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US4447345A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermal insulating flexible ceramic containing flame hydrolysis produced microporous oxide aerogel

Assignee: Gruenzweig und Hartmann und Glasfaser AG
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Filing: 1982-03-09
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Granted: 1984-05-08
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Expires: 2002-03-09
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Abstract

Abstract A thermal insulating flexible ceramic based on a microporous oxide aerogel obtained from flame hydrolysis, especially a silica aerogel with elastically bending or limply bending inorganic fibers and possibly additional additive substances, such as opacifiers, has a portion by weight between about 10 and 30% of the flexible ceramic in the form of fibers with a length of more than 10 mm with a comparatively high bulk density of about 200 to 250 kg/m 3 , especially of about 350 kg/m 3 . Although no binder such as e.g. phenol resin is contained therein, said flexible ceramic in the case of a given high content of long fibers, has a high bending strength, but at the same time it is very resistant to breakage in the case even of multiple bendings around relatively small bending radii. For such a flexible ceramic, one may produce pliable thermal insulating foils (5) with low thicknesses (d) of, if necessary less than 1 mm, which still have considerable stability of shape, but which may be bent very well and may even be stamped. Furthermore, the flexible ceramic may be used for the formation of covered up insulating layers or of insulating layers laminated on both sides in thermal insulating elements possibly also of a more complicated molding. In order to be able to admix the high portion of long fibers without the formation of local fiber agglomerations, said fibers are admixed separated, e.g. by flakes, as a last component to the already finished premixture of the raw material.

Inventors

  • 👤 Hans Kummermehr
  • 👤 Rolf Sommer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 12:54
CPC Classifications
B; B32; B32B; B32B9/00; B32B9/04; B32B9/041; B32B7/00; B32B7/04; B32B7/12; C; C04; C04B; C04B30/00; C04B30/02; B32B2307/00; B32B2307/30; B32B2307/304; Y; Y10; Y10S; Y10S428/00; Y10S428/92; Y10T; Y10T428/00; Y10T428/23; Y10T428/239; Y10T428/25; Y10T428/259; Y10T428/29; Y10T428/2913; Y10T428/2927

Claims Analysis

Total Claims: 76
Claim 1
Independent Claim 180 words
Thermal insulating flexible ceramic on the basis of microporous oxide aerogel obtained from flame hydrolysis with elastically bending or limply bending, fibers with or without additional additive substances characterized by the combination of the following features: (a) the frequency distribution of the length of fibers has a maximum of over 10 mm; (b) the flexible ceramic is compressed up to a bulk density of more than 200 kg/m 3 ; (c) the sum of the portions of weight of the fibers and of the additive substances, which however contain no binder, lies between about 10% and 60% of the flexible ceramic; and (d) the portion of weight of fibers with a specific density of the fiber material of 2.55 g/cm 3 insofar as the fibers have a greater length than 10 mm, lies between about 10% and 30% of the flexible ceramic, whereby in the case of fiber material with a density of 2.55 g/cm 3 , the portions deviating from weight are to be changed with a factor which corresponds to the ratio of the deviating density to 2.55.
Claim 2
Dependent Claim 180 words
Thermal insulating flexible ceramic on the basis of microporous oxide aerogel obtained from flame hydrolysis with elastically bending or limply bending, fibers with or without additional additive substances characterized by the combination of the following features: (a) the frequency distribution of the length of fibers has a maximum of over 10 mm; (b) the flexible ceramic is compressed up to a bulk density of more than 200 kg/m 3 ; (c) the sum of the portions of weight of the fibers and of the additive substances, which however contain no binder, lies between about 10% and 60% of the flexible ceramic; and (d) the portion of weight of fibers with a specific density of the fiber material of 2.55 g/cm 3 insofar as the fibers have a greater length than 10 mm, lies between about 10% and 30% of the flexible ceramic, whereby in the case of fiber material with a density of 2.55 g/cm 3 , the portions deviating from weight are to be changed with a factor which corresponds to the ratio of the deviating density to 2.55.
Claim 3
Dependent Claim 29 words
Flexible ceramic as in claim 1, characterized in that the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%.
Claim 4
Dependent Claim 28 words
Flexible ceramic as in claim 2, characterized in that the portion of weight of the fiber with a greater length than 10 mm lies between 12 and 20%.
Claim 5
Dependent Claim 18 words
Flexible ceramic as in claim 1, characterized in that the thickness of the fibers lies below 10 μm.
Claim 6
Dependent Claim 25 words
Flexible ceramic as in claim 1, characterized in that the frequency distribution of the fiber length has a maximum between 20 mm and 70 mm.
Claim 7
Dependent Claim 25 words
Flexible ceramic as in claim 1, characterized in that the bulk density of the plastic lies between 300 kg/m 3 and 400 kg/m 3 .
Claim 8
Dependent Claim 15 words
Flexible ceramic as in claim 1, characterized in that the inorganic fibers are mineral fibers.
Claim 9
Dependent Claim 15 words
Flexible ceramic as in claim 1, characterized in that the inorganic fibers are metallic fibers.
Claim 10
Dependent Claim 29 words
Flexible ceramic as in claim 1, characterized in that the oxide aerogel is a silica aerogel, zerconium oxide or an aluminum oxide aerogel, zerconium oxide or a mixture thereof.
Claim 11
Dependent Claim 32 words
Process for the production of a flexible ceramic as in claim 1 comprising mixing and pressing the components with the fibers being admixed at the last components at least separated as groups.
Claim 12
Dependent Claim 47 words
Process as in claim 10 wherein there is used an additive substance and first of all there is produced a premixture of aerogel and additive substance in which the additive substance is present a homogeneous distribution corresponding at least approximately to the distribution in the flexible ceramic.
Claim 13
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 1.
Claim 14
Dependent Claim 14 words
Thermal insulating flexible ceramic according to claim 1, wherein there is present an opacifier.
Claim 15
Dependent Claim 14 words
Thermal insulating flexible ceramic according to claim 1, wherein the fibers are inorganic fibers.
Claim 16
Dependent Claim 14 words
Thermal insulating flexible ceramic according to claim 14 wherein there is present an opacifier.
Claim 17
Dependent Claim 23 words
Thermal insulating flexible ceramic according to claim 15 wherein the plastic is compressed to a bulk density of over 250 kg/m 3 .
Claim 18
Dependent Claim 29 words
Thermal insulating flexible ceramic according to claim 15 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%.
Claim 19
Dependent Claim 28 words
Thermal insulating flexible ceramic according to claim 17 wherein the portion of weight of the fibers with a greater length than 10 mm lies between 12 and 22%.
Claim 20
Dependent Claim 28 words
Thermal insulating flexible ceramic according to claim 1 wherein the portion of weight of the fibers with a greater length than 10 mm lies between 12 and 22%.
Claim 21
Dependent Claim 28 words
Thermal insulating flexible ceramic according to claim 17 wherein the portion of weight of the fibers with a greater length than 10 mm lies between 12 and 20%.
Claim 22
Dependent Claim 28 words
Thermal insulating flexible ceramic according to claim 17 wherein the portion of weight of the fibers with a greater length than 10 mm lies between 14 and 20%.
Claim 23
Dependent Claim 28 words
Thermal insulating flexible ceramic according to claim 17 wherein the portion of weight of the fibers with a greater length than 10 mm lies between 15 and 18%.
Claim 24
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 15 wherein the thickness of the fibers lies below 10 μm.
Claim 25
Dependent Claim 29 words
Thermal insulating flexible ceramic according to claim 23 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%.
Claim 26
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 24 wherein the thickness of the fibers lies below 5 μm.
Claim 27
Dependent Claim 20 words
Thermal insulating flexible ceramic according to claim 25 wherein the thickness of the fibers is at 1 to 3 μm.
Claim 28
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 4 wherein the thickness of the fibers lies below 5 μm.
Claim 29
Dependent Claim 20 words
Thermal insulating flexible ceramic according to claim 27 wherein the thickness of the fibers is at 1 to 3 μm.
Claim 30
Dependent Claim 25 words
Thermal insulating flexible ceramic according to claim 15 wherein the frequency distribution of the fiber length has a maximum between 20 mm and 70 mm.
Claim 31
Dependent Claim 24 words
Thermal insulating flexible ceramic according to claim 29 wherein the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 32
Dependent Claim 24 words
Thermal insulating flexible ceramic according to claim 1 wherein the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 33
Dependent Claim 24 words
Thermal insulating flexible ceramic according to claim 17 wherein the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 34
Dependent Claim 29 words
Thermal insulating flexible ceramic according to claim 32 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%.
Claim 35
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 33 wherein the thickness of the fibers lies below 10 μm.
Claim 36
Dependent Claim 20 words
Thermal insulating flexible ceramic according to claim 34 wherein the thickness of the fibers is at 1 to 3 μm.
Claim 37
Dependent Claim 25 words
Thermal insulating flexible ceramic according to claim 15 wherein the bulk density of the plastic lies between 300 kg/m 3 and 400 kg/m 3 .
Claim 38
Dependent Claim 21 words
Thermal insulating flexible ceramic according to claim 36 wherein the bulk density of the plastic is about 350 kg/m 3 .
Claim 39
Dependent Claim 21 words
Thermal insulating flexible ceramic according to claim 1 wherein the bulk density of the plastic is about 350 kg/m 3 .
Claim 40
Dependent Claim 25 words
Thermal insulating flexible ceramic according to claim 17 wherein the bulk density of the plastic lies between 300 kg/m 3 and 400 kg/m 3 .
Claim 41
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 39 wherein the thickness of the fibers lies below 10 μm.
Claim 42
Dependent Claim 20 words
Thermal insulating flexible ceramic according to claim 40 wherein the thickness of the fibers is at 1 to 3 μm.
Claim 43
Dependent Claim 24 words
Thermal insulating flexible ceramic according to claim 41 wherein the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 44
Dependent Claim 24 words
Thermal insulating flexible ceramic according to claim 15 wherein the inorganic fibers are aluminum silicate fibers, aluminum oxide fibers, quartz fibers or metal fibers.
Claim 45
Dependent Claim 22 words
Thermal insulating flexible ceramic according to claim 5 wherein the inorganic fibers are aluminum silicate fibers, aluminum oxide fibers or quartz fibers.
Claim 46
Dependent Claim 25 words
Thermal insulating flexible ceramic according to claim 44 wherein the bulk density of the plastic lies between 300 kg/m 3 and 400 kg/m 3 .
Claim 47
Dependent Claim 29 words
Thermal insulating flexible ceramic according to claim 45 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%.
Claim 48
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 46 wherein the thickness of the fibers lies below 10 μm.
Claim 49
Dependent Claim 20 words
Thermal insulating flexible ceramic according to claim 47 wherein the thickness of the fibers is at 1 to 3 μm.
Claim 50
Dependent Claim 24 words
Thermal insulating flexible ceramic according to claim 48 wherein the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 51
Dependent Claim 15 words
Thermal insulating flexible ceramic according to claim 43 wherein the inorganic fibers are metal fibers.
Claim 52
Dependent Claim 16 words
Thermal insulating flexible ceramic according to claim 50 wherein the metal fibers are noble steel fibers.
Claim 53
Dependent Claim 54 words
Thermal insulating flexible ceramic according to claim 51 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%, the thickness of the fibers lies below 10 μm and the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 54
Dependent Claim 23 words
Thermal insulating flexible ceramic according to claim 9 wherein the aerogel is a silica aerogel, an aluminum oxide aerogel or a mixture thereof.
Claim 55
Dependent Claim 22 words
Thermal insulating flexible ceramic according to claim 6 wherein the inorganic fibers are aluminum silicate fibers, aluminum oxide fibers or quartz fibers.
Claim 56
Dependent Claim 25 words
Thermal insulating flexible ceramic according to claim 54 wherein the bulk density of the plastic lies between 300 kg/m 3 and 400 kg/m 3 .
Claim 57
Dependent Claim 29 words
Thermal insulating flexible ceramic according to claim 55 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%.
Claim 58
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 56 wherein the thickness of the fibers lies below 10 μm.
Claim 59
Dependent Claim 20 words
Thermal insulating flexible ceramic according to claim 57 wherein the thickness of the fibers is at 1 to 3 μm.
Claim 60
Dependent Claim 24 words
Thermal insulating flexible ceramic according to claim 58 wherein the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 61
Dependent Claim 15 words
Thermal insulating flexible ceramic according to claim 53 wherein the inorganic fibers are metal fibers.
Claim 62
Dependent Claim 54 words
Thermal insulating flexible ceramic according to claim 60 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%, the thickness of the fibers lies below 10 μm and the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 63
Dependent Claim 54 words
Thermal insulating flexible ceramic according to claim 54 wherein the portion of weight of the fibers with a greater length than 10 mm lies between about 12 and 25%, the thickness of the fibers lies below 10 μm and the frequency distribution of the fiber length has a maximum between 30 and 50 mm.
Claim 64
Dependent Claim 28 words
Thermal insulating flexible ceramic according to claim 62 wherein the inorganic fibers are aluminum silicate fibers, the aerogel is a silica aerogel and the opacificer is silicon carbide.
Claim 65
Dependent Claim 15 words
Thermal insulating flexible ceramic according to claim 53 wherein the aerogel is a silica aerogel.
Claim 66
Dependent Claim 18 words
Thermal insulating flexible ceramic according to claim 15 wherein the opacifier is silicon carbide, titanium dioxide or ilmenite.
Claim 67
Dependent Claim 17 words
Process according to claim 10 wherein the fibers are inorganic fibers and there is present an opacifier.
Claim 68
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 15.
Claim 69
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 2.
Claim 70
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 3.
Claim 71
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 4.
Claim 72
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 5.
Claim 73
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 6.
Claim 74
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 7.
Claim 75
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 8.
Claim 76
Dependent Claim 21 words
Thermal insulating, pliable foil with a thickness up to below 1 mm made of a flexible ceramic according to claim 9.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-05-08 1987-11-07 1988-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-05-08 1991-11-07 1992-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-05-08 1995-11-07 1996-05-08 $7700.00 Window Closed / Lapsed

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