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US4461816A Expired / Lapsed US ⏱️ 0.0 years remaining

Solid lithium nitride electrolyte battery comprising lithium alloy anode

Assignee: European Space Agency
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Filing: 1982-09-29
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Granted: 1984-07-24
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Expires: 2002-09-29
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Abstract

Abstract The present invention discloses an electrochemical generator which comprises an anode formed from an alloy comprising 65 to 85% of lithium and 15 to 35% of lead or a mixture of lead and tin and a cathode formed of a material capable of undergoing intercalation reactions while reacting with lithium, and having a solid electrolyte which contains lithium nitride impregnated in a resinous matrix.

Inventors

  • 👤 Henri R. Leribaux

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 17:09
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/38; H01M4/40; H01M6/00; H01M6/14; H01M6/18; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 60 words
An electrochemical generator which comprises an anode formed from an alloy comprising 65 to 85% of lithium and 15 to 35% of lead or a mixture of lead and tin and a cathode formed of a material capable of undergoing intercalation reaction while reacting with lithium, and having a solid electrolyte which contains lithium nitride impregnated in a resinous matrix.
Claim 2
Dependent Claim 60 words
An electrochemical generator which comprises an anode formed from an alloy comprising 65 to 85% of lithium and 15 to 35% of lead or a mixture of lead and tin and a cathode formed of a material capable of undergoing intercalation reaction while reacting with lithium, and having a solid electrolyte which contains lithium nitride impregnated in a resinous matrix.
Claim 3
Dependent Claim 37 words
The electrochemical generator as claimed in claim 1, wherein the anode is formed form an alloy containing 79% of lithium and 21% of lead or a lead-tin alloy of a density close to 3.3 g/cm 3 .
Claim 4
Dependent Claim 40 words
The electrochemical generator as claimed in claim 1, wherein the cathode is formed from a material chosen from the group which contains TiS 2 , MoS 3 , MoO 3 , NiPS 3 , NiS 2 , FeS 2 .
Claim 5
Dependent Claim 29 words
The electrochemical generator as claimed in claim 3, wherein the cathode is formed from a TiS 2 -MoS 3 mixture containing about 80 mol % of TiS 2 .
Claim 6
Dependent Claim 29 words
The electrochemical generator as claimed in claim 3, wherein the cathode is formed from an NiS 2 -FeS 2 mixture in the molar proportion of 40% to 60% respectively.
Claim 7
Dependent Claim 38 words
The electrochemical generator as claimed in claim 1, wherein the materials forming the cathode may be intimately mixed with 1 to 6% of their weight of molybdenum powder or a mixture of molybdenum powder and a polyfluoronated resin.
Claim 8
Dependent Claim 21 words
The electrochemical generator as claimed in claim 1, wherein the plastic material for impregnation of the solid electrolyte is a polyolefin.
Claim 9
Dependent Claim 19 words
The electrochemical generator as claimed in claim 1, wherein the plastic material for impregnation of the electrolyte is polytetrafluoroethylene.
Claim 10
Dependent Claim 24 words
The electrochemical generator as claimed in claim 1, wherein the thickness of the layer of electrolyte separating the electrodes is 1 to 2 mm.
Claim 11
Dependent Claim 36 words
The electrochemical generator as claimed in claim 1, wherein the cathode and the anode are made from sintered materials filling the inside of a metal frame forming a collector and a support for the connection terminals.
Claim 12
Dependent Claim 24 words
The electrochemical generator as claimed in claim 1, formed from four-element units, comprising four pairs of positive electrodes and four pair of negative electrodes.
Claim 13
Dependent Claim 32 words
The electrochemical generator as claimed in claim 1, wherein the anode is formed from an alloy containing 70-80% of lithium and 20-30% of a lead or a mixture of lead and tin.

References Cited (Backward Citations)

US3506492A Cited
FR2232841A1 Cited
US3898096A Cited
US3933520A Cited
US3992222A Cited
US4011372A Cited
FR2389247A1 Cited
FR2408548A1 Cited
US4234554A Cited
FR2414253A1 Cited
GB2048839A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-24 1988-01-23 1988-07-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-24 1992-01-23 1992-07-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-24 1996-01-23 1996-07-24 $7700.00 Window Closed / Lapsed

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