Composite connecting rod and process

Claim 2

A composite engine part, comprising: a laminated amide-imide resinous polymeric connecting rod comprising a plurality of plies, each ply having an amide-imide resinous polymeric matrix with a fabric layer comprising a fibrous reinforcing material selected from the group consisting essentially of graphite and glass, said laminated amide-imide connecting rod having a split crankshaft-receiving end, a wrist pin-receiving end and an elongated intermediate connecting member extending between and connecting said crankshaft-receiving end and said wrist pin-receiving end, said split crankshaft-receiving end having a detachable portion and an attached portion integrally connected to said intermediate member, said detachable portion and said attached portion cooperating with each other to define a crankshaft hole for pivotally receiving a crankshaft and longitudinally aligned bolt holes, said wrist pin-receiving portion defining a wrist pin hole for pivotally receiving a wrist pin, and said laminated amide-imide connecting rod maintaining its structural integrity at engine operating conditions; and fastening means comprising bolts insertable in said bolt holes for securing said detachable portion to said attached portion about a crankshaft.

Claim 3

A composite engine part in accordance with claim 1 including a metal bushing mounted in said wrist pin hole and a split metal bearing mounted in said crankshaft hole.

Claim 4

A composite engine part in accordance with claim 1 wherein said attached portion of said laminated connecting rod comprises a generally U-shaped attached portion, said detached portion of said laminated connecting rod comprises an inverted generally U-shaped detached portion, and said attached and detachable portions of said laminated amide-imide connecting rod have interlocking shoulders for substantially minimizing lateral movement between said attached and detachable portions when secured about said crankshaft.

Claim 5

A composite engine part in accordance with claim 1 wherein said laminated connecting rod comprises from 55% to 75% by weight of said reinforcing material.

Claim 6

A composite engine part in accordance with claim 4 wherein said laminated connecting rod comprises about 65% by weight of said reinforcing material.

Claim 7

A composite engine part in accordance with claim 5 wherein said reinforcing material comprises graphite.

Claim 8

A composite engine part in accordance with claim 6 wherein said polymer comprises a product of about a 30% by weight of amide-imide resinous polymer and about a 70% by weight solvent of n-methyl-2-pyrrolidone.

Claim 9

A composite engine part in accordance with claim 1 wherein said connecting rod comprises a reaction product of a trifunctional carboxylic acid compound and at least one diprimary aromatic diamine.

Claim 10

A composite engine part in accordance with claim 8 wherein said connecting rod comprises at least one of the following moieties: ##STR8## wherein one carbonyl group is meta to and one carbonyl group is para to each amide group and wherein Z is a trivalent benzene ring or lower-alkyl-substituted trivalent benzene ring, R 1 and R 2 are different and are divalent aromatic hydrocarbon radicals of from 6 to about 10 carbon atoms or two divalent aromatic hydrocarbon radicals of from 6 to about 10 carbon atoms joined directly or by stable linkages selected from the group consisting of --O--, methylene, --CO--, --SO 2 --, and --S-- radicals and wherein said R 1 and R 2 containing units run from about 10 mole percent R 1 containing unit and about 90 mole percent R 2 containing unit to about 90 mole percent R 1 containing unit and about 10 mole percent R 2 containing unit.

Claim 11

A composite engine part in accordance with claim 9 wherein R 1 is ##STR9## and R 2 is ##STR10## or wherein R 1 is ##STR11## and R 2 is ##STR12##

Claim 12

A composite engine part in accordance with claim 9 wherein Z is a trivalent benzene ring, R 1 is ##STR13## R 2 is ##STR14## and wherein the concentration range runs from about 30 mole percent of the R 1 containing units and about 70 mole percent of the R 2 containing units to about 70 mole percent of the R 1 containing units and about 30 mole percent of the R 2 containing units.

Claim 13

A composite engine part in accordance with claim 1 wherein said connecting rod comprises from 30% to 100% by weight amide-imide resinous polymer.

Claim 14

A process for forming a composite laminated connecting rod for use in an engine, comprising the steps of: forming a stack having a plurality of plies including forming each ply by coating a fabric comprising graphite fibers with an amide-imide resinous polymer, drying each ply, and stacking said dried plies in a preform fixture; applying pressure to said stack of plies by placing a weight upon said stack of plies; staging said pressured stack of plies by heating said pressured stack of plies in an oven to consolidate said stack of plies and form an amide-imide blank; removing said weight; laminating said amide-imide blank by consolidating said amide-imide blank in a platen press and heating said amide-imide blank in said platen press; cooling said laminated amide-imide in said platen press to below its plastic deformation temperature; removing said cooled laminated amide-imide blank from said press; post curing said cooled laminated amide-imide blank by solid state polymerization to increase the strength and integrity of said laminated amide-imide blank; cutting the outside profile of a connecting rod in said post cured laminated amide-imide blank; drilling a wrist pin hole, a crankshaft hole and bolt holes in said post cured laminated amide-imide blank; splitting said post cured laminated amide-imide blank by substantially bisecting said crankshaft hole to form a generally U-shaped detachable portion and an inverted generally U-shaped attached portion; and bolting said detachable portion to said attached portion of said laminated amide-imide blank to form said composite connecting rod.

Claim 15

A process for forming a composite laminated connecting rod for use in an engine, comprising the steps of: forming a stack having a plurality of plies including forming each ply by coating a fabric comprising graphite fibers with an amide-imide resinous polymer, drying each ply, and stacking said dried plies in a preform fixture; applying pressure to said stack of plies by placing a weight upon said stack of plies; staging said pressured stack of plies by heating said pressured stack of plies in an oven to consolidate said stack of plies and form an amide-imide blank; removing said weight; laminating said amide-imide blank by consolidating said amide-imide blank in a platen press and heating said amide-imide blank in said platen press; cooling said laminated amide-imide in said platen press to below its plastic deformation temperature; removing said cooled laminated amide-imide blank from said press; post curing said cooled laminated amide-imide blank by solid state polymerization to increase the strength and integrity of said laminated amide-imide blank; cutting the outside profile of a connecting rod in said post cured laminated amide-imide blank; drilling a wrist pin hole, a crankshaft hole and bolt holes in said post cured laminated amide-imide blank; splitting said post cured laminated amide-imide blank by substantially bisecting said crankshaft hole to form a generally U-shaped detachable portion and an inverted generally U-shaped attached portion; and bolting said detachable portion to said attached portion of said laminated amide-imide blank to form said composite connecting rod.

Claim 16

A process in accordance with claim 13 including inserting a bushing in a wrist pin hole and a split metal bearing in said crankshaft hole.

Claim 17

A process in accordance with claim 13 including longitudinally opening said crankshaft hole to form an oval hole before said splitting, and said splitting includes sawing.

Claim 18

A process in accordance with claim 15 wherein said cutting includes cutting said post cured blank with a pattern on a milling machine to form said outside profile of said connecting rod, and grinding said laminated cut blank.

Claim 19

A process in accordance with claim 13 including 72 plies about 13 mils thick, drying said plies at about 300° F. for about 16 hours, heating said blank in an oven at about 500° F. for about 2 hours, heating said blank in said platen press at about 650° F. from about 2 minutes to 15 minutes at about 1,500 psi to 5,000 psi, and cooling said blank in said press to about 400° F. at about 1,500 psi to 5,000 psi.

Claim 20

A process in accordance with claim 13 wherein said ply comprises 55% to 75% by weight of said graphite and 25% to 45% by weight amide-imide resinous polymer.

Claim 21

A process in accordance with claim 18 wherein said ply comprises about 65% by weight graphite.

Claim 22

A process in accordance with claim 19 wherein said polymer is prepared by dissolving about 30% by weight of an amide-imide resinous polymeric material with about 70% by weight of a solvent comprising n-methyl-2-pyrrolidone.

Claim 23

A process in accordance with claim 18 wherein said amide-imide polymer is prepared by reacting a trifunctional carboxylic acid compound with at least one diprimary aromatic diamine.

Claim 24

A process in accordance with claim 18 wherein said amide-imide polymer comprises one of the following moieties: ##STR15## wherein one carbonyl group is meta to and one carbonyl group is para to each amide group and wherein Z is a trivalent benzene ring or lower-alkyl-substituted trivalent benzene ring, R 1 and R 2 are different and are divalent aromatic hydrocarbon radicals of from 6 to about 10 carbon atoms or two divalent aromatic hydrocarbon radicals of from 6 to about 10 carbon atoms joined directly or by stable linkages selected from the group consisting of --O--, methylene, --CO--, --SO 2 --, and --S-- radicals and wherein said R 1 and R 2 containing units run from about 10 mole percent R 1 containing unit and about 90 mole percent R 2 containing unit to about 90 mole percent R 1 containing unit and about 10 mole percent R 2 containing unit.

Claim 25

A process in accordance with claim 18 wherein R 1 is ##STR16## and R 2 is ##STR17## or wherein R 1 is ##STR18## and R 2 is ##STR19##

Claim 26

A process in accordance with claim 18 wherein Z is a trivalent benzene ring, R 1 is ##STR20## R 2 is ##STR21## and wherein the concentration range runs from about 30 mole percent of the R 1 containing units and about 70 mole percent of the R 2 containing units to about 70 mole percent of the R 1 containing units and about 30 mole percent of the R 2 containing units.