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US4450013A Expired / Lapsed US ⏱️ 0.0 years remaining

Grinding or dispersing agents for pigments

Assignee: BASF SE
•
Filing: 1982-06-10
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Granted: 1984-05-22
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Expires: 2002-06-10
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Abstract

Abstract The subject invention relates to compositions which are used as auxiliaries for pigment grinding and as dispersing agents for pigments. The compositions are essentially copolymers based upon acrylic acid, methacrylic acid, and sulfonic acid group containing monomers such as 2-acrylamido-2-methylpropanesulfonic acid.

Inventors

  • 👤 Guenter Hirsch
  • 👤 Gregor Ley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:22
CPC Classifications
D; D21; D21H; D21H19/00; D21H19/36; D21H19/44; D21H19/56; D21H19/58; C; C08; C08F; C08F220/00; C08F220/02; C08F220/04; C08F220/06; C09; C09K; C09K23/00; C09K23/22; C09K23/24

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 226 words
A stable, highly concentrated aqueous slurry of an inorganic pigment selected from the group consisting of chalk, clay from primary and secondary deposits, satin white, titanium dioxide, kaolin, and dolomite, said slurry having a viscosity largely unaffected by temperature change between 25° C. and 70° C.; wherein the slurry is stabilized by a dispersant which is a copolymer of: (a) 40 to 90 percent by weight of an ethylenically unsaturated aliphatic carboxylic acid selected from the group consisting of acrylic and methacrylic acids, (b) 10 to 60 percent by weight of a compound having the formula: ##STR4## where R is hydrogen or methyl X is --NH-- or --O-- A is C 1 to C 8 alkylene or C 1 to C 3 substituted alkylene, and Me is hydrogen, sodium potassium, or ammonium; and (c) 0 to 10 percent by weight of another ethylenically unsaturated copolymerizable monomer selected from the group consisting of acrylate and methacrylate esters of C 1 -C 4 alcohols, C 1 -C 4 esters or half esters of maleic acid, acrylo- and methacrylonitrile, acryl- and methacrylamide; said copolymer dispersant having a K-value of 15 to 50 and an adjusted pH value of 7 to 8 in one percent solution at 20° C. and being used in an amount of 0.05 to 1.0 percent by weight based on the amount of pigment being dispersed.
Claim 2
Dependent Claim 226 words
A stable, highly concentrated aqueous slurry of an inorganic pigment selected from the group consisting of chalk, clay from primary and secondary deposits, satin white, titanium dioxide, kaolin, and dolomite, said slurry having a viscosity largely unaffected by temperature change between 25° C. and 70° C.; wherein the slurry is stabilized by a dispersant which is a copolymer of: (a) 40 to 90 percent by weight of an ethylenically unsaturated aliphatic carboxylic acid selected from the group consisting of acrylic and methacrylic acids, (b) 10 to 60 percent by weight of a compound having the formula: ##STR4## where R is hydrogen or methyl X is --NH-- or --O-- A is C 1 to C 8 alkylene or C 1 to C 3 substituted alkylene, and Me is hydrogen, sodium potassium, or ammonium; and (c) 0 to 10 percent by weight of another ethylenically unsaturated copolymerizable monomer selected from the group consisting of acrylate and methacrylate esters of C 1 -C 4 alcohols, C 1 -C 4 esters or half esters of maleic acid, acrylo- and methacrylonitrile, acryl- and methacrylamide; said copolymer dispersant having a K-value of 15 to 50 and an adjusted pH value of 7 to 8 in one percent solution at 20° C. and being used in an amount of 0.05 to 1.0 percent by weight based on the amount of pigment being dispersed.
Claim 3
Dependent Claim 40 words
The product of claim 1 wherein the copolymer is produced by the copolymerization of the monomer mixture in isopropanol containing 0 to 60 percent by weight of water at a temperature of 95° C. to 180° C. under autogenous pressure.
Claim 4
Dependent Claim 20 words
The product of claim 1 wherein the copolymer contains as a monomer of group (b), 2-acrylamido-2-methylpropanesulfonic acid in polymerized form.
Claim 5
Dependent Claim 20 words
The product of claim 2 wherein the copolymer contains as a monomer of group (b), 2-acrylamido-2-methylpropanesulfonic acid in polymerized form.

References Cited (Backward Citations)

US3022299A Cited
US4158572A Cited
US4243430A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-22 1987-11-21 1988-05-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-22 1991-11-21 1992-05-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-22 1995-11-21 1996-05-22 $7700.00 Window Closed / Lapsed

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