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US4459416A Expired / Lapsed US ⏱️ 0.0 years remaining

Water soluble thioxantone photoinitiators

Assignee: Sericol Ltd
•
Filing: 1982-08-25
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Granted: 1984-07-10
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Expires: 2002-08-25
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Abstract

Abstract The invention provides novel thioxanthone photoinitiators having the formula: ##STR1## wherein R 1 alkyl, alkoxy, alkylthio, halogeno, nitro, amino, alkyl-amino, di-alkyl-amino, hydroxy alkyl-amino, alkanoylamino, benzoylamino, N-alkanoyl-N-benzoyl-amino, sulphonamido, or acetyl, R 2 is alkylene, A is --COOH, --SO 3 H, --OSO 3 H, or --O--CO--X--COOH (where X is such that HO--CO--X--COOH is a di- or tri-carboxylic acid of up to 8 carbon atoms), n is 0, 1, or 2 and m is 1 or 2, provided that when A is --COOH, m is 2, the aforesaid alkyl, alkoxy, alkanoyl, and alkylene residues containing up to 4 carbon atoms each, as the free acid or as a salt thereof. The photoinitiators may advantageously be used in water-based photopolymerizable compositions, e.g. for use in screen stencil production.

Inventors

  • 👤 John R. Curtis
  • 👤 Peter E. Heaton

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 15:09
CPC Classifications
C; C07; C07D; C07D335/00; C07D335/04; C07D335/10; C07D335/12; C07D335/14; C07D335/16; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 103 words
A thioxanthone of the formula: ##STR4## wherein R 1 is alkyl, alkoxy, alkylthio, halogeno, nitro, amino, alkyl-amino, di-alkyl-amino, hydroxy alkyl-amino, alkanoylamino, benzoylamino, N-alkanoyl-N-benzoyl-amino, or acetyl, R 2 is alkylene, A is --COOH, --SO 3 H, --OSO 3 H, or --O--CO--X--COOH (where X is such that HO--CO--X--COOH is a di- or tri-carboxylic acid of up to 8 carbon atoms), n is 0, 1 or 2 and m is 1 or 2, provided that when A is --COOH, m is 2, the aforesaid alkyl, alkoxy, alkanoyl, and alkylene residues containing up to 4 carbon atoms each, as the free acid or as a salt thereof.
Claim 2
Dependent Claim 103 words
A thioxanthone of the formula: ##STR4## wherein R 1 is alkyl, alkoxy, alkylthio, halogeno, nitro, amino, alkyl-amino, di-alkyl-amino, hydroxy alkyl-amino, alkanoylamino, benzoylamino, N-alkanoyl-N-benzoyl-amino, or acetyl, R 2 is alkylene, A is --COOH, --SO 3 H, --OSO 3 H, or --O--CO--X--COOH (where X is such that HO--CO--X--COOH is a di- or tri-carboxylic acid of up to 8 carbon atoms), n is 0, 1 or 2 and m is 1 or 2, provided that when A is --COOH, m is 2, the aforesaid alkyl, alkoxy, alkanoyl, and alkylene residues containing up to 4 carbon atoms each, as the free acid or as a salt thereof.
Claim 3
Dependent Claim 45 words
A thioxanthone according to claim 1 wherein R 1 is methyl, R 2 is ethylene, trimethylene, or tetramethylene, A is --SO 3 H, n is 0, 1 or 2 and m is 1 or 2 as the free acid or as a water-soluble salt thereof.
Claim 4
Dependent Claim 14 words
A thioxanthone according to claim 1 which is 2-(3-sulphopropoxy)thioxanthone or a water-soluble salt thereof.
Claim 5
Dependent Claim 14 words
A thioxanthone according to claim 1 which is 2-[2-(2-sulphoethoxy)ethoxy]thioxanthone or a water-soluble salt thereof.
Claim 6
Dependent Claim 14 words
A thioxanthone according to claim 1 which is 2-(4-sulphobutoxy)thioxanthone or a water-soluble salt thereof.
Claim 7
Dependent Claim 14 words
A thioxanthone according to claim 1 which is 2-(3-sulphopropoxy)-3,4-dimethyl-thioxanthone or a water-soluble salt thereof.

References Cited (Backward Citations)

US3642997A Cited
GB2050378A Cited
EP0033720A1 Cited
US4348530A Cited
GB2075506A Cited
US4385182A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-10 1988-01-09 1988-07-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-10 1992-01-09 1992-07-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-10 1996-01-09 1996-07-10 $7700.00 Window Closed / Lapsed

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