US4452929A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Water reducible epoxy based coating compositions
Assignee: Shell USA Inc
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Filing: 1983-09-09
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Granted: 1984-06-05
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Expires: 2003-09-09
Abstract
Abstract Aqueous coating composition, useful on metal substrates which are deep drawn after being coated, e.g., bottle caps, are made from (A) a blend of an aqueous solution of the reaction product of a glycidyl polyether of a dihydric phenol, a polyethylene glycol and phosphoric acid, (B) an aqueous dispersion of a glycidyl polyether of a dihydric phenol and, optionally, (C) an alkoxymethylmelamine.
Inventors
- 👤 Edward J. Powers
- 👤 Thomas E. Walsh
- 👤 Donald R. Stewart
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 01:50
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/62; C08G59/14; C08G59/1405; C08G59/1422; C08G59/182; C08G59/20; C08G59/22; C08G59/226; C08G59/4007; C08G59/4071; C09; C09D; C09D163/00
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
205 words
A coating composition comprising A. an aqueous solution of a resinous composition which is the reaction product of: (i) about 55 to about 90 weight percent of a glycidyl polyether of a dihydric phenol having an epoxide equivalent weight of about 400 to about 1200; (ii) about 8 to about 44.1 weight percent of a polyethylene glycol having a molecular weight of about 300 to about 2000; and (iii) about 0.9 to about 2 weight percent of ortho phosphoric acid; wherein said aqueous solution has a solids content of about 20 to about 50 weight percent; B. an aqueous dispersion of a glycidyl polyether of a dihydric phenol having an epoxide equivalent weight of about 400 to about 2000, wherein said aqueous dispersion has a solids content of about 30 to about 70 weight percent; and C. an alkoxymethylmelamine wherein A, B, and C are blended in such amounts that the coating composition contains about 30 to about 60 weight percent of the reaction product of A, about 40 to about 60 weight percent of the glycidyl polyether of B and 0 to about 10 weight percent of C, said weight percents being based on the total weight of reaction product, glycidyl polyether and alkoxymethylmelamine.
Claim 2
Dependent Claim
205 words
A coating composition comprising A. an aqueous solution of a resinous composition which is the reaction product of: (i) about 55 to about 90 weight percent of a glycidyl polyether of a dihydric phenol having an epoxide equivalent weight of about 400 to about 1200; (ii) about 8 to about 44.1 weight percent of a polyethylene glycol having a molecular weight of about 300 to about 2000; and (iii) about 0.9 to about 2 weight percent of ortho phosphoric acid; wherein said aqueous solution has a solids content of about 20 to about 50 weight percent; B. an aqueous dispersion of a glycidyl polyether of a dihydric phenol having an epoxide equivalent weight of about 400 to about 2000, wherein said aqueous dispersion has a solids content of about 30 to about 70 weight percent; and C. an alkoxymethylmelamine wherein A, B, and C are blended in such amounts that the coating composition contains about 30 to about 60 weight percent of the reaction product of A, about 40 to about 60 weight percent of the glycidyl polyether of B and 0 to about 10 weight percent of C, said weight percents being based on the total weight of reaction product, glycidyl polyether and alkoxymethylmelamine.
Claim 3
Dependent Claim
26 words
The coating composition of claim 1 wherein the glycidyl polyether of a dihydric phenol in A and in B is a glycidyl polyether of p,p'-dihydroxydiphenyl propane.
Claim 4
Dependent Claim
45 words
The coating composition of claim 2 wherein the glycidyl polyether of p,p'-dihydroxydiphenyl propane of A has an epoxide equivalent weight of about 500 to about 750 and the glycidyl polyether of p,p'-dihydroxydiphenyl propane of B has an epoxide equivalent of about 500 to about 650.
Claim 5
Dependent Claim
20 words
The coating composition of claim 1 wherein the polyethylene glycol has a molecular weight of about 500 to about 1200.
Claim 6
Dependent Claim
49 words
The coating composition of claim 1 wherein the resinous composition of A is the reaction product of about 60 to about 75 weight percent glycidyl polyether of a dihydric phenol, about 24 to about 38.5 weight percent polyethylene glycol and about 1 to about 1.5 weight percent phosphoric acid.
Claim 7
Dependent Claim
11 words
The coating composition of claim 1 wherein the alkoxymethylmelamine is hexamethoxymethylmelamine.
Claim 8
Dependent Claim
11 words
The coating composition of claim 1 wherein the alkoxymethylmelamine is trimethoxymethylmelamine.
Claim 9
Dependent Claim
55 words
The coating composition of claim 1 wherein A, B and C are blended in such amounts that the coating composition contains about 40 to about 53 weight percent reaction product of A, about 45 to about 55 weight percent of the glycidyl polyether of B and about 2 to about 5 weight percent of C.
References Cited (Backward Citations)
US3100756A
Cited
US3352809A
Cited
US3957716A
Cited
US4059550A
Cited
US4289812A
Cited
US4360613A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-06-05 | 1987-12-05 | 1988-06-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-06-05 | 1991-12-05 | 1992-06-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-06-05 | 1995-12-05 | 1996-06-05 | $7700.00 | Window Closed / Lapsed |