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US4450190A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for sensitizing articles for metallization and resulting articles

Assignee: MECHATRONICS LLC
•
Filing: 1979-10-01
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Granted: 1984-05-22
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Expires: 1999-10-01
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Abstract

Abstract Surfaces of articles are sensitized for the deposition of adherent metal from electroless metal solutions in contact therewith by prior treatment with an activatable complex of copper in a liquid medium formed from a solution comprising a mixture of halogen, cuprous and cupric components and thereafter forming a deposit on the treated article surfaces of a water-insoluble derivative of the said complex. Such surface deposits are treated with a reducing agent or water to enhance their reception of metal in an electroless metal deposition bath.

Inventors

  • 👤 Francis J. Nuzzi
  • 👤 Edward J. Leech
  • 👤 Richard W. Charm
  • 👤 Joseph Polichette

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 11:39
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/1851; C23C18/1872; C23C18/1886; C23C18/1889

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 138 words
A process for the electroless deposition of metal on a non-metallic surface, said process comprising the steps of: (a) pre-sensitizing the non-metallic surface to the electroless deposition of metal by contacting said non-metallic surface with a liquid medium comprising an admixture of a polar liquid, a halide, cupric ions and cuprous ions in a weight ratio of cuprous ions to cupric ions of at least 0.4:1; (b) Rinsing said contacted surface with an aqueous solution and forming an adherent water-insoluble derivative of said liquid medium adsorbed on said non-metallic surface; (c) treating said rinsed surface with an electroless metal deposition bath containing a reducing agent to render said insoluble derivative catalytic to the electroless deposition of metal; and (d) contacting said catalytically sensitive surface with an electroless metal deposition bath to form an electroless deposit of metal thereon.
Claim 2
Dependent Claim 138 words
A process for the electroless deposition of metal on a non-metallic surface, said process comprising the steps of: (a) pre-sensitizing the non-metallic surface to the electroless deposition of metal by contacting said non-metallic surface with a liquid medium comprising an admixture of a polar liquid, a halide, cupric ions and cuprous ions in a weight ratio of cuprous ions to cupric ions of at least 0.4:1; (b) Rinsing said contacted surface with an aqueous solution and forming an adherent water-insoluble derivative of said liquid medium adsorbed on said non-metallic surface; (c) treating said rinsed surface with an electroless metal deposition bath containing a reducing agent to render said insoluble derivative catalytic to the electroless deposition of metal; and (d) contacting said catalytically sensitive surface with an electroless metal deposition bath to form an electroless deposit of metal thereon.
Claim 3
Dependent Claim 27 words
A process according to claim 1, wherein said reducing agent includes at least one member selected from the group consisting of borohydrides, amine boranes and hydrazine hydrate.
Claim 4
Dependent Claim 14 words
A process according to claim 1, wherein said liquid medium also contains a stabilizer.
Claim 5
Dependent Claim 15 words
A process according to claim 1, wherein said liquid medium also contains a wetting agent.

References Cited (Backward Citations)

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US3561995A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-22 1987-11-21 1988-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-22 1991-11-21 1992-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-22 1995-11-21 1996-05-22 $7700.00 Window Closed / Lapsed

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