Method of making flaky β-SiC

Claim 5

In a method of making a ceramic material having improved properties of resistance to thermal shock, thermal fatigue and oxidation, excluding MgO refractories and CaO refractories, the improvement wherein the method comprises a step of introducing into the ceramic material to be molded, flaky β-SiC having a thickness of 10-100μ and a width and length of 100μ to 10 mm, and orienting said flaky β-SiC in a laminar direction in the ceramic material, said flaky β-SiC being prepared by the steps of: (a) forming a sheet of an average thickness of 10-100μ from an organic silicon polymer containing the carbon and silicon atoms as the major skeletal components, said polymer being selected from at least one of the following unit structures (I)-(IV): ##STR4## wherein R 1 is --CH 3 and R 2 , R 3 and R 4 are one or more members selected from the group consisting of hydrogen, alkyl, aryl, (CH 3 ) 2 CH--, (C 6 H 5 ) 2 SiH and (CH 3 ) 3 Si--; k, l, m and n are the respective numbers of repetition of the unit structures defined by the immediately preceding parentheses or brackets and k=1-80, l=15-350, m=1-80, and n=15-350, the average molecular weight of the polymer being in the range of 800-20000; M is a metallic or nonmetallic element which is Si, B, Ti, Fe, Al, Zr or Cr; and R 5 , R 6 , R 7 and R 8 are one or more members selected from the group consisting of hydrogen, alkyl, aryl, (CH 3 ) 2 CH--, (C 6 H 5 ) 2 SiH-- and (CH 3 ) 3 Si-- and any one or more of R 5 , R 6 , R 7 and R 8 may be absent depending on the valence of M and the unit structure, (b) making said sheet infusible by conventional methods to provide an infusible sheet, (c) heating said polymer in an atmosphere of a non-oxidative gas at a temperature of 1200°-1800° C., and (d) cutting said sheet either before or after said heating step to provide flaky material having said width and length of 100μ to 10 mm.

Claim 6

In a method of making a ceramic material having improved properties of resistance to thermal shock, thermal fatigue and oxidation, excluding MgO refractories and CaO refractories, the improvement wherein the method comprises a step of introducing into the ceramic material to be molded, flaky β-SiC having a thickness of 10-100μ and a width and length of 100μ to 10 mm, and orienting said flaky β-SiC in a laminar direction in the ceramic material, said flaky β-SiC being prepared by the steps of: (a) forming a sheet of an average thickness of 10-100μ from an organic silicon polymer containing the carbon and silicon atoms as the major skeletal components, said polymer being selected from at least one of the following unit structures (I)-(IV): ##STR4## wherein R 1 is --CH 3 and R 2 , R 3 and R 4 are one or more members selected from the group consisting of hydrogen, alkyl, aryl, (CH 3 ) 2 CH--, (C 6 H 5 ) 2 SiH and (CH 3 ) 3 Si--; k, l, m and n are the respective numbers of repetition of the unit structures defined by the immediately preceding parentheses or brackets and k=1-80, l=15-350, m=1-80, and n=15-350, the average molecular weight of the polymer being in the range of 800-20000; M is a metallic or nonmetallic element which is Si, B, Ti, Fe, Al, Zr or Cr; and R 5 , R 6 , R 7 and R 8 are one or more members selected from the group consisting of hydrogen, alkyl, aryl, (CH 3 ) 2 CH--, (C 6 H 5 ) 2 SiH-- and (CH 3 ) 3 Si-- and any one or more of R 5 , R 6 , R 7 and R 8 may be absent depending on the valence of M and the unit structure, (b) making said sheet infusible by conventional methods to provide an infusible sheet, (c) heating said polymer in an atmosphere of a non-oxidative gas at a temperature of 1200°-1800° C., and (d) cutting said sheet either before or after said heating step to provide flaky material having said width and length of 100μ to 10 mm.