US4465491A
Expired / Lapsed
US
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Solid dye preparation of water soluble dyes with aliphatic aminocarboxylic acid
Assignee: Novartis Corp
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Filing: 1983-07-20
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Granted: 1984-08-14
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Expires: 2003-07-20
Abstract
Abstract The solid dye preparations contain (a) 30-90 percent by weight of a water-soluble dye, (b) 1-25 percent by weight of an aliphatic aminocarboxylic acid or a salt thereof, and (c) 0-50 percent by weight of further additives. There is preferably at least 2% of anionic dispersing agent in the preparations. The preparations are particularly suitable for dyeing textile material made from cotton, polyacrylonitrile, wool or synthetic polyamide.
Inventors
- 👤 Paolo Balliello
- 👤 Paul Erzinger
- 👤 Ernst Tempel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 10:30
CPC Classifications
C; C09; C09B; C09B67/00; C09B67/0071; C09B67/0092
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
271 words
A dyestuff granulate, readily soluble in cold water and containing (1) 30-90 percent by weight of an anionic dye containing at least one water-solubilizing group, (2) 1-25 percent by weight of a compound of the formula ##STR29## or an alkali salt thereof wherein R is a bivalent aliphatic radical having 1 to 7 C atoms, R 1 is hydrogen, --R--COOH, or an aliphatic radical (C 1 -C 12 ) which is unsubstituted or substituted by hydroxyl, alkylamino or alkoxy, R 2 is hydrogen, an aliphatic radical (C 1 -C 12 ) which is unsubstituted or substituted by hydroxyl; or the group --(CH 2 ) n --NH--CO--C p H 2p+1 wherein n is an integer from 1 to 3 and p is an integer from 1 to 5, or the group ##STR30## in which B is a direct bond, or a bivalent aliphatic radical selected from an ether or thioether radical, --CH 2 --, ##STR31## and --(CH 2 ) q -- wherein q is an integer from 3 to 6, and when R 1 and/or R 6 are hydrogen, q can also be 2, and when R 1 and R 3 are each hydrogen, R 2 can also be ##STR32## wherein n'is a number from 1 to 3, and m is an integer from 1 to 10, R 3 is hydrogen or methyl, R 6 is hydrogen, --R--COOH, or (C 1 -C 12 )-alkyl which is unsubstituted or substituted by hydroxyl, alkylamino or alkoxy, and (3) 0-50 percent by weight of further additives, which granulate is obtained forming an aqueous mixture of the constituents (1) to (3) and spray drying said mixture.
Claim 2
Dependent Claim
271 words
A dyestuff granulate, readily soluble in cold water and containing (1) 30-90 percent by weight of an anionic dye containing at least one water-solubilizing group, (2) 1-25 percent by weight of a compound of the formula ##STR29## or an alkali salt thereof wherein R is a bivalent aliphatic radical having 1 to 7 C atoms, R 1 is hydrogen, --R--COOH, or an aliphatic radical (C 1 -C 12 ) which is unsubstituted or substituted by hydroxyl, alkylamino or alkoxy, R 2 is hydrogen, an aliphatic radical (C 1 -C 12 ) which is unsubstituted or substituted by hydroxyl; or the group --(CH 2 ) n --NH--CO--C p H 2p+1 wherein n is an integer from 1 to 3 and p is an integer from 1 to 5, or the group ##STR30## in which B is a direct bond, or a bivalent aliphatic radical selected from an ether or thioether radical, --CH 2 --, ##STR31## and --(CH 2 ) q -- wherein q is an integer from 3 to 6, and when R 1 and/or R 6 are hydrogen, q can also be 2, and when R 1 and R 3 are each hydrogen, R 2 can also be ##STR32## wherein n'is a number from 1 to 3, and m is an integer from 1 to 10, R 3 is hydrogen or methyl, R 6 is hydrogen, --R--COOH, or (C 1 -C 12 )-alkyl which is unsubstituted or substituted by hydroxyl, alkylamino or alkoxy, and (3) 0-50 percent by weight of further additives, which granulate is obtained forming an aqueous mixture of the constituents (1) to (3) and spray drying said mixture.
Claim 3
Dependent Claim
17 words
A preparation according to claim 1, which contains 2-50 percent by weight of an anionic dispersing agent.
Claim 4
Dependent Claim
15 words
A preparation according to claim 2, which contains 2-20 percent by weight of component (2).
Claim 5
Dependent Claim
15 words
A preparation according to claim 3, which contains 3-10 percent by weight of component (2).
Claim 6
Dependent Claim
55 words
A preparation according to claim 1, in which R is a bivalent aliphatic radical having 1 to 7 C atoms selected from --CH 2 --CH═CH--, ##STR33## ##STR34## and --(CH 2 ) n-- wherein n is a number from 1 to 3, and R 4 and R 5 are hydrogen of (C 1 -C 5 )-alkyl.
Claim 7
Dependent Claim
51 words
A preparation according to claim 1, wherein component (2) is an aliphatic mono-α-amino acid of the formula ##STR35## wherein R 1 is hydrogen or methyl, and R 7 is hydrogen, an aliphatic radical (C 1 -C 5 ) having a straight or branched chain which is unsubstituted or substituted by --OH.
Claim 8
Dependent Claim
28 words
A preparation according to claim 6, wherein R 1 is hydrogen or methyl, and R 7 is --(CH 2 ) 2 --OH or C 1 -C 5 -alkyl.
Claim 9
Dependent Claim
127 words
A preparation according to claim 1, wherein component (2) is a bis-α-iminocarboxylic acid of the formula ##STR36## wherein R' is the group ##STR37## n' is a number from 1 to 3, R 1 ' and R 1 " are each independently hydrogen, --R'--COOH, or an aliphatic radical (C 1 -C 12 ) which can be substituted by hydroxyl, alkylamino and alkoxy, R 4 ' and R 5 ' are each independently hydrogen or (C 1 -C 5 ) alkyl, B' is the direct bond, or a bivalent aliphatic radical selected from --CH 2 --, ##STR38## and --(CH 2 ) q -- wherein q is an integer from 3 to 6, and when R 1 ' and/or R 1 " are each hydrogen, q can also be 2.
Claim 10
Dependent Claim
18 words
A preparation according to claim 8, wherein B' is --CH 2 -- or --(CH 2 ) q .
Claim 11
Dependent Claim
43 words
A preparation according to claim 1, wherein the aliphatic aminocarboxylic acid is a polyethyleneimine-N-polyacetic acid of the formula ##STR39## in which R 12 is ##STR40## wherein n' is a number from 1 to 3, and m is an integer from 1 to 10.
Claim 12
Dependent Claim
59 words
A preparation according to claim 1, wherein the component (2) is a linear betain of the formula ##STR41## wherein R" is a bivalent aliphatic radical having 1 to 3 C atoms, R 13 and R 15 are each methyl, and R 14 is an aliphatic radical having 1 to 12 carbon atoms which is unsubstituted or substituted by hydroxyl.
Claim 13
Dependent Claim
66 words
A preparation according to claim 11, wherein R" is --CH 2 --CH═CH--, ##STR42## or --(CH 2 ) n in which n is an integer from 1 to 3, R 13 and R 15 are methyl and R 14 is --(CH 2 ) n --NH--CO--C p H 2p+1 in which n is an integer from 1 to 3, and p is an integer from 1 to 5.
Claim 14
Dependent Claim
22 words
A preparation according to claim 1, wherein the dye contained is an azo or anthraquinone dye having at least one sulfo group.
Claim 15
Dependent Claim
42 words
A preparation according to claim 13, wherein the dye contained is an azo or anthraquinone dye having at least one sulfo group, which additionally contains at least one methoxy, amino, C 1 -C 6 -alkylamino or di-(C 1 -C 6 )-alkylamino group.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-08-14 | 1988-02-13 | 1988-08-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-08-14 | 1992-02-13 | 1992-08-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-08-14 | 1996-02-13 | 1996-08-14 | $7700.00 | Window Closed / Lapsed |