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US4451355A Expired / Lapsed US ⏱️ 0.0 years remaining

Vanadium passivation in a hydrocarbon catalytic cracking process

Assignee: Chevron USA Inc
•
Filing: 1983-09-28
•
Granted: 1984-05-29
•
Expires: 2003-09-28
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Abstract

Abstract Hydrocarbons containing vanadium are converted to lower boiling fractions employing a zeolitic cracking catalyst containing a significant concentration of a calcium-containing additive as a vanadium passivating agent.

Inventors

  • 👤 Bruce R. Mitchell
  • 👤 Roger F. Vogel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 10:28
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; C10G11/05; C10G2300/00; C10G2300/70; C10G2300/705; Y; Y10; Y10S; Y10S502/00; Y10S502/521; Y10S502/525

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 49 words
A process for the conversion of a hydrocarbon oil feed having a significant concentration of vanadium to lighter oil products which comprises contacting said feed under conversion conditions with a cracking catalyst containing a calcium-containing additive selected from the group consisting of calcium-titanium, calcium-zirconium, calcium-titanium-zirconium oxides and mixtures thereof.
Claim 2
Dependent Claim 49 words
A process for the conversion of a hydrocarbon oil feed having a significant concentration of vanadium to lighter oil products which comprises contacting said feed under conversion conditions with a cracking catalyst containing a calcium-containing additive selected from the group consisting of calcium-titanium, calcium-zirconium, calcium-titanium-zirconium oxides and mixtures thereof.
Claim 3
Dependent Claim 18 words
The process of claim 1 wherein the concentration of vanadium in said feed is at least 1.5 ppm.
Claim 4
Dependent Claim 18 words
The process of claim 1 wherein the concentration of vanadium in said catalyst is at least 4000 ppm.
Claim 5
Dependent Claim 16 words
The process of claim 1 wherein the concentration of vanadium on said catalyst exceeds 30,000 ppm.
Claim 6
Dependent Claim 14 words
The process of claim 1 wherein said catalyst includes a catalytically inert porous material.
Claim 7
Dependent Claim 26 words
The process of claim 1 wherein said calcium-containing additive comprises a perovskite selected from the group consisting of calcium titanate and calcium zirconate and mixtures thereof.
Claim 8
Dependent Claim 26 words
The process of claim 6 wherein the concentration of said perovskite is in the range of 5 to 40 weight percent based on the total catalyst.
Claim 9
Dependent Claim 26 words
The process of claim 6 wherein the concentration of said perovskite is in the range of 11 to 40 weight percent based on the total catalyst.

References Cited (Backward Citations)

US2258787A Cited
US2344911A Cited
US2638453A Cited
US2886513A Cited
US3471410A Cited
US3546094A Cited
US3696025A Cited
US4179409A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-29 1987-11-28 1988-05-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-29 1991-11-28 1992-05-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-29 1995-11-28 1996-05-29 $7700.00 Window Closed / Lapsed

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