US4472167A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Mild-cure formaldehyde-free durable-press finishing of cotton textiles with glyoxal and glycols
Assignee: United States Department of Agriculture
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Filing: 1983-08-26
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Granted: 1984-09-18
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Expires: 2003-08-26
Abstract
Abstract The use of glycols as coreactive additives with glyoxal in the aluminum sulfate-catalyzed crosslinking of cotton cellulose in the presence of alpha-hydroxy acids as catalyst activators at moderate curing temperatures is disclosed. The cotton textiles so treated are free from the discoloration and excessive tendering produced by glyoxal in the presence of metal salt catalysts at high temperature, are non-nitrogenous and formaldehyde-free, and exhibit high levels of wrinkle resistance and smooth drying properties without the formaldehyde release characteristic of N-methylolamide finishing agents.
Inventors
- 👤 Clark M. Welch
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 08:42
CPC Classifications
D; D06; D06M; D06M13/00; D06M13/10; D06M13/144; D06M13/148; Y; Y10; Y10S; Y10S8/00; Y10S8/17
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
126 words
A process for imparting a high level of wrinkle resistance and smooth drying properties to cellulosic textiles, without the use of formaldehyde, derivatives of formaldehyde, or agents that release formaldehyde, and without additional discoloration or excessive loss of strength in the textile, which process comprises: (a) padding the cellulosic textile with an aqueous solution containing sufficient amounts of glyoxal, glycol, an aluminum salt of a strong inorganic acid, and a water soluble alpha-hydroxy carboxylic acid, to impregnate the cellulosic textile; (b) removing excess treating solution from the textile and heating the textile for sufficient time at sufficient temperature to dry the textile; (c) heating the textile at sufficient temperature and for a sufficient period of time to form the glycol-modified glyoxal durable-press finish in the cellulose.
Claim 2
Dependent Claim
126 words
A process for imparting a high level of wrinkle resistance and smooth drying properties to cellulosic textiles, without the use of formaldehyde, derivatives of formaldehyde, or agents that release formaldehyde, and without additional discoloration or excessive loss of strength in the textile, which process comprises: (a) padding the cellulosic textile with an aqueous solution containing sufficient amounts of glyoxal, glycol, an aluminum salt of a strong inorganic acid, and a water soluble alpha-hydroxy carboxylic acid, to impregnate the cellulosic textile; (b) removing excess treating solution from the textile and heating the textile for sufficient time at sufficient temperature to dry the textile; (c) heating the textile at sufficient temperature and for a sufficient period of time to form the glycol-modified glyoxal durable-press finish in the cellulose.
Claim 3
Dependent Claim
30 words
The process of claim 1 including the additional steps of washing the textile with water to remove excess reagents and drying the textile after the excess reagents have been removed.
Claim 4
Dependent Claim
128 words
The process of claim 1 wherein the treating solution contains from about 1% to 10% by weight of glyoxal, from 0.5 to 8 moles of glycol for each mole of glyoxal present, which glycol has a molecular chain of from 2 to 11 atoms in length connecting two terminal hydroxyl groups, said glycol being selected from the group consisting of terminal straight-chain alkanediols and poly(ethylene glycols), there also being present in the solution from 0.15% to 0.50% by weight of aluminum sulfate having the formula Al 2 (SO 4 ) 3 , and also a watersoluble alpha-hydroxy carboxylic acid having an acid ionization constant from 1×15 -4 to 3×10 -3 and present to the extent of from 1.5 moles to 15 moles per mole of aluminum sulfate present.
Claim 5
Dependent Claim
30 words
The process of claim 3 wherein the textile is dried at from about 45° C. to 105° C. for a period of time from about 0.5 minutes to 30 minutes.
Claim 6
Dependent Claim
42 words
The process of claim 4 wherein the glycol-modified glyoxal durable-press finish is formed in the cellulose by heating the cellulosic textile at a temperature of from 110° C. to 135° C. for a period of time from about 0.5 to 5 minutes.
Claim 7
Dependent Claim
13 words
The process of claim 4 wherein the cellulosic textile is a cotton fabric.
Claim 8
Dependent Claim
28 words
The process of claim 4 wherein the glycol is selected from the group consisting of: ethylene glycol, an alpha,omega-alkanediol, 1,3-propanediol, 1,4-butanediol, poly(ethylene glycol), diethylene glycol, and triethylene glycol.
Claim 9
Dependent Claim
28 words
The process of claim 7 wherein the alpha-hydroxy carboxylic acid is selected from the group consisting of: glycolic acid, lactic acid, tartaric acid, citric acid, and malic acid.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-18 | 1988-03-19 | 1988-09-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-18 | 1992-03-19 | 1992-09-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-18 | 1996-03-19 | 1996-09-18 | $7700.00 | Window Closed / Lapsed |