US4457858A
Expired / Lapsed
US
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Method of making coated granular bleach activators by spray drying
Assignee: Henkel AG and Co KGaA
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Filing: 1982-07-07
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Granted: 1984-07-03
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Expires: 2002-07-07
Abstract
Abstract Coated granular bleach activators and a process for their preparation comprising spray drying an aqueous slurry containing 1 to 1.7 parts by weight of water per part of a mixtue of (A) a powdery bleach activator and (B) at least one water soluble cellulose ether, starch, or starch ether in a ratio of A:B of from 99:1 to 90:10. The process utilizes a current of a drying gas having an entrance temperature of 100 DEG -200 DEG C. and an exit temperature of 40 DEG -120 DEG C.
Inventors
- 👤 Herbert Saran, deceased
- 👤 Martin Witthaus
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 05:02
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/39; C11D3/3902; C11D3/3905; C11D3/3907; C11D17/00; C11D17/0039; C11D3/3935
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
137 words
A process for the preparation of a bleach activator in granular form comprising the steps of (a) forming an aqueous slurry comprising (A) a bleach activator in powder form, and (B) at least one compound selected from the group consisting of water soluble cellulose ethers, starches, and starch ethers, wherein the slurry contains from about 1 to about 1.7 parts by weight of water per 1 part by weight of the combined nonaqueous ingredients in the slurry, wherein the weight ratio of (A) to (B) is from about 99:1 to about 90:10; and (b) spraying said slurry into a drying chamber wherein the drying gas has an initial contact temperature of from about 100° to about 200° C. to form a granulated bleach activator product having a water content of not more than about 3% by weight.
Claim 2
Dependent Claim
137 words
A process for the preparation of a bleach activator in granular form comprising the steps of (a) forming an aqueous slurry comprising (A) a bleach activator in powder form, and (B) at least one compound selected from the group consisting of water soluble cellulose ethers, starches, and starch ethers, wherein the slurry contains from about 1 to about 1.7 parts by weight of water per 1 part by weight of the combined nonaqueous ingredients in the slurry, wherein the weight ratio of (A) to (B) is from about 99:1 to about 90:10; and (b) spraying said slurry into a drying chamber wherein the drying gas has an initial contact temperature of from about 100° to about 200° C. to form a granulated bleach activator product having a water content of not more than about 3% by weight.
Claim 3
Dependent Claim
29 words
A process in accordance with claim 1 wherein the bleach activator in (A) is selected from the group consisting of N-acylated amines, N-acylated diamines, N-acylated amides, and N-acylated glycourils.
Claim 4
Dependent Claim
13 words
A process in accordance with claim 2 wherein the bleach activator is tetraacetylethylenediamine.
Claim 5
Dependent Claim
55 words
A process in accordance with claim 1 wherein the compound in (B) is at least one compound selected from the group consisting of methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, the sodium salt of carboxymethyl cellulose, or of methyl carboxymethyl cellulose, depolymerized starch, carboxymethyl starch, hydroxyethyl starch, and methyl starch.
Claim 6
Dependent Claim
19 words
A process in accordance with claim 4 wherein the compound in (B) is the sodium salt of carboxymethyl cellulose.
Claim 7
Dependent Claim
22 words
A process in accordance with claim 1 wherein the weight ratio of (A) to (B) is from about 97:3 to about 93:7.
Claim 8
Dependent Claim
27 words
A process in accordance with claim 1 wherein said slurry is formed by first mixing together the water and component (B), followed by mixing component (A) therewith.
Claim 9
Dependent Claim
33 words
A process in accordance with claim 1 wherein from about 1.3 to about 1.5 parts by weight of water per 1 part by weight of combined nonaqueous ingredients is present in the slurry.
Claim 10
Dependent Claim
26 words
A process in accordance with claim 1 wherein said gas in step (b) has an initial contact temperature of from about 120° to about 150° C.
Claim 11
Dependent Claim
17 words
A process in accordance with claim 1 wherein said drying gas is either air or flue gas.
Claim 12
Dependent Claim
27 words
A process in accordance with claim 1 wherein step (b) is carried out by spraying the slurry from spray nozzles at the top of a drying tower.
Claim 13
Dependent Claim
21 words
A process in accordance with claim 11 wherein the drying gas is introduced into the lower section of the drying tower.
Claim 14
Dependent Claim
32 words
A process in accordance with claim 11 or 12 wherein the drying gas exits at the top of the drying tower at a temperature of from about 40° to about 120° C.
Claim 15
Dependent Claim
24 words
A process in accordance with claim 1 wherein the granulated bleach activator product has a water content of from about 0.5% to about 2%.
Claim 16
Dependent Claim
52 words
A process in accordance with claim 1 wherein the particle size range of the product is as follows: 0 wt. % over 1.5 mm 10-50 wt. % of 1.5-0.2 mm 15-60 wt. % of 0.2-0.09 mm 5-50 wt. % of 0.09 to 0.03 mm up to 30 wt. % under 0.03 mm.
Claim 17
Dependent Claim
52 words
A process in accordance with claim 1 wherein the particle size range of the product is as follows: 0 wt. % over 1.5 mm 15-40 wt. % of 1.5-0.2 mm 20-50 wt. % of 0.2-0.09 mm 10-40 wt. % of 0.09 to 0.03 mm up to 30 wt. % under 0.03 mm.
Claim 18
Dependent Claim
49 words
A process in accordance with claim 1 wherein the slurry in (a) also contains one or more constituents that will remain stable in contact with the bleach activator (A) under the process conditions set forth in claim 1 and which will improve the properties of detergents when mixed therewith.
Claim 19
Dependent Claim
48 words
A process in accordance with claim 17 wherein the slurry contains at least one of the following constituents: (i) a polyglycol (ii) a nonionic surfactant (iii) a coloring agent (iv) silicic acid (v) finely divided zeolite (vi) a phosphate (vii) a neutral salt, and (viii) a foam inhibitor.
Claim 20
Dependent Claim
35 words
A process in accordance with claim 17 or 18 wherein from about 0.5 to about 5 wt. %, based on solids content of the slurry, of a foam inhibiting organopolysiloxane is added to the slurry.
Claim 21
Dependent Claim
35 words
A process in accordance with claim 17 or 18 wherein up to about 10 wt. %, based on the solids content of the slurry, of at least one nonionic surfactant is added to the slurry.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-07-03 | 1988-01-02 | 1988-07-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-07-03 | 1992-01-02 | 1992-07-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-07-03 | 1996-01-02 | 1996-07-03 | $7700.00 | Window Closed / Lapsed |