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US4465713A Expired / Lapsed US ⏱️ 0.0 years remaining

Urethane coatings from aliphatic aromatic diisocyanates

Assignee: Dow Chemical Co
•
Filing: 1982-09-20
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Granted: 1984-08-14
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Expires: 2002-09-20
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Abstract

Abstract A surface is coated with a mixture of (i) an aliphatic, aromatic polyisocyanate such as 1,3-bis-(1-isocyanato-1-methylethyl)benzene, and (ii) a polyactive hydrogen compound such as a poly(2-hydroxyethylacrylate), and the mixture is cured under conditions such that an adherent, solid coating is formed on the surface. The coatings of the invention have surprising gloss and lack of yellowness after exposure to ultra-violet light.

Inventors

  • 👤 Michele R. Lock
  • 👤 Kurt C. Frisch, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 21:16
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/74; C08G18/76; C08G18/7614; C08G18/7628; C08G18/765; C08G18/28; C08G18/40; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 126 words
A method for coating a surface with improved gloss and nonyellowing characteristics consisting of a. applying to a surface, a mixture comprising (i) a first component according to the formula ##STR3## wherein A is an organic radical including at least one aromatic ring; each R 1 is independently an aliphatic radical; each n is independently 0 or 1; and each R 2 is independently an organic or inorganic radical selected from the group consisting of a halogen and an aliphatic radical having from one to six carbon atoms, and (ii) a second component comprising a polyahl; and b. curing the mixture; the ratio of the first component and second component, and the curing step being such that an adherent, solid coating is formed on said surface.
Claim 2
Independent Claim 126 words
A method for coating a surface with improved gloss and nonyellowing characteristics consisting of a. applying to a surface, a mixture comprising (i) a first component according to the formula ##STR3## wherein A is an organic radical including at least one aromatic ring; each R 1 is independently an aliphatic radical; each n is independently 0 or 1; and each R 2 is independently an organic or inorganic radical selected from the group consisting of a halogen and an aliphatic radical having from one to six carbon atoms, and (ii) a second component comprising a polyahl; and b. curing the mixture; the ratio of the first component and second component, and the curing step being such that an adherent, solid coating is formed on said surface.
Claim 3
Dependent Claim 54 words
The method of claim 1 wherein A is an aromatic ring having from 6 to 12 members forming the ring; each R 1 is independently an aliphatic radical having from 1 to 6 carbon atoms; and each R 2 is independently, a halogen, or an aliphatic radical having from 1 to 6 carbon atoms.
Claim 4
Dependent Claim 47 words
The method of claim 2 wherein A is an aromatic ring having 6 carbon atoms forming the ring; each R 1 is independently an aliphatic radical having 1 to 3 carbon atoms; and each R 2 is independently an aliphatic radical having 1 to 3 carbon atoms.
Claim 5
Dependent Claim 18 words
The method of claim 3 wherein every n is 0; and every R 2 is a methyl radical.
Claim 6
Dependent Claim 12 words
The method of claim 1 wherein the second component is a polyol.
Claim 7
Dependent Claim 12 words
The method of claim 5 wherein the polyol is a glycol ether.
Claim 8
Dependent Claim 19 words
The method of claim 5 wherein the polyol is an addition polymer of a hydroxy functional addition polymerizable monomer.
Claim 9
Dependent Claim 23 words
The method of claim 7 wherein the polyol is an addition polymer of a hydroxy functional ester of an ethylenically unsaturated carboxylic acid.
Claim 10
Dependent Claim 17 words
The method of claim 1 wherein the mixture additionally comprises a catalytic amount of a urethane catalyst.
Claim 11
Dependent Claim 16 words
A coated surface produce by the method of claim 1, 2, 4, 5, 8 or 9.

References Cited (Backward Citations)

GB1443715A Cited
US4104432A Cited
US4214016A Cited
US4299868A Cited
US4289827A Cited
US4331735A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-08-14 1988-02-13 1988-08-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-08-14 1992-02-13 1992-08-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-08-14 1996-02-13 1996-08-14 $7700.00 Window Closed / Lapsed

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