Substituted anthracene-type isotropic dyes for liquid crystal display devices

Claim 2

A composition of matter comprising a nematic, smectic or cholesteric liquid crystal material, at least one dichroic dyestuff, and an isotropic dyestuff having the general formula ##STR23## wherein W is selected from the group consisting of ##STR24## wherein: R is independently selected from the group consisting of H and C n H 2n+1 ; Q is indepedently selected from the group consisting of H, OH, NH 2 , CN, OC n H 2n+1 , NO 2 , C n H 2n+1 , ##STR25## F, Cl, Br, SH, CHO and CF 3 ; x is 1 to 8; and n is 0 to about 20, wherein said isotropic dyestuff has an optical order parameter of about 0.

Claim 3

The composition of claim 1 wherein said isotropic dyestuff is selected from the group consisting of ##STR26##

Claim 4

The composition of claim 1 wherein said dichroic dye is an azo, azo-stilbene, benzothiazolylpolyazo, methine, azomethine, merocyanine, methinearylidene, tetrazine, oxadiazine, carbazole-azo or anthraquinone type dye, having an absorption maxima between about 400 and 700 nm, and having an optical order parameter of greater than about 0.5.

Claim 5

The composition of claim 1 wherein the concentration of said isotropic dyestuff is about 0.1 to 5 percent by weight of said liquid crystal material, and the concentration of said dichroic dyestuff is about 0.1 to 5 percent by weight of said liquid crystal material.

Claim 6

The composition of claim 1 wherein there is additionally present an optically-active dopant in an amount sufficient to cholesterically order said composition of matter.

Claim 7

The composition of claim 1 wherein said dichroic dye is a helichromic compound, said helichromic compound being a circularly dichroic dye having both a chromophoric moiety and an optically-active moiety, and said helichromic compound is present in said composition in an amount sufficient to enable said composition to propagate light in a circularly polarized manner.

Claim 8

An improved "guest-host" type liquid crystal display which is responsive to the absence or presence of an electric field, and which appears one color in the absence of said electric field and another color in the presence of said electric field, said device comprising: (a) a "guest-host" layer comprising a nematic liquid crystal material and at least one dichroic dye which has an absorption maximum between about 400 and 700 nm; and (b) two conductive electrodes positioned, respectively, adjacent opposing surfaces of said layer; wherein the improvement comprises the presence of the isotropic dyestuff of claim 1 in admixture with said "guest-host," liquid crystal-dichroic dye mixture.

Claim 9

An improved "phase-change" type liquid crystal display device which is responsive to the absence or presence of an electric field, and which appears one color in the absence of said electric field and another color in the presence of said electric field, said device comprising: (a) a layer of a nematic liquid crystal material in admixture with at least one dichroic dye which has an absorption maximum between about 400 and 700 nm, and an optically-active compound; and (b) two conductive electrodes positioned, respectively, adjacent opposing surfaces of said layer; wherein the improvement comprises the presence of the isotropic dyestuff of claim 1 in admixture with said liquid crystal material-dichroic dye mixture.

Claim 10

An improved "helichromic" type liquid crystal display device which is responsive to the absence or presence of an electric field, and which appears one color in the absence of an electric field and another color in the presence of said electric field, said device comprising: (a) a layer of a nematic liquid crystal material in admixture with an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound comprising at least one chromophoric moiety, and at least one optically-active moiety, and said helichromic compound being a circularly dichroic dye having an absorption maximum between about 400 and 700 nm; and (b) two conductive electrodes positioned, respectively, adjacent opposing surfaces of said layer; wherein the improvement comprises the presence of the isotropic dyestuff of claim 1 in admixture with said liquid crystal-helichromic compound mixture.

Claim 11

An improved thermally-addressable liquid crystal display device, which is responsive to the absence or presence of an electric field, and which appears one color in the absence of said electric field and another color in the presence of said electric field, said device comprising: (a) a layer of a liquid crystal medium in admixture with at least one dichroic dye which has an absorption maximum between about 400 and 700 nm, said layer disposed between a top substrate and a bottom substrate, said liquid crystal medium being thermally sensitive and having a transition between at least two thermal phases, an upper phase being a nematic or isotropic phase and a lower thermal phase being a smectic phase, said mixture having two possible states of orientation in said smectic phase, a first orientation state being a state in which said dichroic dye is substantially light absorbing and a second state being a state in which said dichroic dye is substantially light transmissive; (b) a means of affecting a thermal transition between said lower thermal phase and said upper thermal phase; and (c) a means of electrically addressing portions of said mixture to develop said second orientation state when said mixture passes rapidly into said lower thermal state from said upper thermal state, the remaining unaddressed portions of said mixture developing said first orientation state when said mixture passes rapidly into said lower thermal state from said upper thermal state; wherein the improvement comprises the presence of the isotropic dyestuff of claim 1 in said liquid crystal medium.

Claim 12

An improved thermally-addressable "cholesteric-smectic" type liquid crystal display device which is responsive to the absence or presence of an electric field, and which appears one color in the absence of said electric field and another color in the presence of said electric field, said device comprising: (a) a layer of a smectic liquid crystal medium in admixture with at least one dichroic dye which has an absorption maximum between about 400 and 700 nm, and an optically-active cholesteric compound, said layer disposed between a top substrate and a bottom substrate, said liquid crystal medium being thermally sensitive and having a transition between at least two thermal phases, an upper phase being a cholesteric or isotropic phase and a lower thermal phase being a smectic phase, said mixture having two possible states of orientation in said smectic phase, a first orientation state being a state in which said dichroic dye is substantially light absorbing and a second state being a state in which said dichroic dye is substantially light transmissive; (b) a means of affecting a thermal transition between said lower thermal phase and said upper thermal phase; and (c) a means of electrically addressing portions of said mixture to develop said second orientation state when said mixture passes rapidly into said lower thermal state from said upper thermal state, the remaining unaddressed portions of said mixture developing said first orientation state when said mixture passes rapidly into said lower thermal state from said upper thermal state; wherein the improvement comprises the presence of the isotropic dyestuff of claim 1 in said liquid crystal medium.

Claim 13

An improved thermally-addressable "helichromic-smectic" liquid crystal display device which is responsive to the absence or presence of an electric field, and which appears one color in the absence of said electric field and another color in the presence of said electric field, said device comprising: (a) a layer of a smectic liquid crystal medium in admixture with an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound comprising at least one chromophoric moiety and at least one optically-active moiety, and said helichromic compound being a circularly dichroic dye, having an absorption maximum between about 400 and 700 nm, said layer disposed between a top substrate and a bottom substrate, said liquid crystal medium being thermally sensitive and having a transition between at least two thermal phases, an upper phase being a helichromic phase and a lower thermal phase being a smectic phase, said mixture having two possible states of orientation in said smectic phase, a first orientation state being a state in which said helichromic compound is substantially light absorbing and a second state being a state in which said helichromic compound is substantially light transmissive; (b) a means of affecting a thermal transition between said lower thermal phase and said upper thermal phase; and (c) a means of electrically addressing portions of said mixture to develop said second orientation state when said mixture passes rapidly into said lower thermal state from said upper thermal state, the remaining unaddressed portions of said mixture developing said first orientation state when said mixture passes rapidily into said lower thermal state from said upper thermal state; wherein the improvement comprises the presence of the isotropic dyestuff of claim 1 in said liquid crystal medium.