 3
Dependent Claim 26 words
The process of claim 1 wherein said waxy lube stock is contacted with said catalyst at a temperature of about 500° F. to about 675° F.
Claim 4
Dependent Claim 26 words
The process of claim 1 wherein said catalyst comprises an aluminosilicate zeolite having a crystal framework density of not less than 1.6 grams per cubic centimeter.
Claim 5
Dependent Claim 12 words
The process of claim 1 wherein said catalyst is ZSM-5 containing nickel-molybdenum.
Claim 6
Dependent Claim 12 words
The process of claim 1 wherein said catalyst is ZSM-5 containing molybdenum.
Claim 7
Dependent Claim 12 words
The process of claim 1 wherein said catalyst is ZSM-5 containing cobalt-molybdenum.

References Cited (Backward Citations)

US3692858A Cited
US3968024A Cited
US4176050A Cited
US4313817A Cited
US4229282A Cited
US4213847A Cited
US4297243A Cited
US4294687A Cited
US4372839A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-18 1988-03-19 1988-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-18 1992-03-19 1992-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-18 1996-03-19 1996-09-18 $7700.00 Window Closed / Lapsed

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