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US4469908A Expired / Lapsed US ⏱️ 0.0 years remaining

Alkylation of aromatic hydrocarbons

Assignee: Mobil Oil AS
•
Filing: 1982-09-30
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Granted: 1984-09-04
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Expires: 2002-09-30
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Abstract

Abstract A process for the alkylation of aromatic hydrocarbons with alkylating agents having from one to five, and preferably three to five, carbon atoms. The reactants are brought into contact, preferably in the liquid phase, in the presence of a crystalline zeolite catalyst characterized by a silica to alumina ratio of at least 12 and a constraint index within the approximate range of 1-12. The reaction is conducted at 100 DEG C. to 300 DEG C. and a pressure of from about 105 N/m2 to about 2x107 N/m2.

Inventors

  • 👤 George T. Burress

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 14:25
CPC Classifications
C; C07; C07C; C07C2/00; C07C2/86; C07C2/862; C07C2/864; C07C17/00; C07C17/26; C07C17/263; C07C17/2637; C07C17/272; C07C17/275; C07C2/54; C07C2/64; C07C2/66; C07C2529/00; C07C2529/04; C07C2529/06; C07C2529/70

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 84 words
A process for the alkylation of aromatic hydrocarbon compounds comprising contacting the aromatic hydrocarbon with isobutylene in the presence of a crystalline zeolite alkylation catalyst, at a temperature of between about 100° C. and about 300° C., said zeolite alkylation catalyst comprising zeolite ZSM-12, said process being carried out under sufficient pressure to maintain the organic reactants in the liquid phase when brought into contact with said zeolite catalyst, said pressure being between about 10 5 N/m 2 and 2×10 7 N/m 2 .
Claim 2
Dependent Claim 84 words
A process for the alkylation of aromatic hydrocarbon compounds comprising contacting the aromatic hydrocarbon with isobutylene in the presence of a crystalline zeolite alkylation catalyst, at a temperature of between about 100° C. and about 300° C., said zeolite alkylation catalyst comprising zeolite ZSM-12, said process being carried out under sufficient pressure to maintain the organic reactants in the liquid phase when brought into contact with said zeolite catalyst, said pressure being between about 10 5 N/m 2 and 2×10 7 N/m 2 .
Claim 3
Dependent Claim 12 words
A process according to claim 1, wherein said aromatic hydrocarbon is benzene.

References Cited (Backward Citations)

US3251897A Cited
US3385906A Cited
US3755483A Cited
US3751506A Cited
US4049737A Cited
US4291185A Cited
US4393262A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-09-04 1988-03-05 1988-09-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-09-04 1992-03-05 1992-09-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-09-04 1996-03-05 1996-09-04 $7700.00 Window Closed / Lapsed

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