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US4451599A Expired / Lapsed US ⏱️ 0.0 years remaining

Plasticized EVOH and process and products utilizing same

Assignee: Pechiney Plastic Packaging Inc
•
Filing: 1982-04-19
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Granted: 1984-05-29
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Expires: 2002-04-19
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Abstract

Abstract An EVOH copolymer blend is extrudable to produce films of uniform caliper and excellent oxygen barrier properties. Aromatic sulfonamides are desirably utilized as plasticizers, and superior composite films including a layer of the plasticized EVOH are produced.

Inventors

  • 👤 Thomas W. Odorzynski
  • 👤 II Jack E. Knott

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 02:02
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/0016; B; B32; B32B; B32B27/00; B32B27/32; C08K5/36; C08K5/43; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L23/0846; C08L23/0853; C08L23/0861

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 125 words
An ethylene vinyl alcohol copolymer resin blend that is extrudable to produce a film of uniform caliber and excellent oxygen barrier properties, consisting essentially of about 95 to 80 weight percent of ethylene vinyl alcohol copolymer having a molecular weight of about 15,000 to 30,000 and a melting point temperature of about 325 degrees to 375 degrees Fahrenheit, and conversely about 5 to 20 weight percent of a plasticizing agent selected from the group consisting of aromatic sulfonamide plasticizers and is selected from the class consisting of o-p-toluene sulfonamide, N-ethyl-o, p-toluene-sulfonamide and ethylbenzene sulfonamide polyethyl oxazoline, polyvinyl pyrrolidone, polyvinyl formaldehyde, and polyamides having melting point temperatures below about 400 degrees Fahrenheit, said plasticizers being compatible with said copolymer and capable of intermolecular hydrogen bonding therewith.
Claim 2
Dependent Claim 125 words
An ethylene vinyl alcohol copolymer resin blend that is extrudable to produce a film of uniform caliber and excellent oxygen barrier properties, consisting essentially of about 95 to 80 weight percent of ethylene vinyl alcohol copolymer having a molecular weight of about 15,000 to 30,000 and a melting point temperature of about 325 degrees to 375 degrees Fahrenheit, and conversely about 5 to 20 weight percent of a plasticizing agent selected from the group consisting of aromatic sulfonamide plasticizers and is selected from the class consisting of o-p-toluene sulfonamide, N-ethyl-o, p-toluene-sulfonamide and ethylbenzene sulfonamide polyethyl oxazoline, polyvinyl pyrrolidone, polyvinyl formaldehyde, and polyamides having melting point temperatures below about 400 degrees Fahrenheit, said plasticizers being compatible with said copolymer and capable of intermolecular hydrogen bonding therewith.
Claim 3
Dependent Claim 19 words
The composition of claim 1 wherein said composition contains at least about 90 weight percent of said EVOH copolymer.
Claim 4
Dependent Claim 26 words
The composition of claim 1 wherein said plasticizer is an aromatic sulfonamide and is selected from the class consisting of o,p-toluene sulfonamide, N-ethyl-o,p-toluenesulfonamide and ethylbenzene sulfonamide.

References Cited (Backward Citations)

US4284671A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-29 1987-11-28 1988-05-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-29 1991-11-28 1992-05-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-29 1995-11-28 1996-05-29 $7700.00 Window Closed / Lapsed

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