US4465818A
Expired / Lapsed
US
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Room temperature stable, heat activated organopolysiloxane compositions
Assignee: DuPont Toray Specialty Materials KK
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Filing: 1983-03-24
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Granted: 1984-08-14
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Expires: 2003-03-24
Abstract
Abstract Organopolysiloxane compositions which react by way of a hydrosilylation reaction to undergo an increase in viscosity have improved resistance to reaction at room temperature (longer pot life) and/or an improved reaction rate at elevated temperature (shorter cure time) than analogous compositions of the art by incorporating therein an unsaturated hydrocarbon having from 6 to 10 carbon atoms, a terminal acetylenic linkage and an olefinic linkage conjugated therewith. The resulting compositions are useful for preparing various cured siloxanes such as resins, elastomers, gels and foams.
Inventors
- 👤 Akihiko Shirahata
- 👤 Shosaku Sasaki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 02:50
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/01; C08L; C08L83/00; C08L83/04
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
330 words
A composition obtained by a method comprising the mixing of components comprising (a) an alkenyl group-containing organopolysiloxane component comprising at least one siloxane unit having the formula R a 1 R b 2 SiO.sub.(4-a-b)/2 wherein R 1 denotes a silicon-bonded alkenyl group having from 2 to 4 carbon atoms, inclusive, R 2 denotes a silicon-bonded substituted or unsubstituted monovalent hydrocarbon group, a has a value of from 1 to 3, b has a value of from 0 to 2 and a+b has a value of from 1 to 3, all values inclusive, any remaining siloxane units in the alkenyl group-containing organopolysiloxane having the formula R x 2 SiO.sub.(4-x)/2 wherein R 2 is as denoted above and x has a value of from 0 to 3, inclusive; (b) an organohydrogenpolysiloxane component comprising at least one siloxane unit having the formula H c R d 3 SiO.sub.(4-c-d)/2 wherein R 3 denotes a silicon-bonded substituted or unsubstituted monovalent hydrocarbon group, c has a value of from 1 to 3, d has a value of from 0 to 2 and c+d has a value of from 1 to 3, all values inclusive, any remaining siloxane units in the organohydrogenpolysiloxane having the formula R y 3 SiO.sub.(4-y)/2 wherein R 3 is as denoted above and y has a value of from 0 to 3, inclusive; (c) a cure catalyzing amount of a hydrosilylation curing catalyst component for the composition; and (d) a cure inhibiting amount of an unsaturated hydrocarbon component having the formula HC.tbd.C--CR 4 ═CR 5 R 6 wherein each R 4 , R 5 and R 6 denotes, independently, a hydrogen atom, a monovalent hydrocarbon group or a divalent hydrocarbon group with the requirements that the total number of carbon atoms in the R 4 , R 5 and R 6 groups has a value of from 2 to 6 and when R 4 and R 5 or R 5 and R 6 are divalent they are bonded together by their second valence.
Claim 2
Dependent Claim
330 words
A composition obtained by a method comprising the mixing of components comprising (a) an alkenyl group-containing organopolysiloxane component comprising at least one siloxane unit having the formula R a 1 R b 2 SiO.sub.(4-a-b)/2 wherein R 1 denotes a silicon-bonded alkenyl group having from 2 to 4 carbon atoms, inclusive, R 2 denotes a silicon-bonded substituted or unsubstituted monovalent hydrocarbon group, a has a value of from 1 to 3, b has a value of from 0 to 2 and a+b has a value of from 1 to 3, all values inclusive, any remaining siloxane units in the alkenyl group-containing organopolysiloxane having the formula R x 2 SiO.sub.(4-x)/2 wherein R 2 is as denoted above and x has a value of from 0 to 3, inclusive; (b) an organohydrogenpolysiloxane component comprising at least one siloxane unit having the formula H c R d 3 SiO.sub.(4-c-d)/2 wherein R 3 denotes a silicon-bonded substituted or unsubstituted monovalent hydrocarbon group, c has a value of from 1 to 3, d has a value of from 0 to 2 and c+d has a value of from 1 to 3, all values inclusive, any remaining siloxane units in the organohydrogenpolysiloxane having the formula R y 3 SiO.sub.(4-y)/2 wherein R 3 is as denoted above and y has a value of from 0 to 3, inclusive; (c) a cure catalyzing amount of a hydrosilylation curing catalyst component for the composition; and (d) a cure inhibiting amount of an unsaturated hydrocarbon component having the formula HC.tbd.C--CR 4 ═CR 5 R 6 wherein each R 4 , R 5 and R 6 denotes, independently, a hydrogen atom, a monovalent hydrocarbon group or a divalent hydrocarbon group with the requirements that the total number of carbon atoms in the R 4 , R 5 and R 6 groups has a value of from 2 to 6 and when R 4 and R 5 or R 5 and R 6 are divalent they are bonded together by their second valence.
Claim 3
Dependent Claim
45 words
A composition obtained by the method of claim 1 wherein R 1 denotes the vinyl group, component (a) contains an average of at least two silicon-bonded vinyl groups per molecule and component (b) contains an average of at least two silicon-bonded hydrogen atoms per molecule.
Claim 4
Dependent Claim
29 words
A composition obtained by the method of claim 2 wherein the number ratio of silicon-bonded hydrogen atoms to silicon-bonded vinyl groups has a value of from 0.2 to 5.0.
Claim 5
Dependent Claim
19 words
A composition obtained by the method of claim 3 wherein R 2 and R 3 denote the methyl group.
Claim 6
Dependent Claim
16 words
A composition obtained by the method of claim 4 wherein component (a) is a vinyldimethylsiloxane-endblocked polydimethylsiloxane.
Claim 7
Dependent Claim
26 words
A composition obtained by the method of claim 5 wherein component (b) is a trimethylsiloxane-endblocked polymethylhydrogensiloxane having a viscosity of about 10 centipoise at 25° C.
Claim 8
Dependent Claim
26 words
A composition obtained by the method of claim 5 wherein component (b) has the formula Me.sub.3 SiO(Me.sub.2 SiO).sub.3 (MeHSiO).sub.5 SiMe.sub.3 wherein Me denotes the methyl group.
Claim 9
Dependent Claim
14 words
A composition obtained by the method of claim 5 wherein component (d) is 3-methyl-3-pentene-1-yne.
Claim 10
Dependent Claim
14 words
A composition obtained by the method of claim 5 wherein component (d) is 3,5-dimethyl-3-hexene-1-yne.
Claim 11
Dependent Claim
17 words
A composition obtained by the method of claim 4 wherein component (a) is a trimethylsiloxane-endblocked methylvinylsiloxane-co-dimethylsiloxane polysiloxane.
Claim 12
Dependent Claim
26 words
A composition obtained by the method of claim 10 wherein component (b) is a trimethylsiloxane-endblocked polymethylhydrogensiloxane having a viscosity of about 10 centipoise at 25° C.
Claim 13
Dependent Claim
26 words
A composition obtained by the method of claim 10 wherein component (b) has the formula Me.sub.3 SiO(Me.sub.2 SiO).sub.3 (MeHSiO).sub.5 SiMe.sub.3 wherein Me denotes the methyl group.
Claim 14
Dependent Claim
18 words
A composition obtained by the method of claim 3 wherein component (a) contains methyl groups and 3,3,3-trifluoropropyl groups.
Claim 15
Dependent Claim
16 words
A composition obtained by the method of claim 13 wherein component (a) is a vinyldimethylsiloxane-endblocked polymethyl-3,3,3-trifluoropropylsiloxane.
Claim 16
Dependent Claim
18 words
A composition obtained by the method of claim 3 wherein component (a) contains methyl groups and phenyl groups.
Claim 17
Dependent Claim
17 words
A composition obtained by the method of claim 15 wherein component (a) is a phenylmethylvinylsiloxane-endblocked phenylmethylsiloxane-co-dimethylsiloxane polysiloxane.
Claim 18
Dependent Claim
14 words
A composition obtained by the method of claim 16 wherein component (d) is 1-ethynyl-1-cyclohexene.
Claim 19
Dependent Claim
14 words
A composition obtained by the method of claim 1 wherein component (d) is 3-methyl-3-pentene-1-yne.
Claim 20
Dependent Claim
14 words
A composition obtained by the method of claim 1 wherein component (d) is 3,5-dimethyl-3-hexene-1-yne.
Claim 21
Dependent Claim
14 words
A composition obtained by the method of claim 1 wherein component (d) is 1-ethynyl-1-cyclohexene.
References Cited (Backward Citations)
US3445420A
Cited
US3383356A
Cited
US3461185A
Cited
JPS5128119A
Cited
US3983298A
Cited
US3989668A
Cited
US4077937A
Cited
JPS5335983A
Cited
JPS543774A
Cited
US4256870A
Cited
US4347347A
Cited
US4288345A
Cited
US4340710A
Cited
US4336364A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1987-08-14 | 1988-02-13 | 1988-08-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-08-14 | 1992-02-13 | 1992-08-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-08-14 | 1996-02-13 | 1996-08-14 | $7700.00 | Window Closed / Lapsed |