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US4451375A Expired / Lapsed US ⏱️ 0.0 years remaining

Iodine adsorption via picolylamine ion exchange resins

Assignee: Dow Chemical Co
•
Filing: 1983-08-25
•
Granted: 1984-05-29
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Expires: 2003-08-25
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Abstract

Abstract Resins bearing picolylamine moieties selectively adsorb iodide ions from acidic aqueous solutions. The iodide can be readily eluted from the resin with base. Particularly useful resins are obtained by reacting chloromethylated styrene-divinylbenzene copolymers with N-(2-hydroxyethyl)-2-picolylamine or bis-(2-picolyl)amine.

Inventors

  • 👤 Robert R. Grinstead

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 20:05
CPC Classifications
B; B01; B01J; B01J41/00; B01J41/04

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 60 words
A method of extracting iodide ions from an aqueous medium comprising: (a) contacting an acidic aqueous medium containing iodide ions with a polymer bearing a plurality of moieties each containing at least one picolylamine group; (b) separating the polymer from the aqueous medium; and (c) contacting the polymer with a base so as to elute iodide adsorbed by the polymer.
Claim 2
Independent Claim 60 words
A method of extracting iodide ions from an aqueous medium comprising: (a) contacting an acidic aqueous medium containing iodide ions with a polymer bearing a plurality of moieties each containing at least one picolylamine group; (b) separating the polymer from the aqueous medium; and (c) contacting the polymer with a base so as to elute iodide adsorbed by the polymer.
Claim 3
Dependent Claim 26 words
The method as described in claim 1 wherein the aqueous medium to be extracted also contains chloride ions and K Cl I is at least 10.
Claim 4
Dependent Claim 18 words
The method as described in claim 2 wherein the polymer contains picolylamine moieties corresponding to the formula ##STR3##
Claim 5
Dependent Claim 18 words
The method as described in claim 2 wherein the polymer contains picolylamine moieties corresponding to the formula ##STR4##

References Cited (Backward Citations)

US2157508A Cited
US2945746A Cited
FR1401113A Cited
US3352641A Cited
SU339130A1 Cited
US4131645A Cited
US4031038A Cited
US4098867A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-29 1987-11-28 1988-05-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-29 1991-11-28 1992-05-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-29 1995-11-28 1996-05-29 $7700.00 Window Closed / Lapsed

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