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US4457911A Expired / Lapsed US ⏱️ 0.0 years remaining

Dialkyl malonates as organic sunscreen adjuvants

Assignee: ISP Van Dyk Inc
•
Filing: 1982-08-03
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Granted: 1984-07-03
•
Expires: 2002-08-03
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Abstract

Abstract Compositions containing an organic sunscreen and particular substituted dialkyl malonates adjuvants therefor are very effective in providing broad spectrum sunscreen protection.

Inventors

  • 👤 Donald E. Conner
  • 👤 Boris M. Cumpelik

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 11:34
CPC Classifications
A; A61; A61Q; A61Q17/00; A61Q17/04; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/33; A61K8/37

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 97 words
A composition adapted for application to the human skin comprising a cosmetic oil carrier containing distributed therein an effective amount to provide substantial protection against erythemal and tanning radiation of an organic sunscreen selected from the group consisting of 2-ethylhexyl para methoxy cinnamate, homomenthyl salicylate, p-amino-benzoic acid and its esters, p-dimethyl amino benzoates, hydroxy and dihydroxy-4-methoxy benzophenones, and a benzalphthalide, and as an adjuvant therefor a dialkyl malonate selected from the group consisting of p-methoxy benzal diethyl malonate, p-methoxy benzal diisobutyl malonate, cinnamal diethyl malonate, indolal diethyl malonate, fural diethyl malonate, and 3,4,5 trimethoxy benzal diethyl malonate.
Claim 2
Dependent Claim 97 words
A composition adapted for application to the human skin comprising a cosmetic oil carrier containing distributed therein an effective amount to provide substantial protection against erythemal and tanning radiation of an organic sunscreen selected from the group consisting of 2-ethylhexyl para methoxy cinnamate, homomenthyl salicylate, p-amino-benzoic acid and its esters, p-dimethyl amino benzoates, hydroxy and dihydroxy-4-methoxy benzophenones, and a benzalphthalide, and as an adjuvant therefor a dialkyl malonate selected from the group consisting of p-methoxy benzal diethyl malonate, p-methoxy benzal diisobutyl malonate, cinnamal diethyl malonate, indolal diethyl malonate, fural diethyl malonate, and 3,4,5 trimethoxy benzal diethyl malonate.
Claim 3
Dependent Claim 13 words
The composition of claim 1 in which the adjuvant is p-methoxy diisobutyl malonate.
Claim 4
Dependent Claim 13 words
The composition of claim 1 in which the adjuvant in cinnamal diethyl malonate.
Claim 5
Dependent Claim 12 words
The composition of claim 1 in which the organic sunscreen is 4-pentoxybenzalphthalide.
Claim 6
Independent Claim 93 words
A method of protecting the human skin from the effects of erythema and tanning radiation in sunlight which comprises applying to said skin an effective sunscreening amount of an organic sunscreen selected from the group consisting of 2-ethylhexyl para methoxy cinnamate, homomenthyl salicylate, p-amino-benzoic acid and its esters, p-dimethylamino benzoates, hydroxy and dihydroxy-4-methoxybenzophenones, and a benzalphthalide, and as an adjuvant therefor a dialkyl malonate selected from the group consisting of p-methoxy benzal diethyl malonate, p-methoxy benzal diisobutyl malonate, cinnamal diethyl malonate, indolal diethyl malonate, fural diethyl malonate, and 3,4,5 trimethoxy benzal diethyl malonate.
Claim 7
Independent Claim 93 words
A method of protecting the human skin from the effects of erythema and tanning radiation in sunlight which comprises applying to said skin an effective sunscreening amount of an organic sunscreen selected from the group consisting of 2-ethylhexyl para methoxy cinnamate, homomenthyl salicylate, p-amino-benzoic acid and its esters, p-dimethylamino benzoates, hydroxy and dihydroxy-4-methoxybenzophenones, and a benzalphthalide, and as an adjuvant therefor a dialkyl malonate selected from the group consisting of p-methoxy benzal diethyl malonate, p-methoxy benzal diisobutyl malonate, cinnamal diethyl malonate, indolal diethyl malonate, fural diethyl malonate, and 3,4,5 trimethoxy benzal diethyl malonate.
Claim 8
Dependent Claim 14 words
The method of claim 5 in which the adjuvant is p-methoxy benzal diisobutyl malonate.
Claim 9
Dependent Claim 13 words
The method of claim 5 in which the adjuvant is cinnamal diethyl malonate.
Claim 10
Dependent Claim 12 words
The method of claim 5 in which the organic sunscreen is 4-pentoxybenzalphthalide.
Claim 11
Dependent Claim 23 words
The composition of claim 3 in which the total amount of sunscreen and adjuvant comprise up to about 10 wt.% of the composition.

References Cited (Backward Citations)

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US3123647A Cited
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US3160665A Cited
US3415875A Cited
US3670074A Cited
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JPS5239660A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-07-03 1988-01-02 1988-07-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-07-03 1992-01-02 1992-07-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-07-03 1996-01-02 1996-07-03 $7700.00 Window Closed / Lapsed

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