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US4448894A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst and reverse disproportionation process

Assignee: Monsanto Co
•
Filing: 1983-07-18
•
Granted: 1984-05-15
•
Expires: 2003-07-18
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Abstract

Abstract A catalyst containing tungsten, antimony and an alkali or alkaline earth component on a support, preferably silica gel, is disclosed which is useful in reverse disproportionation of stilbene and ethylene to produce styrene.

Inventors

  • 👤 Charles F. Hobbs

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 07:41
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/16; B01J23/24; B01J23/30; C; C07; C07C; C07C6/00; C07C6/02; C07C6/04

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 19 words
A catalyst comprising catalytically-effective amounts of antimony, tungsten and an alkali or alkaline earth component on a carrier material.
Claim 2
Dependent Claim 19 words
A catalyst comprising catalytically-effective amounts of antimony, tungsten and an alkali or alkaline earth component on a carrier material.
Claim 3
Dependent Claim 11 words
Catalyst of claim 1 wherein the carrier material is silica gel.
Claim 4
Dependent Claim 13 words
Catalyst of claim 1 wherein the alkali or alkaline earth component is potassium.
Claim 5
Dependent Claim 38 words
Catalyst of claim 1 wherein the catalyst contains 0.1 to 10 wt % W, 0.01 to 2 wt % alkali or alkaline earth component and 0.03 to 4 wt % Sb, and the carrier material is silica gel.
Claim 6
Dependent Claim 48 words
Catalyst of claim 1 wherein the catalyst contains 1 to 6 wt % W as WO 3 , 0.1 to 1.5 wt % Sb as Sb 2 O 3 , and 0.03 to 0.2 wt % K as K 2 O, and the carrier material is silica gel.
Claim 7
Dependent Claim 13 words
Catalyst of claim 1 wherein the Sb:W atomic ratio is 1:20 to 2:1.
Claim 8
Dependent Claim 11 words
Catalyst of claim 1 wherein the Sb:W atomic ratio is 1:5.

References Cited (Backward Citations)

GB1205677A Cited
US3658930A Cited
US3728414A Cited
US3764635A Cited
US3792107A Cited
US3965206A Cited
US4144197A Cited
US4192961A Cited
US4300007A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-15 1987-11-14 1988-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-15 1991-11-14 1992-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-15 1995-11-14 1996-05-15 $7700.00 Window Closed / Lapsed

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