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US4468337A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the heating and/or thermal conditioning of a building by means of a heat pump operated with a specific mixture of working fluids

Assignee: IFP Energies nouvelles
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Filing: 1983-09-14
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Granted: 1984-08-28
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Expires: 2003-09-14
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Abstract

Abstract Buildings are advantageously heated or heat-conditioned with a heat pump operated with a non-azeotropic mixture of two working fluids. The mixture comprises 99 to 70% by mole of dichlorodifluoromethane (R 12), monochlorodifluoromethane (R 22) or one of the halohydrocarbon azeotropes R 500, R 501 or R 502 with 1 to 30% by mole of trifluoromethane (R 23) or the halohydrocarbon azeotrope R 503.

Inventors

  • 👤 Claude Ramet
  • 👤 Alexandre Rojey

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 11:36
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/02; C09K5/04; C09K5/041; C09K5/044; C09K5/045; F; F25; F25B; F25B30/00; F25B30/02; F25B9/00; F25B9/002; F25B9/006; C09K2205/00; C09K2205/10; C09K2205/12; C09K2205/122

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 189 words
In a cyclic process for heat condition a building by means of a compression heat pump operated with a working fluid, the process comprising the repeated successive steps of (a) compressing a gas phase of a working fluid, (b) cooling the compressed gas phase of the working fluid obtained in step (a), in contact with a cooling fluid at a temperature from about 20° to 75° C., to form a condensed liquid phase of the working fluid, (c) expanding the liquid phase of the working fluid obtained in step (b) and vaporizing at least a portion of the expanded liquid phase of step (c) in contact with a heating fluid at a temperature from about -15° to +40° C. to reconstitute the gas phase of step (a), the improvement comprising using as the working fluid a composition of: (a) 95-80% by mole of (i) R12 being dichlorodifluoromethane, (ii) R500 being by weight 73.8% dichlorodifluoromethane and 26.2% difluoroethane, or (iii) R501 being by weight 75% chlorodifluoromethane and 25% dichlorodifluoromethane; and (b) 5-20% by mole of (i) R23 being trifluoromethane, or (ii) R503 being by weight 40.1% trifluoromethane and 59.9% chlorotrifluoromethane.
Claim 2
Dependent Claim 189 words
In a cyclic process for heat condition a building by means of a compression heat pump operated with a working fluid, the process comprising the repeated successive steps of (a) compressing a gas phase of a working fluid, (b) cooling the compressed gas phase of the working fluid obtained in step (a), in contact with a cooling fluid at a temperature from about 20° to 75° C., to form a condensed liquid phase of the working fluid, (c) expanding the liquid phase of the working fluid obtained in step (b) and vaporizing at least a portion of the expanded liquid phase of step (c) in contact with a heating fluid at a temperature from about -15° to +40° C. to reconstitute the gas phase of step (a), the improvement comprising using as the working fluid a composition of: (a) 95-80% by mole of (i) R12 being dichlorodifluoromethane, (ii) R500 being by weight 73.8% dichlorodifluoromethane and 26.2% difluoroethane, or (iii) R501 being by weight 75% chlorodifluoromethane and 25% dichlorodifluoromethane; and (b) 5-20% by mole of (i) R23 being trifluoromethane, or (ii) R503 being by weight 40.1% trifluoromethane and 59.9% chlorotrifluoromethane.
Claim 3
Dependent Claim 27 words
A process according to claim 1, wherein the composition comprises (a) 95% to 80% by mole of R12 with (b) 5% to 20% by mole of R23.
Claim 4
Dependent Claim 29 words
A process according to claim 1, wherein the composition comprises (a) 92% to 82% by mole of R12 or R500 with (b) 8% to 18% by mole of R23.
Claim 5
Dependent Claim 29 words
A process according to claim 1, wherein the composition comprises (a) 95% to 85% by mole of R12 or R500 with (b) 5% to 15% by mole of R503.
Claim 6
Dependent Claim 77 words
A process according to claim 1, wherein the working fluid is a composition of: (1) 92% to 82% by mole of R12 or R500 with 8% to 18% by mole of R23; or (2) 95% to 85% by mole of R12 or R500 with 5% to 15% by mole of R503; the cooling fluid is at a temperature of from about 40° to 75° C.; and the heating fluid is at a temperature higher than 5° C.
Claim 7
Dependent Claim 117 words
A process according to claim 1, wherein step (b) is conducted up to substantially complete condensation of the working fluid, the resultant substantially condensed working fluid is contacted in heat exchange relationship with a hereinafter defined cooling fluid (F), to subcool said substantially completely condensed working fluid, the subcooled working fluid is partly vaporized in step (d) and the resultant partly vaporized working fluid from step (d) is contacted, as said cooling fluid (F), with said substantially completely condensed, working fluid, and then recycled to step (a), the contact conditions between said fluid (F) and said substantially completely condensed working fluid being such as to complete the vaporization of the subcooled working fluid initiated in step (d).

References Cited (Backward Citations)

SU304282A1 Cited
GB1063416A Cited
US3300996A Cited
US3851494A Cited
EP0011971A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-28 1988-02-27 1988-08-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-28 1992-02-27 1992-08-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-28 1996-02-27 1996-08-28 $7700.00 Window Closed / Lapsed

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