US4463134A
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Modified epoxy resin composition
Assignee: Tohto Kasei Co Ltd
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Filing: 1981-12-22
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Granted: 1984-07-31
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Expires: 2001-12-22
Abstract
Abstract Modified epoxy resin compositions having excellent flexibility and excellent compatibility with conventional epoxy resins as well as exhibiting the original properties of the epoxy resin before being modified such as mechanical strength, adhesion, heat resistance are disclosed and chemical resistance, which are obtained by treating an epoxy resin with at least one modified adduct [D] of a conjugated diene polymer or copolymer which has an imido bond and/or amido bond and a semi-ester structure and has an acid value owing to a free carboxyl group of 5 to 100. The modified adduct is obtained by reacting an adduct [A] of a polymer of a conjugated diene having a number average molecular weight of 300 to 20,000 or a copolymer of the conjugated diene and a vinyl monomer with an alpha , beta -unsaturated dicarboxylic acid or its anhydride, with a compound [B] containing one primary amino group in the molecule and a compound [C] containing a hydroxy group in the molecule.
Inventors
- 👤 Minoru Hino
- 👤 Takao Oshima
- 👤 Akihiro Tachibana
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 14:54
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/50; C08C; C08C19/00; C08C19/30; C08C19/34; C08C19/36; C08G59/02; C08G59/10; C08L; C08L63/00; Y; Y10; Y10S; Y10S525/00; Y10S525/911
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
199 words
A modified epoxy resin composition, which comprises an epoxy resin and a modified adduct [D] of a conjugated diene polymer or copolymer which has an imido bond and/or amido bond and a semi-ester structure and has an acid value owing to a free carboxyl group of 5 to 100, said modified adduct being obtained by reacting in the absence of an epoxy resin an adduct [A] of a polymer of a conjugated diene having a number average molecular weight of 300 to 20,000 or a copolymer of the conjugated diene and a vinyl monomer with an α,β-unsaturated dicarboxylic acid or its anhydride, with a compound [B] of the formula: R.sub.1 --NH.sub.2 [I] wherein R 1 is an aliphatic hydrocarbon group having 1 to 18 carbon atoms or an alicyclic hydrocarbon group having 3 to 18 carbon atoms, said aliphatic and alicyclic hydrocarbon groups containing optionally an ether bond, and a compound [C] of the formula: R.sub.2 --CH.sub.2).sub.n OH [II] wherein R 2 is a saturated or unsaturated hydrocarbon group having 1 to 18 carbon atoms which may optionally contain cyano, a halogen, an ether bond to an ester bond, and n is an integer of from 0 to 3.
Claim 2
Dependent Claim
199 words
A modified epoxy resin composition, which comprises an epoxy resin and a modified adduct [D] of a conjugated diene polymer or copolymer which has an imido bond and/or amido bond and a semi-ester structure and has an acid value owing to a free carboxyl group of 5 to 100, said modified adduct being obtained by reacting in the absence of an epoxy resin an adduct [A] of a polymer of a conjugated diene having a number average molecular weight of 300 to 20,000 or a copolymer of the conjugated diene and a vinyl monomer with an α,β-unsaturated dicarboxylic acid or its anhydride, with a compound [B] of the formula: R.sub.1 --NH.sub.2 [I] wherein R 1 is an aliphatic hydrocarbon group having 1 to 18 carbon atoms or an alicyclic hydrocarbon group having 3 to 18 carbon atoms, said aliphatic and alicyclic hydrocarbon groups containing optionally an ether bond, and a compound [C] of the formula: R.sub.2 --CH.sub.2).sub.n OH [II] wherein R 2 is a saturated or unsaturated hydrocarbon group having 1 to 18 carbon atoms which may optionally contain cyano, a halogen, an ether bond to an ester bond, and n is an integer of from 0 to 3.
Claim 3
Dependent Claim
61 words
A modified epoxy resin composition according to claim 1, wherein said conjugated diene monomer is selected from at least one member of the group consisting of butadiene, isoprene, chloroprene, and 1,3-pentadiene, and said vinyl monomer is selected from at least one member of the group consisting of an acrylic acid ester, a methacrylic acid ester, acrylonitrile, styrene, acetylene, ethylene, and propylene.
Claim 4
Dependent Claim
37 words
A modified epoxy resin composition according to claim 1, wherein said α,β-unsaturated dicarboxylic acid is selected from at least one member of the group consisting of maleic, anhydride, maleic acid, fumaric acid, itaconic acid, and citraconic acid.
Claim 5
Dependent Claim
19 words
A modified epoxy resin composition according to claim 1, wherein said epoxy resin contains at least one epxoy group.
Claim 6
Dependent Claim
35 words
A modified epoxy resin composition according to claim 1, wherein said modified adduct [D] is used in an amount of 5 to 300 parts by weight to 100 parts by weight of said epoxy resin.
Claim 7
Dependent Claim
206 words
A process for producing a modified epoxy resin composition which comprises mixing an epoxy resin with at least one modified adduct [D] of a conjugated diene polymer or copolymer which has an imido bond and/or amido bond and a semi-ester structure and has an acid value owing to a free carboxyl group of 5 to 100, said modified adduct being obtained by reacting in the absence of an epoxy resin an adduct [A] of a polymer of a conjugated diene having a number average molecular weight of 300 to 20,000 or a copolymer of the conjugated diene and a vinyl monomer with an α,β-unsaturated dicarboxylic acid or its anhydride, with a compound [B] of the formula: R.sub.1 --NH.sub.2 [I] wherein R 1 is an aliphatic hydrocarbon group having 1 to 18 carbon atoms or an alicyclic hydrocarbon group having 3 to 18 carbon atoms, said aliphatic and alicyclic hydrocarbon groups containing optionally an ether bond, and a compound [C] of the formula: R.sub.2 --CH.sub.2).sub.n OH [II] wherein R 2 is a saturated or unsaturated hydrocarbon group having 1 to 18 carbon atoms which may optionally contain cyano, a halogen, an ether bond or an ester bond, and n is an integer of from 0 to 3.
Claim 8
Dependent Claim
206 words
A process for producing a modified epoxy resin composition which comprises mixing an epoxy resin with at least one modified adduct [D] of a conjugated diene polymer or copolymer which has an imido bond and/or amido bond and a semi-ester structure and has an acid value owing to a free carboxyl group of 5 to 100, said modified adduct being obtained by reacting in the absence of an epoxy resin an adduct [A] of a polymer of a conjugated diene having a number average molecular weight of 300 to 20,000 or a copolymer of the conjugated diene and a vinyl monomer with an α,β-unsaturated dicarboxylic acid or its anhydride, with a compound [B] of the formula: R.sub.1 --NH.sub.2 [I] wherein R 1 is an aliphatic hydrocarbon group having 1 to 18 carbon atoms or an alicyclic hydrocarbon group having 3 to 18 carbon atoms, said aliphatic and alicyclic hydrocarbon groups containing optionally an ether bond, and a compound [C] of the formula: R.sub.2 --CH.sub.2).sub.n OH [II] wherein R 2 is a saturated or unsaturated hydrocarbon group having 1 to 18 carbon atoms which may optionally contain cyano, a halogen, an ether bond or an ester bond, and n is an integer of from 0 to 3.
Claim 9
Dependent Claim
57 words
The process of claim 6 wherein said conjugated diene monomer is selected from at least one member of the group consisting of butadiene, isoprene, chloroprene, and 1,3-pentadiene, and said vinyl monomer is selected from at least one member of the group consisting of an acrylic acid ester, a methacrylic acid ester, acrylonitrile, styrene, acetylene, ethylene, and propylene.
Claim 10
Dependent Claim
33 words
The process of claim 6 wherein said α,β-unsaturated dicarboxylic acid is selected from at least one member of the group consisting of maleic anhydride, maleic acid, fumaric acid, itaconic acid, and citraconic acid.
Claim 11
Dependent Claim
15 words
The process of claim 6 wherein said epoxy resin contains at least one epxoy group.
Claim 12
Dependent Claim
31 words
The process of claim 6 wherein said modified adduct [D] is used in an amount of 5 to 300 parts by weight to 100 parts by weight of said epoxy resin.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-07-31 | 1988-01-30 | 1988-07-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-07-31 | 1992-01-30 | 1992-07-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-07-31 | 1996-01-30 | 1996-07-31 | $7700.00 | Window Closed / Lapsed |