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US4468446A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrostatographic encapsulated toner material improved in powder characteristics

Assignee: Fujifilm Holdings Corp
•
Filing: 1982-09-30
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Granted: 1984-08-28
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Expires: 2002-09-30
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Abstract

Abstract An electrostatographic toner material suitably employable for the pressure fixing process, which comprises encapsulated toner particles having an average particle size in the range from about 0.5 to 1,000 microns, in which the toner particle comprises a pressure fixable adhesive core material containing a colorant and a pressure rupturable shell enclosing the core material, the outer surface of the shell being provided with an organofluoro compound.

Inventors

  • 👤 Takeshi Mikami
  • 👤 Noriyuki Hosoi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 13:32
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/093; G03G9/09307; G03G9/09314; G03G9/09328; G03G9/09335

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 268 words
An electrostatographic toner material comprising encapsulated toner particles having an average particle size in the range from about 0.5 to about 1,000 microns, in which the toner particle comprises a pressure fixable adhesive core material containing a colorant and a pressure rupturable shell enclosing the core material, the outer surface of the shell being provided with an organofluoro compound having the formula (I) (Cf)-(Y).sub.n (I) in which (Cf) is a group of n valency, containing both of at least 3 fluorine atoms and at least 3 carbon atoms, n is 1 or 2, and (Y) is ##STR7## in which M is a hydrogen atom, a cation such as an alkali metal an alkaline earth metal or a quaternary ammonium group, or a hydrocarbon residue containing 1-18 carbon atoms; --AO-- is a poly(alkylene oxide) selected from the group consisting of polyoxyethylene, polyoxypropylene, and a block copolymer of ethylene oxide and propylene oxide, in which the polymerization degree ranges from 2 to 100; R is an alkyl group having 1-18 carbon atoms or an aryl group having 6-18 carbon atoms; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are the same or different and each represents an alkyl or hydroxyalkyl group having 1-4 carbon atoms; X is a halogen atom or R-O-SO 2 -O - group in which R has the same meaning as defined above; Z is a group of atoms for constituting a 5- or 6-membered ring in cooperation with the N atom; and D is an alkylene group having 1-5 carbon atoms.
Claim 2
Dependent Claim 268 words
An electrostatographic toner material comprising encapsulated toner particles having an average particle size in the range from about 0.5 to about 1,000 microns, in which the toner particle comprises a pressure fixable adhesive core material containing a colorant and a pressure rupturable shell enclosing the core material, the outer surface of the shell being provided with an organofluoro compound having the formula (I) (Cf)-(Y).sub.n (I) in which (Cf) is a group of n valency, containing both of at least 3 fluorine atoms and at least 3 carbon atoms, n is 1 or 2, and (Y) is ##STR7## in which M is a hydrogen atom, a cation such as an alkali metal an alkaline earth metal or a quaternary ammonium group, or a hydrocarbon residue containing 1-18 carbon atoms; --AO-- is a poly(alkylene oxide) selected from the group consisting of polyoxyethylene, polyoxypropylene, and a block copolymer of ethylene oxide and propylene oxide, in which the polymerization degree ranges from 2 to 100; R is an alkyl group having 1-18 carbon atoms or an aryl group having 6-18 carbon atoms; R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and R 8 are the same or different and each represents an alkyl or hydroxyalkyl group having 1-4 carbon atoms; X is a halogen atom or R-O-SO 2 -O - group in which R has the same meaning as defined above; Z is a group of atoms for constituting a 5- or 6-membered ring in cooperation with the N atom; and D is an alkylene group having 1-5 carbon atoms.
Claim 3
Dependent Claim 28 words
The electrostatographic toner material as claimed in claim 1, in which the shell is made of a polymer selected from the group consisting of polyurethane, polyurea and polythiourethane.
Claim 4
Dependent Claim 25 words
The electrostatographic toner material as claimed in claim 2, in which the shell is made substantially of a polycondensation product of polyisocyanate, polyol and water.
Claim 5
Dependent Claim 25 words
The electrostatographic toner material as claimed in claim 2, in which the shell is made substantially of a polycondensation product of polyisocyanate, polyol and polyamine.
Claim 6
Dependent Claim 31 words
The electrostatographic toner material as claimed in claim 1, in which the shell is composed substantially of a double layer comprising a polyurethane, polyurea and/or polythiourethane layer and a polyamide layer.
Claim 7
Dependent Claim 30 words
The electrostatographic toner material as claimed in claim 1, in which the pressure fixable adhesive core material is a liquid medium boiling at a temperature of higher than 180° C.
Claim 8
Dependent Claim 22 words
The electrostatographic toner material as claimed in claim 1, in which a flow lubricant is provided onto the surface of the shell.

References Cited (Backward Citations)

US3346612A Cited
US3431412A Cited
US3798167A Cited
US4259426A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-28 1988-02-27 1988-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-28 1992-02-27 1992-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-28 1996-02-27 1996-08-28 $7700.00 Window Closed / Lapsed

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