US4452860A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Carbon fibers and process for producing the same
Assignee: Hercules LLC
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Filing: 1983-01-24
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Granted: 1984-06-05
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Expires: 2003-01-24
Abstract
Abstract In the course of producing acrylic fibers, the spun filament bundle before the heat stretching treatment is subjected to a special stretching treatment in a warm water bath under a specific condition so that the degree of filament separability of said spun filament bundle traveling through the heat stretching step will be maintained within a prescribed range, and when the acrylic fibers so prepared are heat-treated for carbonization, carbon fibers representing a peculiar load-elongation behavior can be produced in an industrially advantageous manner.
Inventors
- 👤 Isamu Obama
- 👤 Yoshihisa Yamamoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 13:55
CPC Classifications
D; D01; D01F; D01F9/00; D01F9/08; D01F9/12; D01F9/14; D01F9/32; D01F9/20; D01F9/21; D01F9/22; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2918
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
261 words
A bundle of carbonized filaments, said bundle having a load-elongation curve wherein the greatest load peak is situated in a region above 0.7% elongation and wherein there is no load maximum peak or shoulder-shaped peak resulting from interaction between the filaments appearing in the region below 0.5% elongation, said fiber produced by a process which comprises: (a) forming a spinning solution of an acrylonitrile polymer containing at least 90 wt % acrylonitrile, (b) extruding said spinning solution through a spinnerette having a plurality of orifices into air or an inert gas which is a non-coagulating gas for said spinning solution to form a filament bundle, (c) cold stretching said filament bundle, (d) water washing said spun filament bundle, (e) introducing said washed filament bundle into a gel treating bath comprising an aqueous solution containing alkali metal or ammonium ions, (f) pre-stretching the filament bundle of step (e) in a water bath at a temperature which is more than 10° C. lower than the heat stretching treatment of following step (g) but not lower than 30° C. and at a stretching ratio satisfying formula (2) below, (g) heat-stretching the filament bundle of step (f) in a water bath having a temperature determined as indicated in step (f) and wherein the coefficient of filament separability of the filament bundle produced by this step is 1.2 to 4.0, said coefficient being determined by the formula (1): ##EQU3## wherein A represents the stretching ratio in step (f) and B represents the stretching ratio in step (g) and (h) carbonizing the filament bundle of step (g).
Claim 2
Dependent Claim
261 words
A bundle of carbonized filaments, said bundle having a load-elongation curve wherein the greatest load peak is situated in a region above 0.7% elongation and wherein there is no load maximum peak or shoulder-shaped peak resulting from interaction between the filaments appearing in the region below 0.5% elongation, said fiber produced by a process which comprises: (a) forming a spinning solution of an acrylonitrile polymer containing at least 90 wt % acrylonitrile, (b) extruding said spinning solution through a spinnerette having a plurality of orifices into air or an inert gas which is a non-coagulating gas for said spinning solution to form a filament bundle, (c) cold stretching said filament bundle, (d) water washing said spun filament bundle, (e) introducing said washed filament bundle into a gel treating bath comprising an aqueous solution containing alkali metal or ammonium ions, (f) pre-stretching the filament bundle of step (e) in a water bath at a temperature which is more than 10° C. lower than the heat stretching treatment of following step (g) but not lower than 30° C. and at a stretching ratio satisfying formula (2) below, (g) heat-stretching the filament bundle of step (f) in a water bath having a temperature determined as indicated in step (f) and wherein the coefficient of filament separability of the filament bundle produced by this step is 1.2 to 4.0, said coefficient being determined by the formula (1): ##EQU3## wherein A represents the stretching ratio in step (f) and B represents the stretching ratio in step (g) and (h) carbonizing the filament bundle of step (g).
Claim 3
Independent Claim
265 words
A method for producing a bundle of carbonized filaments, said bundle having a load-elongation curve wherein the greatest load peak is situated in a region above 0.7% elongation and wherein there is no load maximum peak or shoulder -shaped peak resulting from interation between the filaments appearing in the region to below 0.5% elongation, said method comprising the following steps: (a) forming a spinning solution of an acrylonitrile polymer containing at least 90 wt % acrylonitrile, (b) extruding said spinning solution through a spinnerette having a plurality of orifices into air or an inert gas which is a non-coagulating gas for said spinning solution to form a filament bundle, (c) cold stretching said filament bundle, (d) water washiing said spun filament bundle, (e) introducing said washed filament bundle into a gel treating bath comprising an aqueous solution containing alkali metal or ammonium ions, (f) pre-stretching the filament bundle of step (e) in a water bath at a temperature which is more than 10° C. lower than the heat stretching treatment of following step (g) but not lower than 30° C. and at a stretching ratio satisfying formula (2) below, (g) heat-stretching the filament bundle of step (f) in a water bath having a temperature determined as indicated in step (f) and wherein the coefficient of filament separability of the filament bundle produced by this step is 1.2 to 4.0, said coefficient being determined by the formula (1): ##EQU4## wherein A represents the stretching ratio in step (f) and B represents the stretching ratio in step (g) and (h) carbonizing the filament bundle of step (g).
Claim 4
Independent Claim
265 words
A method for producing a bundle of carbonized filaments, said bundle having a load-elongation curve wherein the greatest load peak is situated in a region above 0.7% elongation and wherein there is no load maximum peak or shoulder -shaped peak resulting from interation between the filaments appearing in the region to below 0.5% elongation, said method comprising the following steps: (a) forming a spinning solution of an acrylonitrile polymer containing at least 90 wt % acrylonitrile, (b) extruding said spinning solution through a spinnerette having a plurality of orifices into air or an inert gas which is a non-coagulating gas for said spinning solution to form a filament bundle, (c) cold stretching said filament bundle, (d) water washiing said spun filament bundle, (e) introducing said washed filament bundle into a gel treating bath comprising an aqueous solution containing alkali metal or ammonium ions, (f) pre-stretching the filament bundle of step (e) in a water bath at a temperature which is more than 10° C. lower than the heat stretching treatment of following step (g) but not lower than 30° C. and at a stretching ratio satisfying formula (2) below, (g) heat-stretching the filament bundle of step (f) in a water bath having a temperature determined as indicated in step (f) and wherein the coefficient of filament separability of the filament bundle produced by this step is 1.2 to 4.0, said coefficient being determined by the formula (1): ##EQU4## wherein A represents the stretching ratio in step (f) and B represents the stretching ratio in step (g) and (h) carbonizing the filament bundle of step (g).
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-06-05 | 1987-12-05 | 1988-06-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-06-05 | 1991-12-05 | 1992-06-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-06-05 | 1995-12-05 | 1996-06-05 | $7700.00 | Window Closed / Lapsed |