Silver halide photographic light-sensitive material

Claim 2

A silver halide photograhic light-sensitive material material comprising a support having thereon at least one light-sensitive silver halide emulsion layer and at least one light-insensitive layer, the photographic light-sensitive material containing (A) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR19## wherein R represents a hydrogen atom, a lower alkyl group having from 1 to 4 carbon atoms or a chlorine atom; X represents --CONH--, --COO-- or a phenylene group; A represents a linking group selected from an alkylene group having from 1 to 20 carbon atoms or an arylene group having from 6 to 20 carbon atoms; Y represents --COO--, --OCO--, --CONH--, --NHCO--, --SO 2 NH--, --NHSO 2 --, --SO 2 -- or --O--; m represents 0 or an integer of 1; n represents 0 or an integer of 1; and Q represents an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR20## wherein R 1 and R 2 , which may be the same or different, each represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms, provided that the both of R 1 and R 2 do not simultaneously represent hydrogen atoms, and further R 1 and R 2 may combine to form an atomic group necessary to form a cyclic amino group; R 3 represents a cyano group, --COOR 5 , --CONHR 5 , --COR 5 or --SO 2 R 5 ; and R 4 represents a cyano group, --COOR 6 , --CONHR 6 , --COR 6 or --SO 2 R 6 ; wherein R 5 and R 6 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms, and further R 5 and R 6 may combine to form an atomic group necessary to form a 1,3-dioxocyclohexane nucleus, a 1,3-diaza-2,4,6- trioxocyclohexane nucleus (a barbituric acid nucleus), a 1,2- diaza-3,5-dioxocyclopentane nucleus or a 2,4-diaza-1-alkoxy-3,5-dioxocyclohexene nucleus; and at least one of R 1 , R 2 , R 3 and R 4 bonds to the vinyl group through the linking group, ##STR21## wherein R 11 , R 12 , R 13 , R 14 and R 15 each represents a hydrogen atom, a halogen atom, an alkyl group having from 1 to 20 carbon atoms, an aryl group having from 6 to 20 carbon atoms, an alkoxy group having from 1 to 20 carbon atoms, an aryloxy group having from 6 to 20 carbon atoms, an alkylthio group having from 1 to 20 carbon atoms, an arylthio group having from 6 to 20 carbon atoms, an amino group, an alkylamino group having from 1 to 20 carbon atoms, an arylamino group having from 6 to 20 carbon atoms, a hydroxyl group, a cyano group, a nitro group, an acylamino group, a carbamoyl group, a sulfonyl group, a sulfamoyl group, a sulfonamido group, an acyloxy group or an oxycarbonyl group, and R 11 and R 12 , R 12 and R 13 , R 13 and R 14 or R 14 and R.sub. 15 may form a 5- or 6-membered ring by ring closure; R 16 represents a hydrogen atom or an alkyl group having from 1 to 20 carbon atoms; R 17 represents a cyano group, --COOR 19 , --CONHR 19 , --COR 19 or --SO 2 R 19 ; and R 18 represents a cyano group, --COOR 20 , --CONHR 20 , --COR 20 or --SO 2 R 20 ; wherein R 19 and R 20 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl having from 6 to 20 carbon atoms; wherein one of R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 and R 18 bonds to the vinyl group through the linking group, and (B) a fluorine containing cationic surface active agent.

Claim 3

A silver halide photographic light-sensitive material as claimed in claim 1, wherein R 1 and R 2 each represents an alkyl group having from 1 to 20 carbon atoms; R 3 represents a cyano group or --SO 2 R 5 ; R 4 represents a cyano group or --COOR 6 ; and R 5 and R 6 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms.

Claim 4

A silver halide photographic light-sensitive material as claimed in claim 1, wherein R 1 and R 2 each represents an alkyl group having from 1 to 6 carbon atoms; R 3 represents --SO 2 R 5 ; R 4 represents --COOR 6 ; R 5 represents a phenyl group which may be substituted; and R 6 represents an alkyl group having from 1 to 20 carbon atoms.

Claim 5

A silver halide photographic light-sensitive material as claimed in claim 1, wherein R 11 , R 12 , R 13 , R 14 and R 15 each represents a hydrogen atom, a halogen atom, an alkyl group having from 1 to 20 carbon atoms, an aryl group having from 6 to 20 carbon atoms, an alkoxy group having from 1 to 20 carbon atoms, an aryloxy group having from 6 to 20 carbon atoms, an alkylamino group having from 1 to 20 carbon atoms, an arylamino group having from 6 to 20 carbon atoms, a hydroxy group, an acylamino group, a carbamoyl group, an acyloxy group or an oxycarbonyl group, and R 11 and R 12 , R 12 and R 13 , R 13 and R 14 or R 14 and R 15 may form a 5- or 6-membered ring by ring closure; R 16 represents a hydrogen atom or an alkyl group having from 1 to 20 carbon atoms; R 17 represents a cyano group, --COOR 19 , --CONHR 19 , --COR 19 or --SO 2 R 19 ; and R 18 represents a cyano group, --COOR 20 , --CONHR 20 , --COR 20 or --SO 2 R 20 ; wherein R 19 and R 20 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms; and at least one of R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 and R 18 bonds to the vinyl group through the linking group.

Claim 6

A silver halide photographic light-sensitive material as claimed in claim 1, wherein R represents a hydrogen atom, a lower alkyl group having from 1 to 4 carbon atoms or a chlorine atom; X represents --COO--; m and n represent 0; and Q represents an ultraviolet ray absorbing group represented by the general formula (III); wherein R 11 , R 12 , R 14 and R 15 each represents a hydrogen atom; R 13 represents a hydrogen atom or an alkyl group having from 1 to 5 carbon atoms; R 16 represents a hydrogen atom; R 17 represents a cyano group; and R 18 represents --COOR 20 ; wherein R 20 represents an alkylene group having from 1 to 20 carbon atoms which bonds to the vinyl group.

Claim 7

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex comprises a homopolymer having a repeating unit derived from the monomer represented by the general formula (I).

Claim 8

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex comprises a copolymer of the monomer represented by the general formula (I) with a copolymerizable monomer.

Claim 9

A silver halide photographic light-sensitive material as claimed in claim 7, wherein the copolymerizable monomer is selected from the group consisting of an acrylic acid ester, an acrylic acid amide, a vinyl ester, an acrylonitrile, an aromatic vinyl compound, itaconic acid, citraconic acid, crotonic acid, vinylidene chloride, a vinyl alkyl ether, a maleic acid ester, N-vinylpyrrolidone, N-vinylpyridine, and 2-or 4-vinylpyridine.

Claim 10

A silver halide photographic light-sensitive material as claimed in claim 7, wherein the copolymerizable monomer is selected from the group consisting of an acrylic acid ester, a methacrylic acid ester and an aromatic vinyl compound.

Claim 11

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex is a latex prepared by emulsion polymerization of monomers comprising the monomer represented by the general formula (I).

Claim 12

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex is a latex prepared by dissolving an oleophilic polymer ultraviolet ray absorbing agent obtained by polymerization of monomers comprising the monomer represented by the general formula (I) in an organic solvent and then dispersing the solution in a latex form in an aqueous gelatin solution.

Claim 13

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the amount of the ultraviolet ray absorbing agent portion in the polymer latex is from 5 to 100% by weight.

Claim 14

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the amount of the ultraviolet ray absorbing agent in the polymer latex is from 50 to 100% by weight.

Claim 15

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex is present in a surface protective layer, an intermediate layer or a silver halide emulsion layer.

Claim 16

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex is present in a surface protective layer or a hydrophilic colloid layer adjacent to the surface protective layer.

Claim 17

A silver halide photographic light-sensitive material as claimed in claim 15, wherein the surface protective layer is composed of two separate layers and the lower layer thereof contains the ultraviolet ray absorbing polymer latex.

Claim 18

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex is present in an amount within the range of from 10 to 2,000 mg/m 2 of the material.

Claim 19

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex is present in an amount within the range of from 50 to 1,000 mg/m 2 of the material.

Claim 20

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the fluorine containing cationic surface active agent is a compound represented by the following general formula (IV): R.sub.f --A--X.sup.⊕ Y.sup.⊖ (IV) wherein R f represents a hydrocarbon group having from 1 to 20 carbon atoms in which at least one hydrogen atom is substituted with a fluorine atom; A represents a chemical bond or a divalent group; X.sup.⊕ represents a cationic group; and Y.sup.⊖ represents a counter anion.

Claim 21

A silver halide photographic light-sensitive material as claimed in claim 19, wherein R f represents --C n F 2n+1 HC n F 2n --, --C n F 2n-1 or --C 3m F 6m-1 (wherein n is from 1 to 20 and wherein m is from 1 to 4).

Claim 22

A silver halide photographic light-sensitive material as claimed in claim 19, wherein A represents ##STR22## ##STR23## ##STR24## --O--A'--O--(CH 2 ) p --, --O--A'--(CH 2 ) p --, --O(CH 2 CH 2 O) q --(CH 2 ) p -- --O--(CH 2 ) p --, ##STR25## (wherein R' represents a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms; A' represents an alkylene group or an arylene group; p is from 0 to 6 and q is from 1 to 20).

Claim 23

A silver halide photographic light-sensitive material as claimed in claim 19, wherein X represents --N(R') 3 , --N(CH 2 CH 2 OCH 3 ) 3 , ##STR26## wherein R' represents a hydrogen atom or an alkyl group having from 1 to 6 carbon atoms and p is from 0 to 6.

Claim 24

A silver halide photographic light-sensitive material as claimed in claim 19, wherein Y represents I, Cl, Br, CH 3 SO 4 or ##STR27##

Claim 25

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the fluorine containing cationic surface active agent is present in a surface protective layer, a back layer, an intermediate layer, a subbing layer, or an overcoating layer.

Claim 26

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the fluorine containing cationic surface active agent is present in a surface protective layer, a back layer or an overcoating layer.

Claim 27

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the fluorine containing cationic surface active agent is present in an amount within the range of from 0.0001 to 2.0 g/m 2 of the material.

Claim 28

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the fluorine containing cationic surface active agent is present in an amount within the range from 0.0005 to 0.05 g/m 2 of the material.

Claim 29

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the photographic light-sensitive material further contains a color forming coupler.

Claim 30

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the photographic light-sensitive material comprises a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a blue-sensitive silver halide emulsion layer.

Claim 31

A silver halide photographic light-sensitive material as claimed in claim 1, wherein the ultraviolet ray absorbing polymer latex and the fluorine containing cationic surface active agent are present in a surface protective layer.

Claim 32

A silver halide photographic light-sensitive material as claimed in claim 30, wherein the surface protective layer is composed of two separate layers and the lower layer thereof contains the ultraviolet ray absorbing polymer latex and the upper layer thereof contains the fluorine containing cationic surface active agent.

Claim 33

A multilayer color photographic light-sensitive material comprising a support having thereon a red-sensitive silver halide emulsion layer containing a cyan forming coupler, a green-sensitive silver halide emulsion layer containing a magenta forming coupler, a blue-sensitive silver halide emulsion layer containing a yellow forming coupler and at least one light-insensitive layer, the photographic light-sensitive material containing (A) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR28## wherein R represents a hydrogen atom, a lower alkyl group having from 1 to 4 carbon atoms or a chlorine atom; X represents --CONH--, --COO-- or a phenylene group; A represents a linking group selected from an alkylene group having from 1 to 20 carbon atoms or an arylene group having from 6 to 20 carbon atoms; Y represents --COO--, --OCO--, --CONH--, --NHCO--, --SO 2 NH--, --NHSO 2 --, --SO 2 -- or --O--; m represents 0 or an integer of 1; n represents 0 or an integer of 1; and Q represents an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR29## wherein R 1 and R 2 , which may be the same or different, each represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms, provided that the both of R 1 and R 2 do not simultaneously represent hydrogen atoms, and further R 1 and R 2 may combine to form an atomic group necessary to form a cyclic amino group; R 3 represents a cyano group, --COOR 5 , --CONHR 5 , --COR 5 or --SO 2 R 5 ; and R 4 represents a cyano group, --COOR 6 , --CONHR 6 , --COR 6 or --SO 2 R 6 ; wherein R 5 and R 6 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms, and further R 5 and R 6 may combine to form an atomic group necessary to form a 1,3-dioxocyclohexane nucleus, a 1,3-diaza-2,4,6-trioxocyclohexane nucleus (a barbituric acid nucleus), a 1,2-diaza-3,5-dioxocyclopentane nucleus or a 2,4-diaza-1-alkoxy-3,5-dioxocyclohexene nucleus; and at least one of R 1 , R 2 , R 3 and R 4 bonds to the vinyl group through the linking group, ##STR30## wherein R 11 , R 12 , R 13 , R 14 and R 15 each represents a hydrogen atom, a halogen atom, an alkyl group having from 1 to 20 carbon atoms, an aryl group having from 6 to 20 carbon atoms, an alkoxy group having from 1 to 20 carbon atoms, an aryloxy group having from 6 to 20 carbon atoms, an alkylthio group having from 1 to 20 carbon atoms, an arylthio group having from 6 to 20 carbon atoms, an amino group, an alkylamino group having from 1 to 20 carbon atoms, an arylamino group having from 6 to 20 carbon atoms, a hydroxyl group, a cyano group, a nitro group, an acylamino group, a carbamoyl group, a sulfonyl group, a sulfamoyl group, a sulfonamide group, an acyloxy group or an oxycarbonyl group, and R 11 and R 12 , R 12 and R 13 , R 13 and R 14 or R 14 and R 15 may form a 5- or 6-membered ring by ring closure; R 16 represents a hydrogen atom or an alkyl group having from 1 to 20 carbon atoms; R 17 represents a cyano group, --COOR 19 , --CONHR 19 , --COR 19 or --SO 2 R 19 ; and R 18 represents a cyano group, --COOR 20 , --CONHR 20 , --COR 20 or --SO 2 R 20 ; wherein R 19 and R 20 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms; wherein one of R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 and R 18 bonds to the vinyl group through the linking group, and (B) a fluorine containing cationic surface active agent.

Claim 34

A multilayer color photographic light-sensitive material comprising a support having thereon a red-sensitive silver halide emulsion layer containing a cyan forming coupler, a green-sensitive silver halide emulsion layer containing a magenta forming coupler, a blue-sensitive silver halide emulsion layer containing a yellow forming coupler and at least one light-insensitive layer, the photographic light-sensitive material containing (A) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR28## wherein R represents a hydrogen atom, a lower alkyl group having from 1 to 4 carbon atoms or a chlorine atom; X represents --CONH--, --COO-- or a phenylene group; A represents a linking group selected from an alkylene group having from 1 to 20 carbon atoms or an arylene group having from 6 to 20 carbon atoms; Y represents --COO--, --OCO--, --CONH--, --NHCO--, --SO 2 NH--, --NHSO 2 --, --SO 2 -- or --O--; m represents 0 or an integer of 1; n represents 0 or an integer of 1; and Q represents an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR29## wherein R 1 and R 2 , which may be the same or different, each represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms, provided that the both of R 1 and R 2 do not simultaneously represent hydrogen atoms, and further R 1 and R 2 may combine to form an atomic group necessary to form a cyclic amino group; R 3 represents a cyano group, --COOR 5 , --CONHR 5 , --COR 5 or --SO 2 R 5 ; and R 4 represents a cyano group, --COOR 6 , --CONHR 6 , --COR 6 or --SO 2 R 6 ; wherein R 5 and R 6 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms, and further R 5 and R 6 may combine to form an atomic group necessary to form a 1,3-dioxocyclohexane nucleus, a 1,3-diaza-2,4,6-trioxocyclohexane nucleus (a barbituric acid nucleus), a 1,2-diaza-3,5-dioxocyclopentane nucleus or a 2,4-diaza-1-alkoxy-3,5-dioxocyclohexene nucleus; and at least one of R 1 , R 2 , R 3 and R 4 bonds to the vinyl group through the linking group, ##STR30## wherein R 11 , R 12 , R 13 , R 14 and R 15 each represents a hydrogen atom, a halogen atom, an alkyl group having from 1 to 20 carbon atoms, an aryl group having from 6 to 20 carbon atoms, an alkoxy group having from 1 to 20 carbon atoms, an aryloxy group having from 6 to 20 carbon atoms, an alkylthio group having from 1 to 20 carbon atoms, an arylthio group having from 6 to 20 carbon atoms, an amino group, an alkylamino group having from 1 to 20 carbon atoms, an arylamino group having from 6 to 20 carbon atoms, a hydroxyl group, a cyano group, a nitro group, an acylamino group, a carbamoyl group, a sulfonyl group, a sulfamoyl group, a sulfonamide group, an acyloxy group or an oxycarbonyl group, and R 11 and R 12 , R 12 and R 13 , R 13 and R 14 or R 14 and R 15 may form a 5- or 6-membered ring by ring closure; R 16 represents a hydrogen atom or an alkyl group having from 1 to 20 carbon atoms; R 17 represents a cyano group, --COOR 19 , --CONHR 19 , --COR 19 or --SO 2 R 19 ; and R 18 represents a cyano group, --COOR 20 , --CONHR 20 , --COR 20 or --SO 2 R 20 ; wherein R 19 and R 20 each represents an alkyl group having from 1 to 20 carbon atoms or an aryl group having from 6 to 20 carbon atoms; wherein one of R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 and R 18 bonds to the vinyl group through the linking group, and (B) a fluorine containing cationic surface active agent.