US4472265A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Dormant mesophase pitch
Assignee: Fuji Standard Research Inc
•
Filing: 1981-12-10
•
Granted: 1984-09-18
•
Expires: 2001-12-10
Abstract
Abstract A novel carbonaceous pitch which is optically isotropic in nature and which turns into optically anisotropic when shear forces are applied thereto. The carbonaceous pitch may be obtained by hydrogenating the mesophase of a mesophase pitch to the extent that the mesophase is rendered soluble in quinoline. The carbonaceous pitch is useful as a binder and an impregnator and as a precursor material for a highly oriented, high-strength and high-modulus carbon fiber, needle coke or the like carbonaceous materials.
Inventors
- 👤 Sugio Otani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:21
CPC Classifications
C; C10; C10C; C10C3/00; D; D01; D01F; D01F9/00; D01F9/08; D01F9/12; D01F9/14; D01F9/145
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
60 words
A carbonaceous pitch comprising dormant anisotropic components which are partially hydrogenated, polycyclic polycondensed ring aromatic hydrocarbons derived from the mesophase of a mesophase pitch by hydrogenation of said mesophase and which are soluble in quinoline, said carbonaceous pitch being optically isotropic in nature but, upon being subjected to shear forces in one direction, capable of being oriented in said direction.
Claim 2
Dependent Claim
60 words
A carbonaceous pitch comprising dormant anisotropic components which are partially hydrogenated, polycyclic polycondensed ring aromatic hydrocarbons derived from the mesophase of a mesophase pitch by hydrogenation of said mesophase and which are soluble in quinoline, said carbonaceous pitch being optically isotropic in nature but, upon being subjected to shear forces in one direction, capable of being oriented in said direction.
Claim 3
Dependent Claim
18 words
A carbonaceous pitch as claimed in claim 1, and having a H/C atomic ratio of 0.55 to 1.2.
Claim 4
Dependent Claim
22 words
A carbonaceous pitch as claimed in claim 1, wherein said mesophase pitch has a mesophase content of 1 to 90 wt %.
Claim 5
Dependent Claim
22 words
A carbonaceous pitch as claimed in claim 1, wherein said mesophase pitch has a mesophase content of 5 to 70 wt %.
Claim 6
Dependent Claim
19 words
A carbonaceous pitch as claimed in claim 1, and being a homogeneous liquid when heated above its melting point.
Claim 7
Dependent Claim
19 words
A carbonaceous pitch as claimed in claim 1, and having a melting point of about 150° to 300° C.
Claim 8
Dependent Claim
23 words
A carbonaceous pitch as claimed in claim 1, and exhibiting a viscosity of about 100 poises when heated to 200° to 300° C.
Claim 9
Dependent Claim
54 words
A process for the preparation of a carbonaceous pitch which is optically isotropic in nature but is capable of being oriented in one direction when subjected to shear forces in said direction, comprising providing a mesophase pitch, and hydrogenating the mesophase of said mesophase pitch so that the mesophase is rendered soluble in quinoline.
Claim 10
Dependent Claim
54 words
A process for the preparation of a carbonaceous pitch which is optically isotropic in nature but is capable of being oriented in one direction when subjected to shear forces in said direction, comprising providing a mesophase pitch, and hydrogenating the mesophase of said mesophase pitch so that the mesophase is rendered soluble in quinoline.
Claim 11
Dependent Claim
31 words
A process as claimed in claim 8, wherein said hydrogenation comprises subjecting said mesophase pitch to hydrogenating conditions, so that substantially all the mesophase contained therein is rendered soluble in quinoline.
Claim 12
Dependent Claim
20 words
A process as claimed in claim 8, wherein said mesophase pitch has a H/C atomic ratio of 0.43 to 0.75.
Claim 13
Dependent Claim
20 words
A process as claimed in claim 10, wherein said mesophase pitch has a H/C atomic ratio of 0.45 to 0.65.
Claim 14
Dependent Claim
32 words
A process as claimed in claim 8, wherein the product of said hydrogenation is heated above its melting point for a period of time sufficient to remove low boiling point components therefrom.
Claim 15
Dependent Claim
24 words
A process as claimed in claim 12, wherein the product of said hydrogenation is heated to a temperature of about 450° C. or less.
Claim 16
Dependent Claim
24 words
A process as claimed in claim 13, wherein the product of said hydrogenation is heated to a temperature of about 280° to 430° C.
Claim 17
Dependent Claim
21 words
A process as claimed in claim 8, wherein said mesophase pitch has a mesophase component of 1 to 90 wt %.
Claim 18
Dependent Claim
21 words
A process as claimed in claim 8, wherein said mesophase pitch has a mesophase component of 5 to 70 wt %.
Claim 19
Dependent Claim
116 words
A process for the production of a carbon fiber comprising the steps of: providing a carbonaceous pitch comprising dormant anisotropic components which are partially hydrogenated, polycyclic polycondensed ring aromatic hydrocarbons derived from the mesophase of a mesophase pitch by hydrogenation of said mesophase and which are soluble in quinoline, said carbonaceous pitch being optically isotropic in nature but, upon being subjected to shear forces in one direction, capable of being oriented in said direction; heating said carbonaceous pitch above its melting point; spinning a carbonaceous fiber from said molten pitch; exposing said spun fiber to an oxygen-containing atmosphere so that said spun fiber is rendered infusible; and heat-treating said infusible fiber at temperatures above 800° C.
Claim 20
Dependent Claim
116 words
A process for the production of a carbon fiber comprising the steps of: providing a carbonaceous pitch comprising dormant anisotropic components which are partially hydrogenated, polycyclic polycondensed ring aromatic hydrocarbons derived from the mesophase of a mesophase pitch by hydrogenation of said mesophase and which are soluble in quinoline, said carbonaceous pitch being optically isotropic in nature but, upon being subjected to shear forces in one direction, capable of being oriented in said direction; heating said carbonaceous pitch above its melting point; spinning a carbonaceous fiber from said molten pitch; exposing said spun fiber to an oxygen-containing atmosphere so that said spun fiber is rendered infusible; and heat-treating said infusible fiber at temperatures above 800° C.
Claim 21
Dependent Claim
44 words
A carbonaceous pitch obtained by hydrogenating the mesophase of a mesophase pitch to render said mesophase soluble in quinoline, said carbonaceous pitch being optically isotropic in nature but being capable of being oriented in one direction when subjected to shear forces in said direction.
Claim 22
Dependent Claim
44 words
A carbonaceous pitch obtained by hydrogenating the mesophase of a mesophase pitch to render said mesophase soluble in quinoline, said carbonaceous pitch being optically isotropic in nature but being capable of being oriented in one direction when subjected to shear forces in said direction.
References Cited (Backward Citations)
US2772219A
Cited
US4115527A
Cited
US3723150A
Cited
US3754957A
Cited
US4146576A
Cited
US3745104A
Cited
US3814642A
Cited
US3928170A
Cited
US3787541A
Cited
US3991170A
Cited
US3917806A
Cited
US3974264A
Cited
US4138525A
Cited
US4209500A
Cited
US4184942A
Cited
US4213956A
Cited
US4331620A
Cited
US4272501A
Cited
US4303631A
Cited
EP0044714A2
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-18 | 1988-03-19 | 1988-09-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-18 | 1992-03-19 | 1992-09-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-18 | 1996-03-19 | 1996-09-18 | $7700.00 | Window Closed / Lapsed |