Epoxy resin and the process for its production

Claim 2

An epoxy resin substantially represented by the general formula ##STR5## where Ar 1 is a residual group of a dihydric phenol derived from a compound having one or two benzene nuclei, Ar 2 is residual group of a halogen-substituted benzenoid compound having two halogen atoms on its nuclei and represented by the formula --Ar 3 --Y--Ar 4 -- where each of Ar 3 and Ar 4 is a hydrocarbon group having a divalent benzene nucleus and Y is a sulfone group or a carbonyl group, and n is an integer of from 1 to 50.

Claim 3

The epoxy resin according to claim 1 wherein Ar 1 in the general formula I is a residual group of a dihydric phenol selected from the group consisting of 2,2-bis(4-hydroxyphenyl)propane, bis(4-hydroxyphenyl)methane, 1,2-bis(4-hydroxyphenyl)ethane, 4,4'-dihydroxydiphenyl ether, 4,4'-dihydroxydiphenylsulfide, 4,4'-dihydroxydiphenylsulfone, 4,4'-dihydroxydiphenylketone and biphenol.

Claim 4

The epoxy resin according to claim 1 wherein Ar 2 in the general formula I is a residual group of a halogen-substituted benzenoid compound selected from the group consisting of 4,4'-dichlorodiphenylsulfone, 4,4'-difluorodiphenylsulfone, 4,4'-dichlorodiphenylketone and 4,4'-difluorodiphenylketone.

Claim 5

The epoxy resin according to claim 2 wherein Ar 2 in the general formula I is a residual group of a halogen-substituted benzenoid compound selected from the group consisting of 4,4'-dichlorodiphenylsulfone, 4,4'-difluorodiphenylsulfone, 4,4'-dichlorodiphenylketone and 4,4'-difluorodiphenylketone.

Claim 6

A process for producing an epoxy resin which comprises reacting epichlorohydrin with a reaction product A obtained by reacting a compound represented by the general formula II MO--Ar.sup.1 --OM (II) where Ar 1 is a residual group of a dihydric phenol derived from a compound having one or two benzene nuclei and M is an alkali metal, with a compound represented by the general formula III X--Ar.sup.2 --X (III) where Ar 2 is a residual group of a halogen-substituted benzenoid compound having two halogen atoms on its nuclei and represented by the formula --Ar 3 --Y--Ar 4 -- where each of Ar 3 and Ar 4 is a hydrocarbon group having a divalent benzene nucleus and Y is a sulfone group or a carbonyl group, and X is a fluorine atom, a chlorine atom or a bromine atom, in a solvent containing a highly polar solvent under substantially anhydrous conditions.

Claim 7

A process for producing an epoxy resin which comprises reacting epichlorohydrin with a reaction product A obtained by reacting a compound represented by the general formula II MO--Ar.sup.1 --OM (II) where Ar 1 is a residual group of a dihydric phenol derived from a compound having one or two benzene nuclei and M is an alkali metal, with a compound represented by the general formula III X--Ar.sup.2 --X (III) where Ar 2 is a residual group of a halogen-substituted benzenoid compound having two halogen atoms on its nuclei and represented by the formula --Ar 3 --Y--Ar 4 -- where each of Ar 3 and Ar 4 is a hydrocarbon group having a divalent benzene nucleus and Y is a sulfone group or a carbonyl group, and X is a fluorine atom, a chlorine atom or a bromine atom, in a solvent containing a highly polar solvent under substantially anhydrous conditions.

Claim 8

The process according to claim 5 wherein the compound of the general formula II is reacted with the compound of the general formula III in a molar ratio of the Compound II to the Compound III being from 1.01 to 2.0.

Claim 9

The process according to claim 5 wherein the epichlorohydrin is reacted with the reaction product A in a ratio of at least 1 mol of the epichlorohydrin per one phenolate terminal of the reaction product A.

Claim 10

The process according to claim 6 wherein the epichlorohydrin is reacted with the reaction product A in a ratio of at least 1 mol of the epichlorohydrin per one phenolate terminal of the reaction product A.